Abstract
This study deals with the application of orange peels powder (OPP) for Cr(VI) adsorption from aqueous solutions at room temperature. The OPP was prepared and then characterized by FTIR and SEM for various functional groups and surface morphology, respectively. The powder surface contains different functional groups necessary for adsorption. The powder was of highly porous nature which is a prerequisite for sorption. The variation of adsorption efficiency of the adsorbent with different influencing parameters like pH of solution, contact time, adsorbate concentration and adsorbent dose was studied. The maximum adsorption was achieved at interaction time of 50 min and pH 7 of solution. The data obtained at equilibrium best fitted into Langmuir adsorption isotherm as compared to Freundlich adsorption isotherm. The maximum value of monolayer adsorption capacity was 4.69 mg g–1. The Langmuir separation factor “r” was from 0.193 to 0.0383 for all the initial concentrations suggested favorable adsorption of Cr(VI) on OPP. The adsorption process was found to occur via pseudo-second order equation as revealed from kinetic studies.
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REFERENCES
Kurniawan, T.A., Chan, G.Y.S., Lo, W., and Babel, S., Sci. Total Environ., 2006, vol. 366, p. 409.
Michalak, I., Wołowiec, P., and Chojnacka, K., Environ. Monit. Assess., 2014, vol. 186, p. 2259.
Baruthio, F., Biol. Trace Elem. Res., 1992, vol. 32, p. 145.
Godt, J., Scheidig, F., Grosse-Siestrup, C., Esche, V., Brandenburg, P., Reich, A., and Groneberg, D.A., J. Occup. Med. Toxicol., 2006, vol. 1, p. 22.
Fendorf, S., Michael, H.A., and Geen, A.V., Science, 2010, vol. 328, p. 1123.
McCarty, K.M., Hanh, H.T., and Kim, K.W., Rev. Environ. Health, 2011, vol. 26, p. 71.
He, B., Yun, Z.J., Shi, J.B., and Jiang, G.B., Chin. Sci. Bull., 2013, vol. 58, p. 134.
Florea, A.M. and Busselberg, D., Biometals, 2006, vol. 19, p. 419.
Jaishankar, M., Tseten, T., Anbalagan, N., Mathew, B.B., and Beeregowda, K.N., Interdiscip. Toxicol., 2014, vol. 7, p. 60.
Solenkova, N.V., Newman, J.D., Berger, J.S., Thurston, G., Hochman, J.S., and Lamas, G.A., Am. Heart J., 2014, vol. 168, p. 812.
Vaishaly, A.G., Mathew, B.B., and Krishnamurthy, N.B., Int. J. Adv. Sci. Res., 2015, vol. 1, p. 60.
Sha, L., Xue-yi, G., Chuan, F.N., and Hua, T.Q., Trans. Nonferrous Met. Soc. China, 2010, vol. 20, p. 187.
Aman, T., Kazi, A.A., Sabri, M.U., Bano, Q., Sabri, M.U., and Bano, Q., Colloids Surf., B, 2008, vol. 63, p. 116.
Liang, S., Guo, X., Feng, N., and Tian, F.Q., J. Hazard. Mater., 2009, vol. 170, p. 425.
Volesky, B., Hydrometallurgy, 2001, vol. 59, p. 203.
Argun, M.E., Dursun, S., Ozdemir, C., and Karatas, M., J. Hazard. Mater., 2007, vol. 141, p. 77.
Demirbas, E., Kobya, M., Senturk, E., and Ozkan, T., Water SA, 2004, vol. 30, p. 533.
Huang, M.R., Peng, Q.Y., and Li, X.G., Chem. Eur. J., 2006, vol. 12, p. 4341.
Mehrasbi, M.R., Farahmandkia, Z., Taghibeigloo, B., and Taromi, A., Water, Air, Soil Pollut., 2009, vol. 199, p. 343.
Park, H.J., Jeong, S.W., Yang, J.K., Kim, B.G., and Lee, S.M., J. Environ. Sci., 2007, vol. 19, p. 1436.
Biswas, B.K., Inoue, K., Ghimire, K.N., Ohta, S., Harada, H., Ohto, K., and Kawakita, H., J. Colloid Interface Sci., 2007, vol. 312, p. 214.
Marín, A.B.P., Zapata, V.M., Ortuno, J.F., Aguilar, M., Saez, J., and Llorens, M., J. Hazard. Mater., 2007, vol. 139, p. 122.
Lasheen, M.R., Ammar, N.S., and Ibrahim, H.S., Solid State Sci., 2012, vol. 14, p. 202.
Tran, H.N., Youb, S.J., and Chao, H.P., J. Environ. Chem. Eng., 2016, vol. 4, p. 2671.
Annadural, G., Juang, R.S., and Lee, D.J., Water Sci. Technol., 2003, vol. 47, p. 185.
Crini, G., Peindy, H.N., Gimbert, F., and Robert, C., Sep. Purif. Technol., 2007, vol. 53, p. 97.
Lai, Y.L., Thirumavalavan, M., and Lee, J.F., Toxicol. Environ. Chem., 2010, vol. 92, p. 697.
Zapata, B., Balmased, J., Fregoso-Israel, E., and Torres-Garc, E., J. Therm. Anal. Calorim., 2009, vol. 98, p. 309.
Kalidhasan, S., Gupta, P.A., Cholleti, V.R., Kumar, A.S.K., Rajesh, V., and Rajesh, N., J. Colloid Interface Sci., 2012, vol. 372, p. 88.
Dana, E., Microporous Mesoporous Mater., 2017, vol. 247, p. 145.
Munusamy, T., Ling, L.Y., Chu, L.L., and Fwu, L.J., J. Chem. Eng. Data, 2010, vol. 55, p. 1186.
Goyal, M., Rattan, V.K., Aggarwal, D., and Bansal, R.C., Colloids Surf., A, 2001, vol. 190, p. 229.
Reddy, D.H.K., Lee, S.M., and Seshaiah, K., Environ. Eng. Res., 2012, vol. 17, p. 125.
Nemr, A.E., Chem. Ecol., 2007, vol. 23, p. 409.
Gaya, U.I., Otene, E.L., and Abdullah, A.H., SpringerPlus, 2015, vol. 4, p. 458.
Gupta, V.K., Mittal, A., Malviya, A., and Mittal, J., J. Colloid Interface Sci., 2009, vol. 335, p. 24.
Sen, T.K., Mohammod, M., Maitra, S., Dutta, B.K., Mohammod, M., Maitra, S., and Dutta, B.K., Clean: Soil, Air, Water, 2010, vol. 38, p. 850.
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Khan Malook, Ihsan-ul-Haque Investigation of Aqueous Cr(VI) Adsorption Characteristics of Orange Peels Powder. Prot Met Phys Chem Surf 55, 34–40 (2019). https://doi.org/10.1134/S2070205119010155
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DOI: https://doi.org/10.1134/S2070205119010155