Abstract
It has been shown that, when there is o-fluorophenylbiguanidine (o-FPBG) and its concentration increases (from 0.5 to 40 mM), the change of the nature of slow step of hydrogen evolution on iron is observed in the following order: slow discharge → limiting chemical recombination → slow lateral diffusion → limiting discharge. This series is in sufficient correlation with the experimental adsorption isotherm of o-FPBG on iron.
Similar content being viewed by others
References
Vigdorovich, V.I., D’yachkova, T.P., Pupkova, O.L., and Tsygankova, L.E., Russ. J. Electrochem., 2001, vol. 37, p. 1249.
Tsygankova, L.E., Vigdorovich, V.I., and Vigdorovich, M.V., Electroanalytical Chemistry Research Developments, Yiang, P.N., Ed., New York: Nova, 2006, pp. 135–182.
Vigdorovich, V.I. and Tsygankova, L.E., Elektrokhimicheskoe i korrozionnoe povedenie metallov v kislykh spirtovykh i vodno-spirtovykh sredakh (Electrochemichal and Corrosion Behavior of Metals in Acidic Alcohol and Water-Alcohol Media), Moscow: Radiotekhnika, 2009.
Vigdorovich, V.I. and Matveeva, M.V., Russ. J. Electrochem., 2006, vol. 42, p. 1332.
Vigdorovich, V.I., Tsygankova, L.E., and Kopylova, E.Yu., Russ. J. Electrochem., 2003, vol. 39, p. 753.
Vigdorovich, V.I. and Kopylova, E.Yu., Russ. J. Electrochem., 2004, vol. 40, p. 153.
Vigdorovich, V.I., Tsygankova, L.E., Balybin, D.V., and Kichigin, V.I., J. Electroanal. Chem., 2013, vol. 689, pp. 117–123.
Fiziko-khimicheskie metody analiza (Physicochemical Methods of Analysis), Aleskovskii, V.B. and Yatsimirskii, K.B., Eds., Leningrad: Khimiya, 1971.
Frumkin, A.N., Bagotskii, V.S., Iofa, Z.A., and Kabanov, B.N., Kinetika elektrodnykh protsessov (Kinetics of Electrode Processes), Moscow: Moscow State Univ., 1952.
Vvedenskii, A.V., Gutorov, I.A., and Morozova, N.B., Kondens. Sredy Mezhfaznye Granitsy, 2010, vol. 12, pp. 288–300.
Vvedenskii, A.V., Korroz.: Mater., Zashch., 2011, no. 12, pp. 23–29.
Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorbtsiya organicheskikh soedinenii na elektrodakh (Adsorption of Organic Compounds on Electrodes), Moscow: Nauka, 1968.
Krishtalik, L.I. and Kuz’menko, B.B., Elektrokhimiya, 1973, vol. 9. pp. 664-666.
Krishtalik, L.I., Elektrodnye reaktsii. Mekhanizm elementarnogo akta (Electrode Reactions. Mechanism of Elementary Act), Moscow: Nauka, 1979.
Frumkin, A.N., Dolin, P.I., and Ershler, B.V., Zh. Fiz. Khim., 1940, vol. 14, pp. 907–915.
Gokhshtein, A.Ya., Elektrokhimiya, 1971, vol. 7, p. 594.
Vigdorovich, V.I. and Tsygankova, L.E., Prot. Met., 2007, vol. 43, pp. 628–636.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.I. Vigdorovich, L.E. Tsygankova, D.V. Balybin, O.Yu. Kuzina, 2013, published in Korroziya: Materialy, Zashchita, 2013, No. 9, pp. 30–35.
Rights and permissions
About this article
Cite this article
Vigdorovich, V.I., Tsygankova, L.E., Balybin, D.V. et al. Some features of hydrogen evolution reaction on iron with surfactant on the example of o-fluorophenylbiguanidine. Prot Met Phys Chem Surf 50, 870–874 (2014). https://doi.org/10.1134/S207020511407017X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S207020511407017X