Skip to main content
SpringerLink
Log in

Effect of nonmonotonic changing of surface coverage in multisite adsorption models with possibility of different orientations of molecules with respect to solid surface

  • Physicochemical Processes at The Interfaces
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The reasons for nonmonotonous changing of surface coverage as function of chemical potential in the multisite adsorption models (with allowance for the possibility that molecules can be oriented in a different manner with respect to the solid surface) are revealed in this work. It is demonstrated that this behavior of the surface coverage as function of chemical potential is determined by either the sequence of ordered structures being formed or by the emergence of a stable interface between the ordered phases at temperatures above the tricritical point.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Rudzinski W. and Everett D.H., Adsorption of Gases on Heterogeneous Surfaces, New York: Academic Press, 1992.

    Google Scholar 

  2. Morrison, J. and Lander, J.J., Surf. Sci., 1966, vol. 5, p. 163.

    Article  CAS  Google Scholar 

  3. Vilches, O.E., Ann. Rev. Phys. Chem., 1980, vol. 31, p. 463.

    Article  CAS  Google Scholar 

  4. Bakaev, V.A., Surf. Sci., 1988, vol. 198, p. 571.

    Article  CAS  Google Scholar 

  5. Riccardo, J.L., Ramirez-Pastor, A.J., and Roma, F., Langmuir, 2002, vol. 18, p. 2130.

    Article  CAS  Google Scholar 

  6. Cavenati, S., Grande, C.A., and Rodrigues, A.E., J. Chem. Eng. Data, 2004, vol. 49, p. 1095.

    Article  CAS  Google Scholar 

  7. Otero, R., Rosei, F., and Besenbacher, F., Ann. Rev. Phys. Chem., 2006, vol. 57, p. 497.

    Article  CAS  Google Scholar 

  8. Barth, J.V., Ann. Rev. Phys. Chem., 2007, vol. 58, p. 375.

    Article  CAS  Google Scholar 

  9. Liang, H., He, Y., Ye, Y., et al., Coord. Chem. Rev., 2009, vol. 253, p. 2959.

    Article  CAS  Google Scholar 

  10. Zhdanov, V.P., Elementarnye fiziko-khimicheskie protsessy na poverkhnosti (Elementary Physicochemical Processes on Solid Surfaces), Novosibirsk: Nauka, 1988.

    Google Scholar 

  11. Tovbin, Yu.K., Teoriya fiziko-khimicheskikh protsessov na granitse gaz-tverdoe telo (Theory of Physicochemical Processes at the Gas-Solid Interface), Moscow: Nauka, 1990.

