Adsorption of methane on AU-1 microporous carbon adsorbent

  • E. M. Strizhenov
  • A. A. Fomkin
  • A. A. Zherdev
  • A. A. Pribylov
Physicochemical Processes at the Interfaces

Abstract

Isotherms of absolute methane adsorption are measured on the AU-1 microporous carbon adsorbent in the pressure range of 0.2–25 MPa and temperature range of 300–360 K. The experimental data are used to construct isosteres of methane adsorption. Isosteres in the coordinates of ln p = f (1/T) a are well approximated by straight lines. Dependences of differential molar isosteric adsorption heat on the value of methane adsorption on the given adsorbent are calculated on the basis of experimental data. The effectiveness of adsorption storage systems is analyzed, and the optimum a-p-T parameters of methane accumulation are chosen.

Keywords

Adsorption Concentration Methane Adsorption Adsorption Heat Adsorbent Mass Microporous Carbon 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A Multiyear Plan for the Hydrogen R&D Program. Rationale, Structure, and Technology Roadmaps, Washington: U.S. Department of Energy, 1999, p. 55.Google Scholar
  2. 2.
    Burchell, T. and Rogers, M., SAE Tech. Pap. Ser., 2000, no. 2000-01-2205.Google Scholar
  3. 3.
    Duren, T., Sarkisov, L., Yaghi, O.M., and Snurr, R.Q., Langmuir, 2004, vol. 20, p. 2683.CrossRefGoogle Scholar
  4. 4.
    Vasil’ev, L.L., Kanonchik, L.E., and Mishkinis, D.A., J. Eng. Phys. Thermophys., 1999, vol. 72, no. 5, p. 884.CrossRefGoogle Scholar
  5. 5.
    Zhou, L., Ming, L., and Zhou, Y., Sci. China, vol. 43, no. 2, p. 143.Google Scholar
  6. 6.
    Salem, M.M.K., Braeuer, P., Szombathely, M.V., et al., Langmuir, 1998, vol. 14, p. 3376.CrossRefGoogle Scholar
  7. 7.
    Benard, P. and Chahine, R., Langmuir, 1997, vol. 13, p. 808.CrossRefGoogle Scholar
  8. 8.
    Zhou, L., Zhou, Y., Li, M., et al., Langmuir, 2000, vol. 16, p. 5955.CrossRefGoogle Scholar
  9. 9.
    Zhou, L., Zhou, Y., Bai, Sh., and Yang, B., Adsorption, 2002, no. 8, p. 125.Google Scholar
  10. 10.
    Dreisbach, F., Losch, H.W., and Harting, P., Adsorption, 2002, no. 8, p. 95.Google Scholar
  11. 11.
    Puziy, A.M., Herbst, A., Poddubnaya, O.I., et al., Langmuir, 2003, vol. 19, p. 314.CrossRefGoogle Scholar
  12. 12.
    Fomkin, A.A., Adsorption, 2005, vol. 11, p. 425.CrossRefGoogle Scholar
  13. 13.
    Shkolin, A.V., Fomkin, A.A., and Sinitsyn, V.A., Kolloidn. Zh., 2008, vol. 70, no. 6, p. 849.Google Scholar
  14. 14.
    Shkolin, A.V. and Fomkin, A.A., Izv. Akad. Nauk, Ser. Khim., 2008, vol. 58, no. 9, p. 1765.Google Scholar
  15. 15.
    Pribylov, A.A. and Stekli, Kh.F., Zh. Fiz. Khim., 1998, vol. 72, no. 2, p. 306.Google Scholar
  16. 16.
    Lozano-Castello, D., Cazorla-Amorós, D., Linares-Solano, A., and Quinn, D.F., Carbon, 2002, vol. 40, p. 989.CrossRefGoogle Scholar
  17. 17.
    Balathanigaimani, M.S., Hyun-Chul Kang, Wang-Geun Shim, et al., Korean J. Chem. Eng., 2006, vol. 23, no. 4, p. 663.CrossRefGoogle Scholar
  18. 18.
    Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Fundamental of Adsorption Technics), Moscow: Izd-vo “Khimiya”, 1976.Google Scholar
  19. 19.
    Dubinin, M.M., Adsorbtsiya i poristost’ (Adsorption and Porosity), Moscow: Izd-vo VAKhZ, 1972.Google Scholar
  20. 20.
    Zagoruchenko, V.A. and Zhuravlev, A.M., Teplofizicheskie svoistva gazoobraznogo i zhidkogo metana (Thermophysical Properties of Gaseous and Liquid Methane), Moscow: Izd-vo komiteta standartov, mer i izmeritel’nykh priborov, 1969, p. 236.Google Scholar
  21. 21.
    Pribylov, A.A., Kalashnikov, S.M., and Serpinskii, V.V., Izv. Akad. Nauk SSSR, Ser. Khim., 1990, p. 1233.Google Scholar
  22. 22.
    Burdun, G.D. and Markov, B.N., Osnovy metrologii. Uch. posobie dlya vuzov (Fundamentals of Metrology. Study Guide for Colleges), Moscow: Izd-vo standartov, 1985, 3rd ed.Google Scholar
  23. 23.
    Bakaev, V.A., Doctoral (Phys.-math.) Dissertation, Moscow: Mosk. Gos. Univ., 198, p. 348.Google Scholar
  24. 24.
    Shkolin, A.V., Cand. Sci. (Chem.) Dissertation, Moscow: IFKhE RAN, 2008, p. 263.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • E. M. Strizhenov
    • 1
  • A. A. Fomkin
    • 2
  • A. A. Zherdev
    • 1
  • A. A. Pribylov
    • 2
  1. 1.N.E. Bauman Moscow State UniversityMoscowRussia
  2. 2.A.N. Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia

Personalised recommendations