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The European Physical Journal D

, Volume 51, Issue 3, pp 357–367 | Cite as

Spectral and temporal features of multiple spontaneous NMR-maser emissions

  • D.J.-Y. Marion
  • P. Berthault
  • H. Desvaux
Molecular Physics and Chemical Physics Regular Article

Abstract

When a system composed of dissolved laser-polarized xenon with negative spin temperature is put inside a high field NMR magnet, a series of spontaneous maser emissions can be observed. We report here their spectral and temporal features using a processing model derived from the solution of the Bloch equations in the presence of radiation damping. We show, in particular, that by combining Fourier transformation and squared modulus, a parameter allowing the characterization of the burst of transverse magnetization can be determined. This parameter is shown to be correlated with the radiated energy. Moreover, this processing clearly reveals features which can probably be assigned to effects resulting from distant dipolar fields. Finally, the analysis of the experimental data reveals an unexpected behavior of the 129Xe transverse self-relaxation.

PACS

84.40.Ik Masers; gyrotrons 82.56.-b Nuclear magnetic resonance 76.60.Es Relaxation effects 32.80.Xx Level crossing and optical pumping of atoms 

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References

  1. T.G. Walker, W. Happer, Rev. Mod. Phys. 69, 629 (1997)Google Scholar
  2. D.A. Hall, D.C. Maus, G.J. Gerfen, S.J. Inati, L.R. Becerra, F.W. Dahlquist, R.G. Griffin, Science 276, 930 (1997)Google Scholar
  3. J.H. Ardenkjær-Larsen, B. Fridlund, A. Gram, G. Hansson, L. Hansson, M.H. Lerche, R. Servin, M. Thaning, K. Golman, Proc. Natl. Acad. Sci. USA 100, 10158 (2003)Google Scholar
  4. G. Navon, Y.-Q. Song, T. Rõõm, S. Appelt, R.E. Taylor, A. Pines, Science 271, 1848 (1996)Google Scholar
  5. L. Dubois, P. Berthault, J.G. Huber, H. Desvaux, C. R. Physique 5, 305 (2004)Google Scholar
  6. H. Desvaux, D.J. Marion, G. Huber, L. Dubois, P. Berthault, Eur. Phys. J. Appl. Phys. 36, 25 (2006)Google Scholar
  7. G. Deville, M. Bernier, J.M. Delrieux, Phys. Rev. B 19, 5666 (1979)Google Scholar
  8. W.S. Warren, W. Richter, A.H. Andreotti, B.T. Farmer II, Science 262, 2005 (1993)Google Scholar
  9. J. Jeener, A. Vlassenbroek, P. Broekaert, J. Chem. Phys. 103, 1309 (1995)Google Scholar
  10. S. Lee, W. Richter, S. Vathyam, W.S. Warren, J. Chem. Phys. 105, 874 (1996)Google Scholar
  11. A. Abragam, M. Goldman, Nuclear magnetism: order and disorder (Clarendon Press, Oxford, 1982)Google Scholar
  12. J.D. Walls, F.K.H. Phoa, Y.Y. Lin, Phys. Rev. B 70, 174410 (2004)Google Scholar
  13. N. Bloembergen, R.V. Pound, Phys. Rev. 95, 8 (1954)Google Scholar
  14. X.A. Mao, J.X. Guo, C.H. Ye, Phys. Rev. B 49, 15702 (1994)Google Scholar
  15. M.P. Augustine, Prog. NMR Spectrosc. 40, 111 (2002)Google Scholar
  16. H.T. Edzes, J. Magn. Reson. 86, 293 (1990)Google Scholar
  17. D. Candela, M.E. Hayden, P.J. Nacher, Phys. Rev. Lett. 73, 2587 (1994)Google Scholar
  18. M. Goldman, H. Desvaux, Chem. Phys. Lett. 256, 497 (1996)Google Scholar
  19. K.L. Sauer, F. Marion, P.J. Nacher, G. Tastevin, Phys. Rev. B 63, 184427 (2001)Google Scholar
  20. J.D. Walls, S.Y. Huang, Y.Y. Lin, J. Phys. Chem. B 110, 19985 (2006)Google Scholar
  21. M.E. Hayden, E. Baudin, G. Tastevin, P.J. Nacher, Phys. Rev. Lett. 99, 137602 (2007)Google Scholar
  22. J. Jeener, Phys. Rev. Lett. 82, 1772 (1999)Google Scholar
  23. Y.Y. Lin, N. Lisitza, S.D. Ahn, W.S. Warren, Science 290, 118 (2000)Google Scholar
  24. J. Jeener, J. Chem. Phys. 116, 8439 (2002)Google Scholar
  25. S.Y. Huang, J.D. Walls, Y. Wang, W.S. Warren, Y.Y. Lin, J. Chem. Phys. 121, 6105 (2004)Google Scholar
  26. J. Jeener, in Encyclopedia of NMR, edited by D.M. Grant, R.K. Harris (Wiley, 2002), p. 642Google Scholar
  27. D.J.Y. Marion, G. Huber, P. Berthault, H. Desvaux, ChemPhysChem 9, 1395 (2008)Google Scholar
  28. E. Brun, B. Derighetti, D. Meier, R. Holzner, M. Ravani, J. Opt. Soc. Am. B 2, 156 (1985)Google Scholar
  29. L.W. Casperson, in Lecture notes in physics, Laser physics, edited by D. Walls, J. Harvey (Springer-Verlag, Berlin, 1983), p. 88Google Scholar
  30. T. Enss, S. Ahn, W.S. Warren, Chem. Phys. Lett. 305, 101 (1999)Google Scholar
  31. C.L. Davis, V.K. Henner, A.V. Tchernatinsky, I.V. Kaganov, Phys. Rev. B 72, 054406 (2005)Google Scholar
  32. W.H. Press, S.A. Teukolsky, W.T. Vetterling, B.P. Flannery, Numerical Recipes in C. The art of scientific programming (Cambridge University Press, Cambridge, 1988)Google Scholar
  33. H. Desvaux, T. Gautier, G. Le Goff, M. Pétro, P. Berthault, Eur. Phys. J. D 12, 289 (2000)Google Scholar
  34. D.J.Y. Marion, G. Huber, L. Dubois, P. Berthault, H. Desvaux, J. Magn. Reson. 187, 78 (2007)Google Scholar
  35. D.J.Y. Marion, G. Huber, P. Berthault, H. Desvaux, C.R. Chimie 11, 553 (2008)Google Scholar
  36. D.J.Y. Marion, H. Desvaux, J. Magn. Reson. 193, 153 (2008)Google Scholar
  37. M. Guéron, J.L. Leroy, J. Magn. Reson. 85, 209 (1989)Google Scholar
  38. A. Abragam, Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961)Google Scholar
  39. N. Segebarth, L. Aïtjeddig, E. Locci, K. Bartik, M. Luhmer, J. Phys. Chem. A 110, 10770 (2006)Google Scholar
  40. W.S. Warren, S. Ahn, J. Chem. Phys. 108, 1313 (1998)Google Scholar
  41. P. Flandrin, Temps-fréquence (Hermès, Paris, 1998)Google Scholar

Copyright information

© EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg 2009

Authors and Affiliations

  1. 1.CEA, IRAMIS, Service de Chimie Moléculaire, Laboratoire Structure et Dynamique par Résonance Magnétique, URA CEA/CNRS 331Gif-sur-YvetteFrance

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