Study of the sorption-kinetic properties of carbon molecular sieves

Nanoscale and Nanostructured Materials and Coatings

Abstract

To elucidate the role of the electron-exchange properties of arene molecules that form the pore walls of carbon molecular sieves in their interactions with sorbate molecules, the correlation between the electronexchange and sorption-kinetic properties was studied. The electron-exchange properties were estimated by using quantum-chemical modeling based on the energies of formation of singly charged anions and cations and neutral (both oxidized and reduced) molecules.

PACS

68.43.-h 

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  1. 1.Kemerovo State UniversityKemerovoRussia
  2. 2.Institute of Solid-State Chemistry and Mechanochemistry (Kemerovo Branch), Siberian DivisionRussian Academy of SciencesKemerovoRussia

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