Abstract
A biocompatible material characterized by gradient structure titanium nickelide–tantalum–biodegradable polymer layer was designed for the manufacture of medical implants. The mechanical characteristics of the material and components were studied. The structure and composition were determined by SEM and Auger electron spectroscopy. The formation of surface layers does not significantly affect the mechanical characteristics of the support; high adhesion between the layers and the support is observed.
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REFERENCES
Gyunter, V.E., Itin, V.I., Monasevich, L.A., et al., Effekty pamyati formy i ikh primenenie v meditsine (Shape Memory Effects and Their Application in Medicine), Novosibirsk: Nauka, 1992.
Gyunter, V.O., Khodorenko, V.N., Yasenchuk, Yu.F., and Chekalkin, T.L., Nikelid titana. Meditsinskii material novogo pokoleniya (Titanium Nickelide. Medical Material of New Generation), Tomsk: Nauchno-Issled. Inst. Med. Mater. Implantov Pamyat’yu Formy, 2006.
Petrini, L. and Migliavacca, F., Biomedical applications of shape memory alloys, J. Metall., 2011, vol. 2011, art. ID 501483.
Stoeckel, D., Nitinol medical devices and implants, Minimally Invasive Ther. Allied Technol., 2000, vol. 9, pp. 81–88.
Zabolotnyi, V.T., Kolmakov, A.G., Goncharenko, B.A., Sevost’yanov, M.A., Dolgushin, B.I., and Cherkasov, V.A., Development and production of new design of medical devices like cava filter from nanostructured nitinol, in Fundamental’nye nauki – meditsine. Tezisy dokladov na konferentsiyakh i seminarakh, provedennykh v ramkakh nauchnykh podprogramm v 2012 godu (Conference and Seminar Abstracts of Papers Performed within the Scientific Subprogram in 2012 “Fundamental Sciences for Medicine”), Moscow: Slovo, 2012.
Zabolotnyi, V.T., Kolmakov, A.G., Sevost’yanov, M.A., and Nasakina, E.O., Improvement of medical devices for endovascular operations, Integral, 2013, no. 4 (72), pp. 42–45.
Gu, Y.W., Tay, B.Y., Lim, C.S., Yong, M.S., Biomimetic deposition of apatite coating on surface-modified NiTi alloy, Biomaterials, 2005, vol. 26, no. 34, pp. 6916–6923.
Krupa, D., Baszkiewicz, J., Kozubowski, J.A., Barcz, A., Sobczak, J.W., Biliński, A., Lewandowska-Szumieł, M., and Rajchel, B., Effect of dual ion implantation of calcium and phosphorus on the properties of titanium, Biomaterials, 2005, vol. 26, no. 16, pp. 2847–2856.
Gnedenkov, S.V., Sharkeev, Yu.P., Sinebryukhov, S.L., Khrisanfova, O.A., Legostaeva, E.V., Puz’, A.V., and Khlusov, I.A., Functional coatings for implant materials, Tikhookean. Med. Zh., 2012, no. 1, pp. 12–19.
Surmenev, R.A., Ryabtseva, M.A., Shesterikov, E.V., Pichugin, V.F., Peitsch, T., and Epple, M., The release of nickel from nickel–titanium (NiTi) is strongly reduced by a sub-micrometer thin layer of calcium phosphate deposited by rf-magnetron sputtering, J. Mater. Sci.-Mater. Med., 2010, vol. 21, pp. 1233–1239.
Bazhin, P.M., Stolin, A.M., and Titov, N.V., Composite protective coatings based on TiC–W2C–Co obtained by electric arc surfacing using SHS-electrodes on the parts of agricultural machines, Kompoz. Nanostrukt., 2015, vol. 7, no. 4, pp. 2–9.
Li, P., Zhang, X., Xu, R., Wang, W., Liu, X., Yeung, K.W.K., and Chu, P.K., Electro-chemically deposited chitosan/Ag complex coatings on biomedical NiTi alloy for antibacterial application, Surf. Coat. Technol., 2013, vol. 232, pp. 370–375.
Stolin, A.M. and Bazhin, P.M., Manufacture of multipurpose composite and ceramic materials in the combustion regime and high-temperature deformation (SHS extrusion), Theor. Found. Chem. Eng., 2014, vol. 48, no. 6, pp. 751–763.
Cheng, Y., Cai, W., Li, H.T., and Zheng, Y.F., Surface modification of NiTi alloy with tantalum to improve its biocompatibility and radiopacity, J. Mater. Sci., 2006, vol. 41, pp. 4961–4964.
Zein El Abedin, S., Welz-Biermann, U., and Endres, F., A study on the electrodeposition of tantalum on NiTi alloy in an ionic liquid and corrosion behavior of the coated alloy, Electrochem. Commun., 2005, vol. 7, no. 9, pp. 941–946.
Nasakina, E.O., Baikin, A.S., Sergienko, K.V., Sevost’yanov, M.A., Kolmakov, A.G., Goncharenko, B.A., Zabolotnyi, V.T., Fadeev, R.S., Fadeeva, I.S., Gudkov, S.V., and Solntsev, K.A., Biocompatibility of nanostructured nitinol with titanium or tantalum surface composite layers formed by magnetron sputtering, Dokl. Chem., 2015, vol. 461, no. 1, pp. 86–88.
Pelton, A.R., Huang, G.H., Moine, P., and Sinclair, R., Effects of thermal cycling on microstructure and properties in nitinol, Mater. Sci. Eng., A, 2012, vol. 532, pp. 130–138.
Duerig, T.W., Melton, K.N., Wayman, C.M., and Stöckel, D., Engineering Aspects of Shape Memory Alloys, Oxford: Butterworth-Heinemann, 1990.
Fedotov, A.Yu., Sevost’yanov, M.A., Sergienko, K.V., Teterina, A.Yu., Tsvang, F.M., Egorov, A.A., Komlev, V.S., Kolmakov, A.G., and Barinov, S.M., Chitosan-based films with medicines, Inorg. Mater.: Appl. Res., 2014, vol. 5, no. 4, pp. 330–333.
Li, P., Zhang, X., Xu, R., Wang, W., Liu, X., Yeung, K.W.K., and Chu, P.K., Electrochemically deposited chitosan/Ag complex coatings on biomedical NiTi alloy for antibacterial application, Surf. Coat. Technol., 2013, vol. 232, pp. 370–375.
FUNDING
This work was supported by the Russian Foundation for Basic Research (project no. 15-33-70006 mol_a_mos); the investigations of the alloy were performed in terms of the RF Government task no. 007-00129-18-00.
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Nasakina, E.O., Kaplan, M.A., Sudarchikova, M.A. et al. Mechanical Properties of Titanium Nickelide–Tantalum–Chitosan Composite Material. Inorg. Mater. Appl. Res. 10, 818–821 (2019). https://doi.org/10.1134/S2075113319040270
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DOI: https://doi.org/10.1134/S2075113319040270