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Hydrogen (H2) Adsorption in Model Carbon Adsorbents with Slitlike Micropores

  • Physicochemical Processes at the Interfaces
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Abstract

The Dubinin theory of volume filling of micropores and the linearity of adsorption isosteres were used to calculate the adsorption of hydrogen on model microporous adsorbents with slitlike pores. In calculating, the model adsorbents were considered the micropores of which were formed through a progressive removal of one, two, and so on to seven layers of hexagonal carbon in a graphite crystalline structure, while the micropore sizes varied within a range from 0.5 to 2.5 nm. The integral energy of adsorption was evaluated for the model structures and most of industrial carbon adsorbents. The obtained results were compared with experimental data. Dependences of the gravimetric density of hydrogen on temperature and pressure were analyzed.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    V. Yu. Yakovlev, A. V. Shkolin, A. A. Fomkin & I. E. Men’shchikov

  2. Nuclear Safety Institute, Russian Academy of Science, Moscow, Russia

    V. Yu. Yakovlev

  3. LLC AKELA-N, Khimki, Russia

    A. V. Shkolin

Authors
  1. V. Yu. Yakovlev
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  2. A. V. Shkolin
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  3. A. A. Fomkin
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  4. I. E. Men’shchikov
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Correspondence to V. Yu. Yakovlev.

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Original Russian Text © V.Yu. Yakovlev, A.V. Shkolin, A.A. Fomkin, I.E. Men’shchikov, 2018, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2018, Vol. 54, No. 5, pp. 420–428.

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Yakovlev, V.Y., Shkolin, A.V., Fomkin, A.A. et al. Hydrogen (H2) Adsorption in Model Carbon Adsorbents with Slitlike Micropores. Prot Met Phys Chem Surf 54, 754–762 (2018). https://doi.org/10.1134/S2070205118050234

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  • DOI: https://doi.org/10.1134/S2070205118050234

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