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Some features of hydrogen evolution reaction on iron with surfactant on the example of o-fluorophenylbiguanidine

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Abstract

It has been shown that, when there is o-fluorophenylbiguanidine (o-FPBG) and its concentration increases (from 0.5 to 40 mM), the change of the nature of slow step of hydrogen evolution on iron is observed in the following order: slow discharge → limiting chemical recombination → slow lateral diffusion → limiting discharge. This series is in sufficient correlation with the experimental adsorption isotherm of o-FPBG on iron.

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Correspondence to V. I. Vigdorovich.

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Original Russian Text © V.I. Vigdorovich, L.E. Tsygankova, D.V. Balybin, O.Yu. Kuzina, 2013, published in Korroziya: Materialy, Zashchita, 2013, No. 9, pp. 30–35.

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Vigdorovich, V.I., Tsygankova, L.E., Balybin, D.V. et al. Some features of hydrogen evolution reaction on iron with surfactant on the example of o-fluorophenylbiguanidine. Prot Met Phys Chem Surf 50, 870–874 (2014). https://doi.org/10.1134/S207020511407017X

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  • DOI: https://doi.org/10.1134/S207020511407017X

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