Abstract
The surface tensions of solutions of sodium chloride in water and aqueous solutions of dimethylformamide (DMF) were measured in the range of solute concentrations of up to 1 mol/kg at 298 and 303 K. It was found that the concentration dependence of the surface tension of the electrolyte solution has an extreme character regardless of the solvent nature. The dependences obtained are discussed from the standpoint of the effect of solute solvation processes on the adsorption, the composition of surface layers, and the surface activity of a solution.
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Fedorova, A.A. and Ulitin, M.V., Russ. J. Phys. Chem. A, 2009, vol. 83, no. 1, pp. 98–102.
Fedorova, A.A. and Ulitin, M.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2007, vol. 50, no. 12, p. 37.
Randles, J.E.B. and Schiffrin, D.J., Trans. Faraday Soc., 1966, vol. 62, p. 2403.
Adamson, A., The Physical Chemistry of Surfaces, New York: Wiley, 1967, 2nd ed.
Spravochnik khimika (Handbook of Chemist), Nikol’skii, B.P., Ed., Leningrad: Khimiya, 1965, vol. 2, pp. 88, 146, 242.
Rabinovich, V.A., Termodinamicheskaya aktivnost’ ionov v rastvorakh elektrolitov (Thermodynamic Activity of Ions in Electrolytic Solutions), Leningrad: Khimiya, 1985.
Lopatkin, A.A., Teoreticheskie osnovy fizichekoi adsorbtsii (Theoretical Principles of Physical Absorption), Moscow: Mosk. Gos. Univ., 1983, p. 75.
Krestov, G.A., Termodinamika ionnykh protsessov v rastvorakh (Thermodynamics of Ionic Processes in Solutions), Moscow: Khimiya, 1984, p. 94.
Dubinin, M.M., Dokl. Akad. Nauk SSSR, 1952, vol. 84, p. 539.
Nosach, V.V., Reshenie zadach approksimatsii s pomoshch’yu personal’nykh komp’yuterov (Computing Approximation Task Solution), Moscow: Mikap, 1994, p. 236.
Absorption from Solution at the Solid Liquid Interface, Parfitt, G.D. and Rochester, C.H., Eds., Orlando: Academic, 1983.
Krestov, G.A., Novoselov, N.O., Perelygin, I.S., et al., Ionnaya sol’vatatsiya (Ionic Solvation), Moscow: Nauka, 1987.
Mishustin, A.I. and Kessler, Yu.M., J. Struct. Chem., 1974, vol. 15, no. 2, pp. 191–194.
Kessler, Yu.M., Mishustin, A.I., Yastremskii, P.S., Verstakov, E.S., and Emelin, V.P., J. Struct. Chem., 1975, vol. 16, no. 1, pp. 113–114.
Pukhovskii, Yu.P., Sakharov, D.V., and Safonova, L.P., J. Struct. Chem., 2002, vol. 43, no. 2, pp. 284–292.
Finter, C.K. and Hertz, H.G., J. Chim. Phys. Phys. Chim. Biol., 1988, vol. 85, p. 589.
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Original Russian Text © A.A. Fedorova, T.Yu. Osadchaya, 2015, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2015, Vol. 51, No. 3, pp. 258–262.
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Fedorova, A.A., Osadchaya, T.Y. Surface activity of sodium chloride in aqueous solutions of dimethylformamide. Prot Met Phys Chem Surf 51, 366–370 (2015). https://doi.org/10.1134/S2070205115030065
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DOI: https://doi.org/10.1134/S2070205115030065