Abstract
When colloidal suspensions dry, stresses build up and cracks often occur -a phenomenon undesirable for important industries such as paint and ceramics. We demonstrate an effective method which can completely eliminate cracking during drying: by adding emulsion droplets into colloidal suspensions, we can systematically decrease the amount of cracking, and eliminate it completely above a critical droplet concentration. Since the emulsion droplets eventually also evaporate, our technique achieves an effective function while making little changes to the component of final product, and may therefore serve as a promising approach for cracking elimination. Furthermore, adding droplets also varies the speed of air invasion and provides a powerful method to adjust drying rate. With the effective control over cracking and drying rate, our study may find important applications in many drying- and cracking-related industrial processes.
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References
U.T. Gonzenbach, A.R. Studart, D. Steinlin, E. Tervoort, L.J. Gauckler, J. Am. Ceram. Soc. 90, 3407 (2007)
R.D. Deegan, O. Bakajin, T.F. Dupont, G. Huber, S.R. Nagel, T.A. Witten, Nature (London) 389, 827 (1997)
R.D. Deegan, O. Bakajin, T.F. Dupont, G. Huber, S.R. Nagel, T.A. Witten, Phys. Rev. E. 62, 756 (2000)
E.R. Dufresne, E.I. Corwin, N.A. Greenblatt, J. Ashmore, D.Y. Wang, A.D. Dinsmore, J.X. Cheng, X.S. Xie, J.W. Hutchinson, D.A. Weitz, Phys. Rev. Lett. 91, 224501 (2003)
E.R. Dufresne, D.J. Stark, N.A. Greenblatt, J.X. Cheng, J.W. Hutchinson, L. Mahadevan, D.A. Weitz, Langmuir 22, 7144 (2006)
L. Xu, S. Davies, A.B. Schofield, D.A. Weitz, Phys. Rev. Lett. 101, 094502 (2008)
C. Allain, L. Limat, Phys. Rev. Lett. 74, 2981 (1995)
T. Boeck, H.A. Bahr, S. Lampenscherf, U. Bahr, Phys. Rev. E. 59, 1408 (1999)
S. Kitsunezaki, Phys. Rev. E. 60, 6449 (1999)
A. Groisman, E. Kaplan, Europhys. Lett. 25, 415 (1994)
K.A. Shorlin, J.R. de Bruyn, M. Graham, S.W. Morris, Phys. Rev. E. 61, 6950 (2000)
S. Kitsunezaki, J. Phys. Soc. Jpn. 78, 064801 (2009)
C.J. Martinez, J.A. Lewis, Langmuir 18, 4689 (2002)
K.B. Singh, M.S. Tirumkudulu, Phys. Rev. Lett. 98, 218302 (2007)
K.B. Singh, G. Deoghare, M.S. Tirumkudulu, Langmuir 25, 751 (2009)
J.H. Prosser, T. Brugarolas, S. Lee, A.J. Nolte, D. Lee, Nano Lett. 12, 5287 (2012)
The evaporation rate of the droplets is much slower than the solvent therefore the droplet volume is approximately a constant during our measurement time
L. Xu, A. Bergès, P.J. Lu, A.R. Studart, A.B. Schofield, H. Oki, S. Davies, D.A. Weitz, Phys. Rev. Lett. 104, 128303 (2010)
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Jin, Q., Tan, P., Schofield, A. et al. Eliminating cracking during drying. Eur. Phys. J. E 36, 28 (2013). https://doi.org/10.1140/epje/i2013-13028-9
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DOI: https://doi.org/10.1140/epje/i2013-13028-9