Skip to main content
Log in

Relaxation behavior of latex polymers modified by water-soluble dyes. Negative temperature range

Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The effect of a water-soluble blue indanthrene-type dye on the relaxation structure of styrene–acryl latex with the glass transition point of ≤5°C is studied using the method of dynamic mechanical relaxation spectroscopy. Variation of intensity of the maximum of α-relaxation dissipation losses in the latex polymer is observed, same as its relationship to the mechanism of modification of the polymer film by a dye. Special attention is paid to relaxation effects in the negative temperature range.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. RSC Nanoscience & Nanotechnology, book 16: Polymer Nanocomposites by Emulsion and Suspension Polymerization, Mittal, V., Ed., Cambridge: Royal Society of Chemistry, 2011.

  2. Tsivadze, A.Yu., Kotenev, V.A., Aslamazova, T.R., et al., Materialy ?III Vserossiiskogo Simpoziuma “Aktual’nye problemy teorii adsorbtsii, poristosti i adsorbtsionnoi selektivnosti” s uchastiem inostrannykh uchenykh (Proc. 13th All-Russian Symp. “Topical Problems on Theory of Adsorption, Porosity and Adsorptive Selectivity” with International Participation), Moscow–Klyazma, Apr. 20–24, 2009, p. 159.

    Google Scholar 

  3. Kotenev, V.A., Tyurin, D.N., Tsivadze, A.Yu., et al., Prot. Met. Phys. Chem. Surf., 2009, vol. 45, no. 5, p. 616.

    Article  Google Scholar 

  4. Grishina, A.D., Gorbunova, Yu.G., Krivenko, T.V., Lapkina, L.A., Savel’ev, V.V., Vannikov, A.V., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 4, p. 472.

    Article  Google Scholar 

  5. Omelchenko, O.D., Gribkova, O.L., Tameev, A.R., Novikov, S.V., and Vannikov, A.V., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 5, p. 613.

    Article  Google Scholar 

  6. Voloshina, N.S. and Kamalov, G.L., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 5, p. 587.

    Article  Google Scholar 

  7. Chernyad’ev, A.Yu., Kotenev, V.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 6, p. 964.

    Article  Google Scholar 

  8. Aslamazova, T.R., Kotenev, V.A., Sokolova, N.P., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 4, p. 747.

    Article  Google Scholar 

  9. Aslamazova, T.R., Kotenev, V.A., Zolotarevskii, V.I., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2011, vol. 47, no. 5, p. 572.

    Article  Google Scholar 

  10. Aslamazova, T.R., Kotenev, V.A., Shiryaev, A.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 3, p. 280.

    Article  Google Scholar 

  11. Aslamazova, T.R., Kotenev, V.A., Plachev, Yu.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2012, vol. 48, no. 6, p. 627.

    Article  Google Scholar 

  12. Aslamazova, T.R., Lomovskoi, V.A., and Tsivadze, A.Yu., Materialovedenie, 2012, no. 10, p. 15.

    Google Scholar 

  13. Aslamazova, T.R., Lomovskoi, V.A., and Tsivadze, A.Yu., Polym. Sci., Ser. A, 2013, vol. 55, no. 12, p. 729.

    Article  Google Scholar 

  14. Aslamazova, T.R., Kotenev, V.A., Lomovskaya, N.Yu., et al., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 5, p. 620.

    Article  Google Scholar 

  15. Aslamazova, T.R., Kotenev, V.A., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 4, p. 540.

    Article  Google Scholar 

  16. Terenin, A.N., Fotokhimiya krasitelei (Photochemistry of Coloring Agents), Moscow: Akad. Nauk SSSR, 1947.

    Google Scholar 

  17. Vavilov, N.I., Izv. Akad. Nauk SSSR, 1945, vol. 9, p. 283.

    Google Scholar 

  18. Bartenev, G.M., Struktura i relaksatsionnye svoistva elastomerov (Structure and Relaxation Properties of Elastomers), Moscow: Khimiya, 1979.

    Google Scholar 

  19. Tager, A.A., Fizikokhimiya polimerov (Physical Chemistry of Polymers), Moscow: Nauchn. Mir, 2007.

    Google Scholar 

  20. Lomovskoi, V.A., Abaturova, N.A., and Lomovskaya, N.Yu., Materialovedenie, 2010, no. 1, p. 29.

    Google Scholar 

  21. Valishin, A.A., Gorshkov, A.A., and Lomovskoy, V.A., Mech. Solids, 2011, vol. 46, no. 2, p. 299.

    Article  Google Scholar 

  22. Eliseeva, V.I., Emul’sionnaya polimerizatsiya i ee primenenie v promyshlennosti (Emulsion Polymerization and its Application in Industry), Moscow: Khimiya, 1976.

    Google Scholar 

  23. Eliseeva, V.I., Polimernye dispersii (Polymeric Dispersions), Moscow: Khimiya, 1980.

    Google Scholar 

  24. Erkova, L.N. and Chechik, O.S., Lateksy (Latices), Leningrad: Khimiya, 1983.

    Google Scholar 

  25. Petrukhin, A.A., Neorg. Mater.,1999, vol. 35, p. 1125.

    Google Scholar 

  26. Gorshkov, A.A., Lomovskoi, V.A., and Fomkina, Z.I., Vestn. Mosk. Gos. Univ. Tonk. Khim. Tekhnol. im. M.V. Lomonosova, 2008, vol. 3, no. 5, p. 62.

    Google Scholar 

  27. Gorshkov, A.A. and Lomovskoi, V.A., Mech. Solids, 2009, vol. 44, no. 4, p. 649.

    Article  Google Scholar 

  28. Lomovskoi, V.A., Polym. Sci., Ser. A, 1998, vol. 40, no. 10, p. 1005.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. R. Aslamazova.

Additional information

Original Russian Text © T.R. Aslamazova, V.A. Kotenev, N.Yu. Lomovskaya, V.A. Lomovskoi, A.Yu. Tsivadze, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 6, pp. 621–627.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aslamazova, T.R., Kotenev, V.A., Lomovskaya, N.Y. et al. Relaxation behavior of latex polymers modified by water-soluble dyes. Negative temperature range. Prot Met Phys Chem Surf 52, 1012–1018 (2016). https://doi.org/10.1134/S2070205116060071

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205116060071

Navigation