Abstract
The catalytic properties of complex perovskite-type gadolinium and strontium oxides in carbon dioxide reforming of methane and the production of gaseous olefins by carbon monoxide hydrogenation have been studied. Samples of Gd2SrFe2O7 and Gd2–x Sr1+x Fe2O7 (х = 0.1; 0.2; 0.3; and 0.4) have been obtained by the sol–gel method and ceramic technology, and have been characterized by means of X-ray diffraction, scanning electron microscopy, photon correlation spectroscopy, Mössbauer spectroscopy, and N2 adsorption–desorption analysis. It has been shown that the sol–gel method allows us to produce samples with better catalytic characteristics than ceramic systems. The nonisovalent substitution of Gd3+ for Sr2+ distorts the structure of complex oxide, resulting in the emergence of the heterovalent state of iron atoms (Fe3+ and Fe4+) reflected in the values of reactant conversion and selectivity for the target products. A sample of Gd2–x Sr1+x Fe2O7 with х = 0.3 displays the highest catalytic activity in dry reforming of methane reforming, along with the highest selectivity for unsaturated hydrocarbons (ethylene and propylene) in hydrogenation of carbon monoxide.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Wood, D., Oil Gas J., 2007, vol. 12, pp. 20–24.
Khazova, T., Neftegaz, 2013, no. 4, pp. 34–35.
Pogosyan, N.M., Synthesis of olefins via cooxidation of light hydrocarbons, Cand. Sci. (Chem.) Dissertation, Moscow Gubkin Gos. Univ. Nefti Gaza, 2016.
Zhao, K., He, F., Huang, Z., Wei, G., Zheng, A., Li, H., and Zhao, Z., Appl. Energy, 2016, vol. 168, pp. 193–203.
Salker, A.V. and Gurav, S.M., J. Mater. Sci., 2000, vol. 35, no. 18, pp. 4713–4719.
Mamedov, A.Kh., Mirzabekov, S.R., Shiryaev, Sh.A., and Shapkin, D.P., Neftekhimiya, 1990, vol. 30, pp. 492–496.
Mirzabekova, S.R., Mamedov, A.Kh., and Aliev, V.S., Neftekhimiya, 1993, vol. 33, pp. 62–70.
Mirzabekova, S.R., Mamedov, A.Kh., and Krylov, O.V., Kinet. Katal., 1993, vol. 34, no. 3, pp. 522–528.
Touahra, F., Rabahi, A., Chebout, R., Boudjemaa, A., Lerari, D., Sehailia, M., Halliche, D., and Bachari, K., Int. J. Hydrogen Energy, 2016, vol. 41, no. 4, pp. 2477–2486.
Radlik, M., Adamowska-Teyssier, M., Krzton, A., Koziel, K., Krajewski, W., and Turek, W., Da Costa, P., C. R. Chim., 2015, vol. 18, no. 11, pp. 1242–1249.
De Caprariis, B., De Filippis, P., Palma, V., Petrullo, A., Ricca, A., Ruocco, C., and Scarsella, M., Appl. Catal., A, 2016, vol. 517, pp. 47–55.
Drif, A., Bion, N., Brahmi, R., Ojala, S., Pirault-Roy, L., Turpeinen, E., Seelam, P.K., Keiski, R.L., and Epron, F., Appl. Catal., A, 2015, vol. 504, pp. 576–584.
Shlyakhtin, O.A., Mazo, G.N., Kaluzhskikh, M.S., Komissarenko, D.A., Loktev, A.S., and Dedov, A.G., Mater. Lett., 2012, vol. 75, pp. 20–22.
Dedov, A.G., Loktev, A.C., Mazo, G.N., Leonova, L.S., Komissarenko, D.A, Mamaev, Yu.A., Kaluzhskikh, M.S., Shlyakhtin, O.A., Kuznetsova, E.P., Kartasheva, M.N., and Moiseev, I.I., Dokl. Phys. Chem., 2011, vol. 441, no. 2, pp. 233–236.
Zagaynov, I.V., Loktev, A.S., Arashanova, A.L., Ivanov, V.K., Dedov, A.G., and Moiseev, I.I., Chem. Eng. J., 2016, vol. 290, pp. 193–200.
Dedov, A.G., Loktev, A.S., Moiseev, I.I., Aboukais, A., Lamonier, J.-F., and Filimonov, I.N., Appl. Catal., A, 2003, vol. 245, no. 2, pp. 209–220.
Dedov, A.G., Loktev, A.S., Men’shchikov, V.A., Kartasheva, M.N., Parkhomenko, K.V., and Moiseev, I.I., Dokl. Chem., 2001, vol. 380, no. 4, pp. 301–304.
Dedov, A.G., Loktev, A.S., Nipan, G.D., Dorokhov, S.N., Golikov, S.D., Spesivtsev, N.A., and Moiseev, I.I., Pet. Chem., 2015, vol. 55, no. 2, pp. 163–168.
Nipan, G.D., Loktev, A.S., Parkhomenko, K.V., Golikov, S.D., Dedov, A.G., and Moiseev, I.I., Dokl. Phys. Chem., 2013, vol. 448, no. 2, pp. 19–22.
Li, J., Pan, X., and Bao, X., Chin. J. Catal., 2015, vol. 36, no. 7, pp. 1131–1135.
Gao, X., Zhang, J., Chen, N., Ma, Q., Fan, S., Zhao, T., and Tsubaki, N., Chin. J. Catal., 2016, vol. 37, no. 4, pp. 510–516.
Zvereva, I.A., Otrepina, I.V., Semenov, V.G., Tugova, E.A., Popova, V.F., and Gusarov, V.V., Russ. J. Gen. Chem., 2007, vol. 77, no. 6, pp. 973–978.
Otrepina, I.V., Volodin, V.V., Zvereva, I.A., and Liu, J.-Sh., Glass Phys. Chem., 2009, vol. 35, no. 4, pp. 423–430.
Chislova, I.V., Matveeva, A.A., Volkova, A.V., and Zvereva, I.A., Glass Phys. Chem., 2011, vol. 37, no. 6, pp. 653–660.
Shilova, A., Chislova, I., Panchuk, V., Semenov, V., and Zvereva, I., Solid State Phenom., 2013, vol. 194, pp. 116–119.
Chislova, I.V., Phase formation processes, structure, and magnetic and catalytic properties of complex gadolinium and strontium ferrites Gd2–xSr1 + xFe2O7–a, Cand. Sci. (Chem.) Dissertation, St.Petersburg St. Peterb. State Univ., 2015.
Roginskii, S.Z., Yanovskii, M.I., and Bermand, A.D., Osnovy primeneniya khromatografii v katalize (Principles of the Application of Chromatography in Catalysis), Moscow Nauka, 1972.
Dementyeva, M.V., Sheshko, T.F., and Serov, Yu.M., Theor. Exp. Chem., 2013, vol. 49, no. 1, pp. 46–51.
Rajadurai, S., Carberry, J.J., Li., B., and Alcock, C.B., J. Catal., 1991, vol. 131, no. 2, pp. 582–589.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.F. Sheshko, T.A. Kryuchkova, Yu.M. Serov, I.V. Chislova, I.A. Zvereva, 2017, published in Kataliz v Promyshlennosti.
Rights and permissions
About this article
Cite this article
Sheshko, T.F., Kryuchkova, T.A., Serov, Y.M. et al. New mixed perovskite-type Gd2–x Sr1+x Fe2O7 catalysts for dry reforming of methane, and production of light olefins. Catal. Ind. 9, 162–169 (2017). https://doi.org/10.1134/S207005041702009X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S207005041702009X