Skip to main content
SpringerLink
Log in

Inhibiting HDS and HYD reactions with quinoline on Co(Ni)–PMo(W)/Al2O3 catalysts: Effect of active phase composition on stability in the hydrotreatment of a model petroleum raw material

  • Catalysis in Petroleum Refining Industry
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

Со(Ni)–PMo(W)/Al2O3 catalysts are prepared using Keggin heteropoly acids H3PMo(W)12O40 and cobalt (nickel) citrate. The physicochemical properties of the catalysts are studied via low-temperature nitrogen adsorption, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy. Their catalytic properties are determined in the hydrotreatment of a model raw material containing dibenzothiophene, naphthalene, and different amounts of quinoline (up to 1000 ppm of nitrogen), and in the hydrotreatment of a straight-run diesel fraction and vacuum gas oil. The composition of Со(Ni)–PMo(W)/Al2O3 catalysts plays an important role in the hydrotreatment of a complex hydrocarbon raw material. Ni–PW/Al2O3 catalyst is more resistant to organonitrogen inhibitors than Ni(Co)–PMo/Al2O3 samples with more reactive active sites. Ni–PW/Al2O3 catalyst provides the greatest depth of conversion for sulfur- and nitrogen-containing compounds and polycyclic aromatic hydrocarbons in the hydrotreatment of vacuum gas oil.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Stanislaus, A., Marafi, A., and Rana, M.S., Catal. Today, 2010, vol. 153, nos. 1–2, pp. 1–68.

    Article  CAS  Google Scholar 

  2. Song, C., Catal. Today, 2003, vol. 86, nos. 1–4, pp. 211–263.

    Article  CAS  Google Scholar 

  3. Topsøe, H., Clausen, B.S., and Massoth, F.E., in Catalysis—Science and Technology, vol. 11: Hydrotreating Catalysis, Anderson, J.R., and Boudart, M., Eds., Berlin Springer, 1996.

  4. Reinhoudt, H.R., Boons, C.H.M., van Langeveld, A.D., van Veen, J.A.R., Sie, S.T., and Moulijn, J.A., Appl. Catal., A, 2001, vol. 207, nos. 1–2, pp. 25–36.

    Article  CAS  Google Scholar 

  5. Spojakina, A., Palcheva, R., Jiratova, K., Tyuliev, G., and Petrov, L., Catal. Lett., 2005, vol. 104, no. 1, pp. 45–52.

    Article  CAS  Google Scholar 

  6. Mozhaev, A.V., Nikulshin, P.A., Pimerzin, A.A., Maslakov, K.I., and Pimerzin, A.A., Catal. Today, 2016, vol. 271, pp. 80–90.

    Article  CAS  Google Scholar 

  7. Nikulshin, P.A., Minaev, P.P., Mozhaev, A.V., Maslakov, K.I., Kulikova, M.S., and Pimerzin, A.A., Appl. Catal., B, 2015, vols. 176–177, pp. 374–384.

    Article  Google Scholar 

  8. Minaev, P.P., Nikulshin, P.A., Kulikova, M.S., Pimerzin, A.A., and Kogan, V.M., Appl. Catal., A, 2015, vol. 505, pp. 456–466.

    Article  CAS  Google Scholar 

  9. Nikulshin, P.A., Ishutenko, D.I., Mozhaev, A.A., Maslakov, K.I., and Pimerzin, A.A., J. Catal., 2014, vol. 312, pp. 152–169.

    Article  CAS  Google Scholar 

  10. Speight, J.G. The Chemistry and Technology of Petroleum, Boca Raton, FL CRC Press, 2006.

    Google Scholar 

  11. Halachev, T., Nava, R., and Dimitrov, L., Appl. Catal., A, 1998, vol. 169, no. 1, pp. 111–117.

    Article  CAS  Google Scholar 

  12. Knudsen, K.G., Cooper, B.H., and Topsøe, H., Appl. Catal., A, 1999, vol. 189, no. 2, pp. 205–215.

    Article  CAS  Google Scholar 

  13. Andari, M.K., Abu-Seedo, F., Stanislaus, A., and Qabazard, H.M., Fuel, 1996, vol. 75, no. 14, pp. 1664–1670.

    Article  CAS  Google Scholar 

  14. Sal’nikov, V.A., Nikul’shin, P.A., and Pimerzin, A.A., Pet. Chem., 2013, vol. 53, no. 4, pp. 233–244.

    Article  Google Scholar 

  15. Egorova, M. and Prins, R., Catal. Lett., 2004, vol. 92, no. 3, pp. 87–91.

    Article  CAS  Google Scholar 

  16. Beltramone, A.R., Crossley, S., Resasco, D.E., Alvarez, W.E., and Choudhary, T.V., Catal. Lett., 2008, vol. 123, nos. 3–4, pp. 181–185.

