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Fluctuation formation model and operation mechanism of inhibiting layers on metals: II. Interaction and evolution of inhibitor nuclei

  • Yu. A. Popov
  • N. A. Koval’chukov
  • V. N. Chistokhvalov
Physicochemical Processes at the Interfaces

Abstract

The formation kinetics of inhibitor nuclei during the origination of the primary layer at the metal interface is considered. A model of interactions that change the equilibrium state is presented. An equation of the process referred to as the evolution of nuclei is derived.

Keywords

Heterogeneous Nucleation Surface Site Anodic Dissolution Parent Phase Ionic Component 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Volmer, M., Kinetika obrazovaiya novoi fazy (Kinetics of New Phase Formation), Moscow: Nauka, 1986.Google Scholar
  2. 2.
    Popov, Yu.A. and Koval’chukov, N.A., Fizikokhimiya Poverkhn. Zashch. Mater., 2010, vol. 46, no. 1, p. 24 [Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 1, p. 27].Google Scholar
  3. 3.
    Andreev, V.A. and Andreeva, N.P., Krat. Soobshch. Fiz., Moscow: FIAN, 2001, no. 11, p. 3.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • Yu. A. Popov
    • 1
    • 2
  • N. A. Koval’chukov
    • 1
    • 2
  • V. N. Chistokhvalov
    • 1
    • 2
  1. 1.Karpov Institute of Physical ChemistryMoscowRussia
  2. 2.Russian People’s Friendship UniversityMoscowRussia

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