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Fluctuation formation model and operation mechanism of an inhibiting layer on metals: III. Equations of inhibitor layer at metal boundary

  • Physicochemical Processes at the Interfaces
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Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

Equations of the boundary inhibitor layer are derived. The equations determine the metal surface coverage with equilibrium and nonequilibrium layer nuclei. The role of the electrolyte composition, the potential drop within the electric double layer, the probability of heterogeneous nucleation, and other factors are determined.

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References

  1. Popov, Yu. A., Protection of Metals, 2007, vol. 43, no. 3, p. 211.

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  2. Popov, Yu. A., Protection of Metals, 2008, vol. 44, no. 2, p. 126.

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  3. Popov, Yu.A. and Koval’chukov, N.A., Protection of Metals and Physical Chemistry of Surfaces, 2010, vol.46, no. 1, p. 27.

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Authors and Affiliations

  1. Karpov Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 105064, Russia

    Yu. A. Popov, N. A. Koval’chukov, V. A. Popova & V. N. Chistokhvalov

  2. Russian Peoples’ Friendship University, ul. Mikluho-Maklaya 6, Moscow, 117198, Russia

    Yu. A. Popov, N. A. Koval’chukov, V. A. Popova & V. N. Chistokhvalov

Authors
  1. Yu. A. Popov
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  2. N. A. Koval’chukov
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  3. V. A. Popova
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  4. V. N. Chistokhvalov
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Correspondence to V. A. Popova.

Additional information

Original Russian Text © Yu. A. Popov, N. A. Koval’chukov, V. A. Popova, V. N. Chistokhvalov, 2010, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2010, Vol. 46, No. 3, pp. 268–271.

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Popov, Y.A., Koval’chukov, N.A., Popova, V.A. et al. Fluctuation formation model and operation mechanism of an inhibiting layer on metals: III. Equations of inhibitor layer at metal boundary. Prot Met Phys Chem Surf 46, 316–319 (2010). https://doi.org/10.1134/S2070205110030044

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  • DOI: https://doi.org/10.1134/S2070205110030044

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