Abstract
Experimental methods for protection of metals from corrosion by radiation-oxidative treatment in hydrogen peroxide are considered. It is established that such treatment of stainless steel for 30–50 h (D = 123–205 kGy) leads to the formation of a surface oxide film that passivates the surface of the metal during thermal and radiation-thermal processes of water decomposition. With an increase in the thickness of the oxide film, its defectiveness increases and the oxidation of the metal phase increases.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS2075113320030028/MediaObjects/13188_2020_1354_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS2075113320030028/MediaObjects/13188_2020_1354_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS2075113320030028/MediaObjects/13188_2020_1354_Fig3_HTML.gif)
Similar content being viewed by others
REFERENCES
Belousov, V.V., Catastrophic oxidation of metals, Russ. Chem. Rev., 1998, vol. 67, no. 7, pp. 563–571.
Semenova, I.V., Florianovich, G.M., and Khoroshilov, A.V., Korroziya i zashchita ot nee (Corrosion and Corrosion Protection), Moscow: Fizmatlit, 2008.
Gerasimov, V.V., Korroziya i obluchenie (Corrosion and Irradiation), Moscow: Gosatomizdat, 1963.
Agaev, T.N. and Kasumova, U.M., Effect of gamma-irradiation on the corrosion of stainless steel in water, Materialy XVIII Mendeleevskogo s”ezda po obshchei i prikladnoi khimii, Moskva, 23–28 sentyabrya,2007 (Proc. XVIII Mendeleev Congr. on General and Applied Chemistry, Moscow, September 23–28, 2007), Moscow: Granitsa, 1982. http://www.issp.ac.ru/ebooks/ conf/MC_rus.pdf.
Vettegren, V.I., Bashkarev, A.Ya., and Morozov, G.I., Distribution of corrosion pits on a metal surface, Tech. Phys. Lett., 2002, vol. 28, no. 7, pp. 533–535.
Vettegren, V.I., Bashkarev, A.Ya., Danchukov, K.G., and Morozov, G.I., The kinetics of steel corrosion in sea water, Tech. Phys. Lett., 2003, vol. 29, no. 1, pp. 64–65.
Agaev, T.N., Effect of irradiation on preliminarily radiation-oxidation-treated stainless steel, Met. Sci. Heat Treat., 2009, vol. 51, nos. 1–2, pp. 49–51. https://doi.org/10.1007/s11041-009-9114-z
Agaev, T.N., Garibov, A.A., and Kasumova, U.M., The influence power of radiation dose on radiolysis of water in contact with stainless steel, Estestv. Tekh. Nauki, 2012, no. 4, pp. 317–324.
Voevodin, V.N., Zelenskii, V.F., Neklyudov, I.M., and Borodin, O.V., Radiation-induced microstructure changes in austenitic and ferritic stainless steels, Phys. Met. Metallogr., 1996, vol. 81, no. 3, pp. 294–298.
Votinov, S.N., Prokhorov, V.I., and Ostrovsky, Z.E., Obluchennye nerzhaveyushchie stali (Irradiated Stainless Steel), Moscow: Nauka, 1987.
Garibov, A.A. and Agaev, T.N., Radiation-heterogeneous processes in stainless steel in contact with seawater, Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 4, pp. 454–459.
Kilimnik, A.B. and Gladysheva, N.V., Khimicheskoe soprotivlenie materialov i zashchita ot korrozii (Chemical Resistance of Materials and Protection against Corrosion), Tambov: Tambovsk. Gos. Tekh. Univ., 2008.
Krasovskii, P.V., Shibaev, S.S., and Grigorovich, K.V., Determination of oxygen presence forms in stainless steels by reduction melting method, Zavod. Lab.,Diagn. Mater., 2006, vol. 72, no. 6, pp. 10–16.
Kostyakov, N.S., Muminov, M.I., and Atrash, S.M., Radiatsionnaya elektroprovodnost’ (Radiation Electrical Conductivity), Moscow: Nauka, 2001.
Reformatskaya, I.I., Influence of the structure defining factors on the corrosion-electrochemical behavior of iron and stainless steel, Russ. J. Gen. Chem., 2009, vol. 79, no. 9, pp. 1955–1964. https://doi.org/10.1134/S1070363209090266
Pikaev, A.K., Dozimetriya v radiatsionnoi khimii (Dosimetry in Radiation Chemistry), Moscow: Nauka, 1975.
Elektricheskie izmereniya (Electrical Measurements), Fremke, A.V., Ed., Leningrad: Energiya, 1973.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Lotova
Rights and permissions
About this article
Cite this article
Agaev, T.N., Melikova, S.Z. & Tagiev, M.M. Formation of a Protective Oxide Coating on the Surface of Stainless Steel under Radiation-Oxidative Pretreatment with Gamma Quanta. Inorg. Mater. Appl. Res. 11, 619–622 (2020). https://doi.org/10.1134/S2075113320030028
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2075113320030028