Fluctuation formation model and operation mechanism of an inhibiting layer on metals: III. Equations of inhibitor layer at metal boundary

  • Yu. A. Popov
  • N. A. Koval’chukov
  • V. A. Popova
  • V. N. Chistokhvalov
Physicochemical Processes at the Interfaces

Abstract

Equations of the boundary inhibitor layer are derived. The equations determine the metal surface coverage with equilibrium and nonequilibrium layer nuclei. The role of the electrolyte composition, the potential drop within the electric double layer, the probability of heterogeneous nucleation, and other factors are determined.

Keywords

Heterogeneous Nucleation Time Moment Parent Phase Operation Mechanism Spherical Segment 

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References

  1. 1.
    Popov, Yu. A., Protection of Metals, 2007, vol. 43, no. 3, p. 211.CrossRefGoogle Scholar
  2. 2.
    Popov, Yu. A., Protection of Metals, 2008, vol. 44, no. 2, p. 126.Google Scholar
  3. 3.
    Popov, Yu.A. and Koval’chukov, N.A., Protection of Metals and Physical Chemistry of Surfaces, 2010, vol.46, no. 1, p. 27.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • Yu. A. Popov
    • 1
    • 2
  • N. A. Koval’chukov
    • 1
    • 2
  • V. A. Popova
    • 1
    • 2
  • V. N. Chistokhvalov
    • 1
    • 2
  1. 1.Karpov Institute of Physical ChemistryMoscowRussia
  2. 2.Russian Peoples’ Friendship UniversityMoscowRussia

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