    Article  CAS  Google Scholar 

  17. Shih, S.S., Mizrahi, S., Green, L.A., and Sarli, M.S., Ind. Eng. Chem. Res., 1992, vol. 31, no. 4, pp. 1232–1235.

    Article  CAS  Google Scholar 

  18. Whitehurst, D.D., Isoda, T., and Mochida, I., Adv. Catal., 1998, vol. 42, pp. 345–471.

    CAS  Google Scholar 

  19. Oyama, T.S., J. Catal., 2003, vol. 216, nos. 1–2, pp. 343–352.

    Article  CAS  Google Scholar 

  20. Xiang, C.-E., Chai, Y.-M., Liu, Y.-Q., and Liu, C.-G., J. Fuel Chem. Technol., 2008, vol. 36, no. 6, pp. 684–690.

    Article  CAS  Google Scholar 

  21. Lio, K. and Ng, F.T.T., Catal. Today, 2010, vol. 149, nos. 1–2, pp. 28–34.

    Article  Google Scholar 

  22. Kabe, T., Ishihara, A., and Tajima, H., Ind. Eng. Chem. Res., 1992, vol. 31, no. 6, pp. 1577–1580.

    Article  CAS  Google Scholar 

  23. Macaud, M., Milenkovic, A., Schulz, E., Lemaire, M., and Vrinat, M., J. Catal., 2000, vol. 193, no. 2, pp. 255–263.

    Article  CAS  Google Scholar 

  24. Lio, Z., Zheng, Y., Wang, W., Zhang, Q., and Jia, L., Appl. Catal., A, 2008, vol. 339, no. 2, pp. 209–220.

    Article  Google Scholar 

  25. Rana, M.S., Navarro, R., and Leglise, J., Catal. Today, 2004, vol. 98, nos. 1–2, pp. 67–74.

    Article  CAS  Google Scholar 

  26. Logadóttir, A., Moses, P.G., Hinnemann, P., Topsøe, N.Y., Knudsen, K.G., Topsøe, H., and Nørskov, J.K., Catal. Today, 2006, vol. 111, nos. 1–2, pp. 44–51.

    Article  Google Scholar 

  27. Mizutani, H., Godo, H., Ohsaki, T., Kato, Y., Fujikawa, T., Saih, Y., Funamoto, T., and Segawa, K., Appl. Catal., A, 2005, vol. 295, no. 2, pp. 193–200.

    Article  CAS  Google Scholar 

  28. Egorova, M. and Prins, R., J. Catal., 2004, vol. 221, no. 1, pp. 11–19.

    Article  CAS  Google Scholar 

  29. Egorova, M. and Prins, R., J. Catal., 2004, vol. 224, no. 2, pp. 278–287.

    Article  CAS  Google Scholar 

  30. Laredo, G.C., Montesinos, A., and de los Reyes, J.A., Appl. Catal., A, 2004, vol. 265, no. 2, pp. 171–183.

    Article  CAS  Google Scholar 

  31. Koltai, T., Macaud, M., Guevara, A., Schulz, E., Lemaire, M., Bacaud, R., and Vrinat, M., Appl. Catal., A, 2002, vol. 231, nos. 1–2, pp. 253–261.

    Article  CAS  Google Scholar 

  32. Laredo, G.C.S., De los Reyes, J.A.H., Cano, J.L.D., and Castillo, J.J.M., Appl. Catal., A, 2001, vol. 207, nos. 1–2, pp. 103–112.

    Article  Google Scholar 

  33. Siryuk, A.G. and Zimina, K.I., Khim. Tekhnol. Topl. Masel, 1963, no. 2, pp. 52–56.

    Google Scholar 

  34. Eremina, Yu.V., Studying the specific features of the hydrodesulfonation and hydrogenation reactions of diesel fraction compounds over molybdenum-containing catalysts, Cand. Sci. (Chem.) Dissertation, Samara Samara State Tech. Univ., 2006.

    Google Scholar 

  35. Tayeb, K.B., Lamonier, C., Lancelot, C., Fournier, L., Bonduelle-Skrzypczak, A., and Bertoncini, F., Catal. Lett., 2014, vol. 144, no. 3, pp. 460–468.

    Article  Google Scholar 

  36. Tayeb, K.B., Lamonier, C., Lancelot, C., Fournier, L., Payen, E., Bonduelle, A., and Bertoncini, F., Catal. Today, 2010, vol. 150, no. 3–4, pp. 207–212.

    Article  Google Scholar 

  37. Zuo, D., Vrinat, M., Nie, H., Maugéc, F., Shi, Y., Lacroix, M., and Li., D., Catal. Today, 2004, vols. 93–95, pp. 751–760.

    Article  Google Scholar 

  38. Coulier, L., Kishan, G., van Veen, J.A.R., and Niemantsverdriet, J.W., J. Phys. Chem. B, 2002, vol. 106, no. 23, pp. 5897–5906.

    Article  CAS  Google Scholar 

  39. Mogica-Betancourt, J.C., López-Benítez, A., Montiel-López, J.R., Massin, L., Aouine, M., Vrinat, M., Berhault, G., and Guevara-Lara, A., J. Catal., 2014, vol. 313, pp. 9–23.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Samara State Technical University, Samara, 443100, Russia

    P. P. Minaev, A. S. Koklyukhin & P. A. Nikulshin

  2. Moscow State University, Moscow, 119991, Russia

    K. I. Maslakov

Authors
  1. P. P. Minaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Koklyukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. I. Maslakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. A. Nikulshin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. P. Minaev.

Additional information

Original Russian Text © P.P. Minaev, A.S. Koklyukhin, K.I. Maslakov, P.A. Nikulshin, 2017, published in Kataliz v Promyshlennosti.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Minaev, P.P., Koklyukhin, A.S., Maslakov, K.I. et al. Inhibiting HDS and HYD reactions with quinoline on Co(Ni)–PMo(W)/Al2O3 catalysts: Effect of active phase composition on stability in the hydrotreatment of a model petroleum raw material. Catal. Ind. 9, 146–155 (2017). https://doi.org/10.1134/S2070050417020064

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050417020064

Keywords

Search

Navigation