Skip to main content
Log in

Cyclic polarization analysis of corrosion behavior of ceramic coating on 6061 Al/SiCp composite for marine applications

  • New Substances, Materials, and Coatings
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The study on the corrosion behavior of the composite and evaluation of surface modification technique are of importance since the addition of reinforcement particles affects the continuity of inherent oxide layer on the matrix and hence its corrosion resistance. The present study deals with the investigations of effect of ceramic coating on the corrosion behavior of 6061 Al/SiCP (20 volume % reinforcement) composite in 3.5 M NaCl solution at high temperatures namely 30 and 40°C using potentiodynamic polarization technique and cyclic polarization plots. Aluminum coating by magnetron sputtering technique is employed on the composite and it is subjected to heat treatment at 200°C for duration of 2 h for the alumina formation. The alumina coating formed on the composite surface acts as corrosion protective coating. The potentiodynamic polarization technique is used to determine the corrosion rate of the composite specimen with and without ceramic coating in the corrosion media. The cyclic polarization technique is used to study the pitting behavior of the composite with and without ceramic coating. The microstructural analysis is carried out using scanning electron microscopy (SEM). X-RD analysis shows the amorphous nature of Alumina coating obtained on the composite. The results show that the peak aged composite is more prone to corrosion among the aged group of composites but when coated with alumina shows a vast improvement in pitting nucleation resistance even at high temperatures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Monticelli, C., Zucchi, F., Brunoro, G., and Trabanelli, G., J. Appl. Electrochem., 1997, vol. 27, p. 325.

    Article  Google Scholar 

  2. Pardo, A., Merino, M.C., Merino, S., Veijo, F., Carboneras, M., and Arrabal, R., Corros. Sci., 2005, vol. 47, p. 1750.

    Article  Google Scholar 

  3. Pardo, A., Merino, M.C., Merino, S., Lopez, M., Veijo, F., and Carboneras, M., Mater. Corros. 2003, vol. 54, p. 311.

    Article  Google Scholar 

  4. Da Costa, C.E., Velasco, F., and Toralba, J.M., Rev. Metal. (Madrid, Spain), 2000, vol. 36, p. 179.

    Article  Google Scholar 

  5. Rohtogi, P.K., JOM, 1991, vol. 43, no. 4, p. 10.

    Article  Google Scholar 

  6. Rudnev, V.S., Karimova, S.A., Yarovaya, T.P., Nedozorov, P.M., and Abuzin, Yu.A., Prot. Met. Phys. Chem. Surf., 2009, vol. 45, pp. 730–734.

    Article  Google Scholar 

  7. Kiourtsidis, G.E. and Skolianos, S.M., Corros. Sci., 2007, vol. 49, pp. 2711–2725.

    Article  Google Scholar 

  8. Fontana, M.G., in Metallic Composite, Corrosion Engineering, New York: McGraw-Hill, 1987, pp. 256–259.

    Google Scholar 

  9. Fontana, M.G. and Greene, N.D., Corrosion Engineering, New York McGraw-Hill, 1982.

    Google Scholar 

  10. Chen, C. and Mansfeld, F., Corros. Sci., 1997, vol. 39, no. 6, pp. 1075–1082.

    Article  Google Scholar 

  11. Kossowsky, R., Surface Modeling Engineering, Boca Raton: CRC Press, 1989, vol. 1.

  12. Jaswal, A.K., Singh, V., and Bhambak, S.R., J. Indian Geophys. Union, 2012, vol. 16, no. 2, pp. 41–53.

    Google Scholar 

  13. Baboian, R., Corrosion Tests and Standards: Application and Interpretation, ASTM Int., 2005.

    Book  Google Scholar 

  14. Shimizu, Y., Nishimura, T., and Matsushima, I., Mater. Sci. Eng.: A, 1995, vol. 198, pp. 113–118.

    Article  Google Scholar 

  15. Aylor, D.M. and Moran, P.J., J. Electrochem. Soc., 1985, vol. 132, p. 1277.

    Article  Google Scholar 

  16. Metal Matrix Composites. Mechanism and Properties, Everett, R.K. and Arsenault, R.J., Eds., New York: Academic Press, 1991, p. 79.

  17. Jafarzadeh, K., Shahrabi, T., Hadavi, S.M., and Hosseini, M.G., J. Mater. Sci. Technol., 2007, vol. 23, no. 5, p. 623.

    Google Scholar 

  18. Yerokhin, A.L., Shatrov, A., Samsonov, V., Shashkov, P., Pilkington, A., Leyland, A., and Matthews, A., Surf. Coat. Technol., 2005, vol. 199, pp. 150–157.

    Article  Google Scholar 

  19. Snizhko, L.O., Yerokhin, A.L., Pilkington, A., Gurevina, N.L., Misnyankin, D.O., Leyland, A., and Matthews, A., Electrochimica Acta, 2004, vol. 49, pp. 2085–2095.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jabril A. Khamaj.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khamaj, J.A. Cyclic polarization analysis of corrosion behavior of ceramic coating on 6061 Al/SiCp composite for marine applications. Prot Met Phys Chem Surf 52, 886–893 (2016). https://doi.org/10.1134/S2070205116050117

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205116050117

Navigation