    Google Scholar 

  12. Borowko, M., Computational Methods in Surface and Colloid Science, New York: Marcel Dekker, 2000.

    Book  Google Scholar 

  13. Ramirez-Pastor, A.J., Aligia, A., Roma, F., and Riccardo, J.L., Langmuir, 2000, vol. 16, p. 5100.

    Article  CAS  Google Scholar 

  14. Kasteleyn, P.W., Physica, 1961, vol. 27, p. 1209.

    Article  Google Scholar 

  15. Engel, W., Courbin, L., and Panizza, P., Phys. Rev., vol. 70, p. 165407.

  16. Rzysko, W. and Borowko, M., J. Chem. Phys., 2002, vol. 117, p. 4526.

    Article  CAS  Google Scholar 

  17. Ramirez-Pastor, A.J., Riccardo, J.L., and Pereyra, V.D., Surf. Sci., 1998, vol. 411, p. 294.

    Article  CAS  Google Scholar 

  18. Roma, F., Ramirez-Pastor, A.J., and Riccardo, J.L., Phys. Rev., vol. 68, p. 205407.

  19. Roma, F., Ramirez-Pastor, A.J., and Riccardo, J.L., Langmuir, 2003, vol. 19, p. 6770.

    Article  CAS  Google Scholar 

  20. Rzysko, W. and Borowko, M., Phys. Rev., vol. 67, p. 045403.

  21. Nitta, T., Kiriyama, H., and Shigeta, T., Langmuir, 1997, vol. 13, p. 903.

    Article  CAS  Google Scholar 

  22. Rzysko, W., Patrykiejew, A., and Binder, K., Phys. Rev. B, vol. 72, p. 165416.

  23. Roma, F., Riccardo, J.L., and Ramirez-Pastor, A.J., Ind. Eng. Chem. Res., 2006, vol. 45, p. 2046.

    Article  CAS  Google Scholar 

  24. Temkin, M.I., Zh. Fiz. Khim., 1938, vol. 2, p. 169.

    Google Scholar 

  25. Snagovskii, Yu.S., Zh. Fiz. Khim., 1972, vol. 9, p. 2367.

    Google Scholar 

  26. Snagovskii, Yu.S., Zh. Fiz. Khim., 1972, vol. 10, p. 2584.

    Google Scholar 

  27. Snagovskii, Yu.S., Zh. Fiz. Khim., 1972, vol. 10, p. 2589.

    Google Scholar 

  28. Gorshtein, A.B. and Lopatkin, A.A., Zh. Fiz. Khim., 1974, vol. 48, no. 1, p. 177.

    CAS  Google Scholar 

  29. Gorshtein, A.B. and Lopatkin, A.A., Teor. Eksp. Khim., 1973, vol. 9, no. 2, p. 196.

    CAS  Google Scholar 

  30. Fefelov, V.F., Gorbunov, V.A., Myshlyavtsev, A.V., and Myshlyavtseva, M.D., Chem. Eng. J., 2009, vol. 154, p. 107.

    Article  CAS  Google Scholar 

  31. Fefelov, V.F., Gorbunov, V.A., Myshlyavtsev, A.V., and Myshlyavtseva, M.D., Phys. Rev. E, 2010, vol. 82, no. 4, p. 041602.

    Article  CAS  Google Scholar 

  32. Fefelov, V.F., Gorbunov, V.A., Myshlyavtsev, A.V., et al., Appl. Surf. Sci., 2010, vol. 256, p. 5298.

    Article  CAS  Google Scholar 

  33. Gorbunov, V.A., Myshlyavtsev, A.V., Myshlyavtseva, M.D., and Fefelov, V.F., Izv. Vuzov: Khim. Khim. Tekhnol., 2010, vol. 53, no. 9, p. 66.

    CAS  Google Scholar 

  34. Gorbunov, V.A., Myshlyavtsev, A.V., Myshlyavtseva, M.D., and Fefelov, V.F., Russ. J. Phys. Chem., 2011, no. 1, p. 94.

    Google Scholar 

  35. Landau, D.P. and Binder, K., A Guide to Monte Carlo Simulation in Statistical Physics, Cambridge: University Press, 2000.

    Google Scholar 

  36. Metropolis, N., Rosenbluth, A.W., Rosenbluth, M.N., and Teller, A.H., J. Chem. Phys., 1953, vol. 21, p. 1087.

    Article  CAS  Google Scholar 

  37. Myshlyavtsev, A.V. and Zhdanov, V.P., Chem. Phys. Lett., 1989, vol. 162, p. 43.

    Article  CAS  Google Scholar 

  38. Myshlyavtsev, A.V. and Myshlyavtseva, M.D., Vychislitel’nye aspekty metoda transfer-matritsy (Computation Aspects of the Transfer-Matrix Approach), Kyzyl: TuvIKOPR SO RAN, 2000.

    Google Scholar 

  39. Bykov, V.I., Myshlyavtsev, A.V., and Slin’ko, M.G., Dokl. Akad. Nauk, 2002, vol. 384, no. 5, p. 650.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Omsk State Technical University, pr. Mira 11, Omsk, 644050, Russia

    V. A. Gorbunov, A. V. Myshlyavtsev, M. D. Myshlyavtseva & V. F. Fefelov

  2. Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, ul. Neftezavodskaya 54, Omsk, 644040, Russia

    A. V. Myshlyavtsev

Authors
  1. V. A. Gorbunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Myshlyavtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. D. Myshlyavtseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. F. Fefelov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Gorbunov.

Additional information

Original Russian Text © V.A. Gorbunov, A.V. Myshlyavtsev, M.D. Myshlyavtseva, V.F. Fefelov, 2013, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2013, Vol. 49, No. 4, pp. 352–359.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gorbunov, V.A., Myshlyavtsev, A.V., Myshlyavtseva, M.D. et al. Effect of nonmonotonic changing of surface coverage in multisite adsorption models with possibility of different orientations of molecules with respect to solid surface. Prot Met Phys Chem Surf 49, 379–385 (2013). https://doi.org/10.1134/S2070205113040047

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205113040047

Keywords

Search

Navigation