Abstract
To elucidate the role of the electron-exchange properties of arene molecules that form the pore walls of carbon molecular sieves in their interactions with sorbate molecules, the correlation between the electronexchange and sorption-kinetic properties was studied. The electron-exchange properties were estimated by using quantum-chemical modeling based on the energies of formation of singly charged anions and cations and neutral (both oxidized and reduced) molecules.
Similar content being viewed by others
References
Stoeckli, F., Daguerre, E., and Gulliot, A., Carbon, 1999, vol. 37, p. 2075.
Stoeckli, F. and Centeno, T.A., Carbon, 2005, vol. 43, p. 1184.
Junpirom, S., Do, D.D., Tangsathitkulchai, C., and Tangsathitkulchai, M., Carbon, 2005, vol. 43, p. 1936.
Blayden, H.E., Gibson, J., and Riley, H.L., Conf. on the “Ultra-Fine Structure of Coals and Cokes”, London: The Royal Institution, 1943, p. 176.
Brown, J.K. and Hirsch, P.B., Nature, 1955, vol. 175, p. 229.
Blumenfeld, L.A., Voevodsky, V.V., and Semenov, A.G., Applications of Electron Spin Resonance in Chemistry, Novosibirsk: SB RAS, 1962.
Huttepain, M. and Oberlin, A., Carbon, 1990, vol. 28, p. 103.
Patent 734 394, Kosaka, 1988, no. 4.
Berveno, A.V., Berveno, V.P., Lyrshchikov, S.Yu., et al., Mezhdunarodnaya konferentsiya “Fiziko-khimicheskie protsessy v neorganicheskikh materialakh” (Int. Conf. “Physicochemical Processes in Inorganic Materials”), Kemerovo, 2007.
Berveno, A.V., Berveno, V.P., Lyrshchikov, S.Yu., and Kogodeev, S.E., Abstracts of Papers, CESEP’07: The 2nd Int. Conf. on Carbon for Energy Storage and Environment Protection, Krakow, 2007.
Berveno, A.V. and Berveno, V.P., Polzunov. Vestn., 2008, no. 3, p. 84.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.V. Berveno, V.P. Berveno, 2009, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2009, Vol. 45, No. 4, pp. 411–414.
Rights and permissions
About this article
Cite this article
Berveno, A.V., Berveno, V.P. Study of the sorption-kinetic properties of carbon molecular sieves. Prot Met Phys Chem Surf 45, 440–443 (2009). https://doi.org/10.1134/S207020510904011X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S207020510904011X