Skip to main content
SpringerLink
Log in

The inhibition effects of methionine on corrosion behavior of copper in 3.5% NaCl solution at pH = 8.5

  • Physicochemical Problems of Materials Protection
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The inhibition effect of methionine on the corrosion behaviour of copper was investigated in 3.5% NaCl solution with and without methionine. For this purpose, potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) techniques were used. The surface morphology of the metal surface after exposed to corrosive medium was investigated by scanning electron microscopy (SEM). The effect of temperature has also studied in the temperature range from 298 K to 328 K. The effect of temperature has also studied in the temperature range from 298 K to 328 K. Some thermodynamic parameters were calculated and discussed. It was found that, methionine could inhibit the corrosion of copper in 3.5% NaCl solution. Methionine as a organic corrosion inhibitor for copper, and physically adsorbed molecules forming a protective film. Inhibition efficiency increases with decreasing methionine concentration and behaves as a mixed-type inhibitor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Erbil, M. and Lorenz, W.J., Werkst und Korros, 1978, vol. 29, p. 505.

    Article  CAS  Google Scholar 

  2. Kilinççeker, G., Colloids and Surface A, 2008, vol. 329, p. 112.

    Article  Google Scholar 

  3. Sinapia, F., Deroubaixa, S., Pirlota, C., et al., Electrochim. Acta, 2004, vol. 49, p. 2987.

    Article  Google Scholar 

  4. Kabasakaloğlu, M., Corrosion, 1991, vol. 3, p. 23.

    Google Scholar 

  5. Kabasakaloğlu, M., Corrosion, 1991, vol. 3, p. 43.

    Google Scholar 

  6. Kabasakaloğlu, M., Corrosion, 1991, vol. 3, p. 93.

    Google Scholar 

  7. Crundwell, F.K., Electrochim. Acta, 1993, vol. 37, p. 2707.

    Article  Google Scholar 

  8. Kilinççeker, G. and Galip, H., Mater. Chem. Phys., 2008, vol. 110, p. 380.

    Article  Google Scholar 

  9. Sutter, E.M.M., Fiaud, C., and Lincot, D., Electrochim. Acta, 1993, vol. 38, p. 1471.

    Article  CAS  Google Scholar 

  10. Sherif, E.M. and Park, S.M., Electrochim. Acta, 2006, vol. 51, p. 6556.

    Article  CAS  Google Scholar 

  11. Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorption of Organic Compounds on Electrodes, N.Y.: Plenum Press, 1971.

