Skip to main content
SpringerLink
Log in

Poly[N,N'-bis(3-silsesquioxanyl propyl)thiocarbamide]/Poly-2-methyl-5-vinylpyridine Composite for Extraction of Platinum(IV)

  • NEW SUBSTANCES, MATERIALS, AND COATINGS
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

A new composite adsorbent was obtained by hydrolytic polycondensation of N,N'-bis(3-triethoxysilyl propyl)thiocarbamide in the presence of poly-2-methyl-5-vinylpyridine. The sorption activity of the composite toward platinum(IV) ions was studied in hydrochloric acid solutions. The maximum extraction efficiency of Pt (IV) and the maximum values of sorptive capacity (218 mg g–1) and coefficient of interphase distribution (7090 cm3 g–1) of the studied adsorbent in 1 М solution of HCl were found at 338 K. The Langmuir, Freundlich, and Dubinin–Radushkevich models were used to describe adsorption nature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.

Similar content being viewed by others

REFERENCES

  1. Blokhin, A.A., Abovskii, N.D., Murashkin, Yu.V., et al., Sorbtsionnye Khromatogr. Protsessy, 2004, vol. 4, pp. 40–49.

    Google Scholar 

  2. Abovskii, N.D., Blokhin, A.A., and Murashkin, Yu.V., J. Appl. Chem., 2007, vol. 80, no. 7, pp. 1063–1067.

    Google Scholar 

  3. Neudachina, L.K., Golub, A.Ya., Yatluk, Yu.G., et al., Inorg. Mater., 2011, vol. 47, no. 4, pp. 435–442.

    Article  Google Scholar 

  4. Pavlova, L.A., Davankov, V.A., and Lependina, O.L., Sorbtsionnye Khromatogr. Protsessy, 2014, vol. 14, no. 1, pp. 75–85.

    Google Scholar 

  5. Lebedeva, O.V., Sipkina, E.I., and Pozhidaev, Yu.N., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, no. 1, pp. 80–84.

    Article  Google Scholar 

  6. Sipkina, E.I., Lebedeva, O.V., Pozhidaev, Yu.N., et al., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, no. 4, pp. 657–662.

    Article  Google Scholar 

  7. Sipkina, E.I., Izv. VUZov, Prikl. Khim. Biotekhnol., 2015, no. 4 (15), pp. 7–19.

  8. Lebedeva, O.V., Chernigovskaya, M.A., Sipkina, E.I., et al., Prot. Met. Phys. Chem. Surf., 2016, vol. 52, no. 2, pp. 218–222.

    Article  Google Scholar 

  9. Nuryono, N., Indriyanti, N.Y., Manuhutu, J.B., et al., Malays. J. Anal. Sci., 2013, vol. 17, no. 2, pp. 244–254.

    Google Scholar 

  10. Lin, T.-L. and Lien, H.-L., Int. J. Mol. Sci., 2013, vol. 14, no. 5, pp. 9834–9847.

    Article  Google Scholar 

  11. Pozhidaev, Yu.N., Shaglaeva, N.S., Lebedeva, O.V., et al., Russ. J. Appl. Chem., 2007, vol. 80, no. 8, pp. 1384–1387.

    Article  Google Scholar 

  12. Voronkov, M.G., Vlasova, N.N., and Pestunovich, A.E., Russ. J. Gen. Chem., 1998, vol. 68, no. 5, pp. 770–774.

    Google Scholar 

  13. Langmuir, I., J. Am. Chem. Soc., 1916, vol. 38, p. 2221.

    Article  Google Scholar 

  14. Freundlich, H.M.F., J. Phys. Chem. A, 1906, vol. 57, p. 385.

    Google Scholar 

  15. Dubinin, M.M. and Radushkevich, L.V., Proc. Acad. Sci. USSR, Phys. Chem. Sect., 1947, vol. 55, p. 331.

    Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was financially supported in the framework of a state order for universities and scientific institutions, project no. 10.5737.2017/6.7.

Author information

Authors and Affiliations

  1. Irkutsk National Research Technical University, 664074, Irkutsk, Russia

    O. V. Lebedeva, E. I. Sipkina, S. S. Bochkareva & Yu. N. Pozhidaev

Authors
  1. O. V. Lebedeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. I. Sipkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. S. Bochkareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. N. Pozhidaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. V. Lebedeva.

Additional information

Translated by P. Vlasov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lebedeva, O.V., Sipkina, E.I., Bochkareva, S.S. et al. Poly[N,N'-bis(3-silsesquioxanyl propyl)thiocarbamide]/Poly-2-methyl-5-vinylpyridine Composite for Extraction of Platinum(IV). Prot Met Phys Chem Surf 55, 89–94 (2019). https://doi.org/10.1134/S2070205119010131

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205119010131

Search

Navigation