The European Physical Journal E

, Volume 13, Issue 3, pp 225–237 | Cite as

Calculation of the persistence length of a flexible polymer chain with short-range self-repulsion

Article

Abstract.

For a self-repelling polymer chain consisting of n segments we calculate the persistence length \(L\left(j,n\right)\), defined as the projection of the end-to-end vector on the direction of the j-th segment. This quantity shows some pronounced variation along the chain. Using the renormalization group and \(\epsilon\)-expansion we establish the scaling form and calculate the scaling function to order \(\epsilon^2\). Asymptotically, the simple result \(L\left(j,n\right) \approx \mbox{const} \left(j\left(n-j\right)/n\right)^{2\nu-1}\) emerges for dimension d = 3. Also away from the excluded-volume limit \(L\left(j,n\right)\) is found to behave very similar to the swelling factor of a chain of length \(j \left(n-j\right)/n\). We carry through simulations which are found to be in good accord with our analytical results. For d = 2 both our and previous simulations as well as theoretical arguments suggest the existence of logarithmic anomalies.

Keywords

Polymer Polymer Chain Renormalization Group Theoretical Argument Previous Simulation 

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Copyright information

© Springer-Verlag Berlin/Heidelberg 2004

Authors and Affiliations

  1. 1.Universität Duisburg-EssenEssenGermany

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