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Helium nanodroplet assisted synthesis of bimetallic Ag@Au nanoparticles with tunable localized surface plasmon resonance

  • Florian LacknerEmail author
  • Alexander Schiffmann
  • Maximillian Lasserus
  • Roman Messner
  • Martin Schnedlitz
  • Harald Fitzek
  • Peter Pölt
  • Daniel Knez
  • Gerald Kothleitner
  • Wolfgang E. Ernst
Open Access
Regular Article
Part of the following topical collections:
  1. Topical Issue: Dynamics of Systems on the Nanoscale (2018)

Abstract

Nanoparticles with tunable localized surface plasmon resonance have been prepared by synthesis in helium nanodroplets. Subsequent surface deposition allows for the formation of substrates which can be employed for surface-enhanced Raman spectroscopy (SERS). The assembly of Ag@Au core@shell clusters of about 5 nm diameter in helium droplets with different Ag:Au ratio allows to tune the surface plasmon resonance between the plain Ag resonance at 447 nm and the Au resonance at 555 nm. For the fabricated substrates only a single plasmon resonance is observed in the UV/vis absorption spectra. The prepared nanostructures have been functionalized with 4-methylbenzenethiol (4-MBT) molecules and SERS spectra have been recorded. The results demonstrate the potential of the helium droplet synthesis approach, opening up a new route to the formation of tailored plasmonic nanoparticles and functional nanostructures.

Graphical abstract

Keywords

Clusters and Nanostructures 

Notes

Acknowledgments

Open access funding provided by Austrian Science Fund (FWF).

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Copyright information

© The Author(s) 2019

Open Access This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Authors and Affiliations

  1. 1.Institute of Experimental Physics, Graz University of TechnologyGrazAustria
  2. 2.Institute of Electron Microscopy and Nanoanalysis & Graz Centre for Electron Microscopy, Graz University of TechnologyGrazAustria

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