Skip to main content
SpringerLink
Log in

Inverse gas chromatography for identification of poly(ethylene glycol adipate) and tripropionitrilamine on the surface of polymeric sorbent

  • Separation Processes at the Interfaces. Chromatography
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

Identification of the adsorption of poly(ethylene glycol adipate) (PEGA) and tripropionitrilamine (TPA) on styrene-divinylbenzene porous polymer was performed with the use of the inverse gas-chromatography method in finite concentration. PEGA and TPA were applied in quantities ω = 10−6−10−3 mass fractions. As test sorbates n-propanol, n-butanol, and n-hexane used. The adsorption isotherm and the values of specific retention volumes were calculated via the Glueckauf method. It was found that the dependence of the retention volumes on the sorbate concentration in gas phase of the studied samples is well approximated by a power function corresponding to the Freundlich isotherm. The possibility of detecting PEGA and TPA on the surface of sorbent through the A coefficients of a power function was shown, and a linear dependence between the A values and negative logarithm of ω was also found, making it possible to quantitatively determine TPA and PEGA on the surface of a sorbent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Drugov, Yu.S., Zenkevich, I.G., and Rodin, A.A., Gazokhromatograficheskaya Identifikatsiya Zagryaznenii Vozdukha, Vody, Pochvy i Biosred: Prakticheskoe Rukovodstvo (Gas Chromatography for Identification of Air, Water, Soil, and Biological Mediapollution: a Practical Guide), Moscow: BINOM, 2005, p. 752.

    Google Scholar 

  2. Yang, R.T., Adsorbents: Fundamentals and Applications, Hoboken, New York: Wiley, 2003, p. 410.

    Google Scholar 

  3. Modifitsirovannye kremnezemy v sorbtsii, katalize i khromatografii (Modified Silicas for Sorption, Catalysis, and Chromatography), Lisichkin, G.V., Ed., Moscow: Khimiya, 1986, p. 248.

    Google Scholar 

  4. Conder, J. and Young, C., Physicochemical Measurement by Gas Chromatography, Chichester: Wiley, 1979.

    Google Scholar 

  5. Kiselev, A.V., Mezhmolekulyarnye vzaimodeistviya v adsorbtsii i khromatografii (Intermolecular Interactions in Adsorption and Chromatography), Moscow: Vysshaya Shkola, 1986, p. 360.

    Google Scholar 

  6. Yashkin, S.N. and Shuster, R.Kh., Izv. Akad.Nauk, Ser. Khim., 2003, vol. 52, p. 2233.

    Google Scholar 

  7. Cerefolini, G. and Rudzinski, W., in Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces, Rudzinski W., Steele W., and Zgrablich G., Eds., Amsterdam: Elsevier, 1997, p. 1.

  8. Kiselev, A.V. and Yashin, Ya.I., Gazo-adsorbtsionnayakhromatografiya (Gas Adsorption Chromatography), Moscow: Nauka, 1967, p. 256.

    Google Scholar 

  9. Grajek, H., J. Chromatogr. A, 2003, vol. 986, p. 89.

    Article  Google Scholar 

  10. Adsorption: Theory, Modeling, and Analysis, Toth, J.N.Y., Ed., Basel: Marcel Dekker, 2001, p. 879.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Bashkir State University, Ufa, Bashkortostan, 450076, Russia

    F. Kh. Kudasheva, V. Yu. Guskov & A. G. Ganieva

Authors
  1. F. Kh. Kudasheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Yu. Guskov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. G. Ganieva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. Yu. Guskov.

Additional information

Original Russian Text © F.Kh. Kudasheva, V.Yu. Guskov, A.G. Ganieva, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 6, pp. 645–648.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kudasheva, F.K., Guskov, V.Y. & Ganieva, A.G. Inverse gas chromatography for identification of poly(ethylene glycol adipate) and tripropionitrilamine on the surface of polymeric sorbent. Prot Met Phys Chem Surf 50, 773–776 (2014). https://doi.org/10.1134/S2070205114060094

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205114060094

Keywords

Search

Navigation