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Experimental and theoretical results of resonant and normal Auger decay in dichloromethane

  • Antonio C. F. SantosEmail author
  • Debora N. Vasconcelos
  • Michael A. MacDonald
  • Marcelo M. Sant’Anna
  • Bruno N. C. Tenório
  • Alexandre B. Rocha
  • Viviane Morcelle
  • Narayan Appathurai
  • Lucia Zuin
Regular Article
  • 14 Downloads
Part of the following topical collections:
  1. Topical Issue: Many Particle Spectroscopy of Atoms, Molecules, Clusters and Surfaces (2018)

Abstract

The Auger electron spectra after the chlorine 2p excitation and ionization in the gas phase CH2Cl2 and CD2Cl2 molecules were investigated both theoretically and experimentally. A series of high-level ab initio quantum mechanical calculations have been performed at multiconfigurational self-consistent field (MCSCF) and multireference configuration interaction (MRCI) levels of theory to compute the Cl L2,3VV Auger lines. Calculations were compared with the corresponding experimental photoexcited and photoionized spectra.

Keywords

Topical issue 

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Copyright information

© EDP Sciences / Società Italiana di Fisica / Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Antonio C. F. Santos
    • 1
    Email author
  • Debora N. Vasconcelos
    • 1
  • Michael A. MacDonald
    • 2
  • Marcelo M. Sant’Anna
    • 1
  • Bruno N. C. Tenório
    • 3
  • Alexandre B. Rocha
    • 3
  • Viviane Morcelle
    • 4
  • Narayan Appathurai
    • 2
  • Lucia Zuin
    • 2
  1. 1.Instituto de Física, Universidade Federal do Rio de JaneiroRio de JaneiroBrazil
  2. 2.Canadian Light Source Inc.SaskatoonCanada
  3. 3.Instituto de Química, Universidade Federal do Rio de JaneiroRio de JaneiroBrazil
  4. 4.Departamento de Física, Universidade Federal Rural do Rio de JaneiroSeropédicaBrazil

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