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Local Dissipative Relaxation Processes in a Latex Polymer at Negative Temperatures

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Abstract

Local dissipative processes of μ-relaxation that occur at negative temperatures in an acrylic latex polymer subjected to freeze–thaw pretreatment are investigated using dynamic mechanical spectroscopy. Temperature ranges in which these processes occur are identified by analyzing the derivatives of the temperature−frequency dependences. The maxima characterizing dissipative μ-relaxation processes, which reflect alterations in the relaxation structure of the polymer resulting from changes in the polymer’s loss modulus, are detected.

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REFERENCES

  1. Eliseeva, V.I. and Aslamazova, T.R., Usp. Khim., 1991, vol. 60, no. 2, p. 398.

    Article  Google Scholar 

  2. Aslamazova, T.R., Prog. Org. Coat., 1995, vol. 25, no. 2, p. 109.

    Article  Google Scholar 

  3. Aslamazova, T.R., Zolotarevskii, V.I., Kotenev, V.A., Lomovskaya, N.Yu., Lomovskoi, V.A., and Tsiva-dze, A.Yu., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, no. 6, p. 1081.

    Article  Google Scholar 

  4. Aslamazova, T.R., Kotenev, V.A., Lomovskaya, N.Yu., Lomovskoi, V.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2016, vol. 52, no. 6, p. 1012.

    Article  Google Scholar 

  5. Aslamazova, T.R., Kotenev, V.A., Lomovskaya, N.Yu., Lomovskoi, V.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 5, p. 620.

    Article  Google Scholar 

  6. Aslamazova, T.R., Averin, A.A., Zolotarevskii, V.I., Lomovskaya, N.Yu., Lomovskoi, V.A., Kotenev, V.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, no. 3, p. 437.

    Article  Google Scholar 

  7. Aslamazova, T.R., Zolotarevskii, V.I., Lomovskaya, N.Yu., Lomovskoi, V.A., Kotenev, V.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, no. 1, p. 85.

    Article  Google Scholar 

  8. Aslamazova, T.R., Zolotarevskii, V.I., Kotenev, V.A., Lomovskaya, N.Yu., Lomovskoi, V.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, no. 2, p. 259.

    Article  Google Scholar 

  9. Lomovskoi, V.A., Glass Phys. Chem., 2000, vol. 26, no. 2, p. 113.

    Google Scholar 

  10. Lomovskoi, V.A., Inorg. Mater., 1999, vol. 35, no. 9, p. 957.

    Google Scholar 

  11. Bartenev, G.M., Struktura i relaksatsionnye svoistva elastomerov (Structure and Relaxation Behavior of Elastomers), Moscow: Khimiya, 1979.

  12. Tager, A.A., Fizikokhimiya polimerov (Physical Chemistry of Polymers), Moscow: Nauchnyi Mir, 2007.

  13. Lomovskoi, V.A., Abaturova, N.A., Lomovskaya, N.Yu., Galushko, T.B., Khlebnikova, O.A., and Kiselev, M.R., Materialovedenie, 2010, no. 1, p. 29.

  14. Valishin, A.A., Gorshkov, A.A., and Lomovskoy, V.A., Mech. Solids (Engl. Transl.), 2011, vol. 46, no. 2, p. 299.

  15. Lomovskoi, V.A., Materialovedenie, 2007, no. 2, p. 119.

  16. Bartenev, G.M., Lomovskoi, V.A., Ovchinnikov, Yu.V., Karandashova, N.Yu., and Tulikova, V.V., Vysokomol. Soedin., Ser. A, 1992, vol. 35, no. 10, p. 1659.

    Google Scholar 

  17. Lomovskoi, V.A., Neorg. Mater., 1995, vol. 31, no. 3, p. 291.

    Google Scholar 

  18. Eliseeva, V.I., Aslamazova, T.R., Rabinovich, Ya.I., and Movchan, T.G., Kolloidn. Zh., 1991, vol. 53, no. 1, p. 24.

    Google Scholar 

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Correspondence to T. R. Aslamazova.

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Translated by A. Kukharuk

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Aslamazova, T.R., Lomovskoi, V.A., Kotenev, V.A. et al. Local Dissipative Relaxation Processes in a Latex Polymer at Negative Temperatures. Prot Met Phys Chem Surf 55, 487–490 (2019). https://doi.org/10.1134/S2070205119030055

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  • DOI: https://doi.org/10.1134/S2070205119030055

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