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Surface tension of a solid with adsorption on its surface with its deformation and surface electric charge considered

Physicochemical Processes at the Interfaces

Abstract

The surface tension of a solid at its interface with a liquid phase containing a surfactant is considered. The deformation of the solid surface and its electric charge are taken into account. In terms of the previously proposed theory on equilibrium one-component adsorption on the solid surface with deformation of this surface taken into account, for the model involving two parallel capacitors, the criteria for the “positive” and “negative” Rehbinder effects are obtained. The conditions under which the “positive” Rehbinder effect disappears in moving from tensile deformation to compressive deformation are given. An expression for the derivative of the surface tension with respect to the electric potential of the solid is derived.

Keywords

Surface Tension Solid Surface Tensile Deformation Compressive Deformation Charge Potential 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  1. 1.Institute of Applied MechanicsRussian Academy of SciencesMoscowRussia

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