Advertisement

A nonlinear relation between adsorption enthalpy and a chromatographic retention index

  • A. M. Dolgonosov
Physicochemical Processes at the Interfaces

Abstract

A simple ab initio analytical expression connecting adsorption energy and a Kováts index is deduced on the basis of the theory of generalized charges.

Keywords

Versus Versus Versus Generalize Charge Adsorption Enthalpy Henry Constant Methylcyclopentane 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Dolgonosov, A.M., Model’ elektronnogo gaza i teoretiya obobshchennykh zaryadov dlya opisaniya mezhatomnykh vzaimodeistvii i adsorbtsii (The Model of the Electron Gas and the Theory of Generalized Charges for Description the Interatomic Interactions and Adsorption), Moscow: Librokom, 2009.Google Scholar
  2. 2.
    Dolgonosov, A.M., Nespetsificheskaya selektivnost’ v probleme modelirovaniya vysokoeffektivnoi khromatografii (Nonspecific Selectivity in Modeling of High-Performance Chromatography), Moscow: Krasand, 2012.Google Scholar
  3. 3.
    Dolgonosov, A.M., Rudakov, O.B., Surovtsev, I.S., et al., Kolonochnaya analiticheskaya khromatografiya kak ob”ekt matematicheskogo modelirovaniya (Column Analytical Chromatography as the Object of Mathematical Modeling), Voronezh: Inst. Geokhim. Anal. Khim., Ross. Akad. Nauk, 2013.Google Scholar
  4. 4.
    Dolgonosov, A.M., Russ. J. Phys. Chem. A, 2001, vol. 75, no. 10, p. 1659.Google Scholar
  5. 5.
    Dolgonosov, A.M., Russ. J. Phys. Chem. A, 2002, vol. 76, no. 6, p. 993.Google Scholar
  6. 6.
    Dolgonosov, A.M., Russ. J. Inorg. Chem., 2015, vol. 60, no. 2, p 194.CrossRefGoogle Scholar
  7. 7.
    Dolgonosov, A.M., Russ. J. Phys. Chem. A, 2002, vol. 76, no. 12, p. 2015.Google Scholar
  8. 8.
    Dolgonosov, A.M. and Prudkovskii, A.G., Russ. J. Phys. Chem. A, 2008, vol. 82, no. 5, p. 812.CrossRefGoogle Scholar
  9. 9.
    Dolgonosov, A.M., Dokl. Chem., 2001, vol. 377, nos. 4–6, p. 89.CrossRefGoogle Scholar
  10. 10.
    Dolgonosov, A.M., Zh. Fiz. Khim., 1994, vol. 68, p. 2187.Google Scholar
  11. 11.
    ChemOffice, CambridgeSoft. http://www.cambridgesoft.com/Google Scholar
  12. 12.
    Dolgonosov, A.M., J. Phys. Chem. B, 1998, vol. 102, p. 4715.CrossRefGoogle Scholar
  13. 13.
    Avgul’, N.N., Kiselev, A.V., and Poshkus, D.P., Adsorbtsiya gazov i parov na odnorodnykh poverkhnostyakh (Adsorption of Gases and Vapors on Homogeneous Surfaces), Moscow: Khimiya, 1975.Google Scholar
  14. 14.
    Bogoslovskii, Yu.N., Anvaer, B.I., and Vigdergauz, M.S., Khromatograficheskie postoyannye v gazovoi khromatografii (Chromatographic Constants in Gas Chromatography), Moscow: Izd. Standartov, 1978.Google Scholar
  15. 15.
    Guan, Y., Kiraly, J., and Rijks, J., J. Chromatogr., 1989, vol. 472, p. 129.CrossRefGoogle Scholar
  16. 16.
    Dolgonosov, A.M. and Prudkovskii, A.G., Russ. J. Phys. Chem. A, 2006, vol. 80, no. 6, p. 964.CrossRefGoogle Scholar
  17. 17.
    Dolgonosov, A.M. and Zaitseva, E.A., Sorbtsionnye Khromatogr. Protsessy, 2014, vol. 14, no. 4, p. 578.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  1. 1.Vernadsky Institute of Geochemistry and Analytical ChemistryRussian Academy of SciencesMoscowRussia

Personalised recommendations