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Dynamic structure factor of a stiff polymer in a glassy solution

  • J. Glaser
  • O. Hallatschek
  • K. Kroy
ISMC-2007

Abstract.

We provide a comprehensive overview of the current theoretical understanding of the dynamic structure factor of stiff polymers in semidilute solution based on the wormlike chain (WLC) model. We extend previous work by computing exact numerical coefficients and an expression for the dynamic mean square displacement (MSD) of a free polymer and compare various common approximations for the hydrodynamic interactions, which need to be treated accurately if one wants to extract quantitative estimates for model parameters from experimental data. A recent controversy about the initial slope of the dynamic structure factor is thereby resolved. To account for the interactions of the polymer with a surrounding (sticky) polymer solution, we analyze an extension of the WLC model, the glassy wormlike chain (GWLC), which predicts near power law and logarithmic long-time tails in the dynamic structure factor.

PACS.

61.25.he Polymer solutions 83.10.Kn Reptation and tube theories 67.70.Pj Polymers 

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Copyright information

© EDP Sciences, Società Italiana di Fisica and Springer-Verlag 2008

Authors and Affiliations

  1. 1.Institut für Theoretische PhysikUniversität LeipzigLeipzigGermany
  2. 2.Lyman LaboratoryHarvard UniversityCambridgeUSA
  3. 3.Hahn-Meitner Institut BerlinBerlinGermany

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