    Book  Google Scholar 

  12. Rozenfeld, I.L. and Hardin, R., Corrosion Inhibitors, N.Y.: Mc Graw-Hill, 1981.

    Google Scholar 

  13. Bockris, J.O.M. and Reddy, A.K.N., Modern Electrochemistry, vol. 2, N.Y.: Plenum Press, 1977.

  14. Ayta, A., Özmen, Ü., and Kabasakaloğlu, M., Mater. Chem. Phys., 2005, vol. 89, p. 176.

    Article  Google Scholar 

  15. Aksüt, A.A. and Bilgi, S., Corrosion Sci., 1992, vol. 33, p. 379.

    Article  Google Scholar 

  16. Soneyik, V.L. and Jenkins, D., Water Chemistry, N.Y.: John Wiley & Sons, 1980.

    Google Scholar 

  17. Jinturkar, P., Guan, Y.C., and Han, K.N., Corrosion, 1998, vol. 54, p. 106.

    Article  CAS  Google Scholar 

  18. Dennis, J., Filliaudeau, F., and Gerard, S.P., Electrochim. Acta, 1993, vol. 38, p. 1951.

    Article  Google Scholar 

  19. Cordeiro, G.G.O., Barcia, O.E., and Mattos, O.R., Electrochim. Acta, 1993, vol. 38, p. 319.

    Article  CAS  Google Scholar 

  20. Modestova, A.D., Zhoua, G.D., Gea, H.H, and Loob, B.H., J. Electroanalyt. Chem., 1995, vol. 380, p. 63.

    Article  Google Scholar 

  21. Kabasakaloğlu, M., Kiyak, T., Sendil, O., and Asan, A., Appl. Surf. Sci., 2002, vol. 193, p. 167.

    Article  Google Scholar 

  22. Singh, R.N., Bahadur, L., and Singh, P., Electrochim. Acta, 1987, vol. 32, p. 895.

    Article  CAS  Google Scholar 

  23. Kilinççeker, G., Yazici, B., Yilmaz, A.B., and Erbil, M., Brit. Corrosion, 2002, vol. 37, p. 23.

    Article  Google Scholar 

  24. Kilinççeker, G., Yazici, B., Erbil, M., and Galip, H., Turk. J. Chem., 1999, vol. 23, p. 41.

    Google Scholar 

  25. Kilinççeker, G. and Galip, H., Protect. Met. Phys. Chem. Surf., 2009, vol. 45, p. 232.

    Article  Google Scholar 

  26. Herrag, L., Chetouani, A., Elkadiri, S., et al., Electrochim. Acta, 2008, vol. 26, p. 211.

    CAS  Google Scholar 

  27. Kilinççeker, G., Taze, N., Galip, H., and Yazici, B., Anti-Corros. Meth. Mater., 2011, vol. 58, p. 4.

    Google Scholar 

  28. Erbil, M., Chim. Acta Turc., 1984, vol. 12, p. 97.

    CAS  Google Scholar 

  29. Fonseca, I.T.E. and Marin, A.C.S., Electrochim. Acta, 1992, vol. 37, p. 2541.

    Article  CAS  Google Scholar 

  30. Kilinççeker, G. and Erbil, M., Mater. Chem. Phys., vol. 119, p. 30.

  31. Stern, M. and Geary, A.L., J. Electrochem. Soc., 1957, vol. 104, p. 56.

    Article  CAS  Google Scholar 

  32. De Chialvo, M.R.G., Moll, D.V., Salvarezza, R.C., and Arvia, A.J., Electrochim. Acta, 1985, vol. 30, p. 1501.

    Article  Google Scholar 

  33. Moreira, A.H., Benedetti, A.V., Cabot, P.L., and Sumodjo, P.T.A., Electrochim. Acta, 1993, vol. 38, p. 981.

    Article  CAS  Google Scholar 

  34. Sanchez, M.P., Barrera, M., Gonzalez, S., et al., Electrochim. Acta, 1990, vol. 35, p. 1337.

    Article  Google Scholar 

  35. Souto, R.M., Sanchez, M.P., Barrera, M., et al., Electrochim. Acta, 1992, vol. 37, p. 1437.

    Article  CAS  Google Scholar 

  36. Dogan, T. and Kilineker, G., Corrosion, 2006, vol. 14, p. 14.

    Google Scholar 

  37. Nunez, L., Reguera, E., Corvo, F., et al., Corrosion Sci., 2005, vol. 47, p. 461.

    Article  CAS  Google Scholar 

  38. Lalitha, A., Ramesh, S., Rajeswari, S., Electrochim. Acta, 2005, vol. 51, p. 47.

    Article  CAS  Google Scholar 

  39. Lipkowski, J. and Ross, P.N., Adsorption of Molecules at Metal Electrodes, N.Y.: VCH, 1992.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Science and Letters Faculty, Chemistry Department, Çukurova University, 01330, Balcali, Adana, Turkey

    Güray Kilinççeker & Hasan Demir

Authors
  1. Güray Kilinççeker
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hasan Demir
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Güray Kilinççeker.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kilinççeker, G., Demir, H. The inhibition effects of methionine on corrosion behavior of copper in 3.5% NaCl solution at pH = 8.5. Prot Met Phys Chem Surf 49, 788–797 (2013). https://doi.org/10.1134/S2070205113060221

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205113060221

Keywords

Search

Navigation