Abstract
The paper considers a thermodynamically consistent model of compressible multicomponent mixtures with phase transitions. For the isothermal case, this enables one to obtain surfaces of phase equilibrium and other thermodynamic functions in analytic form. Use is made of simple model equations of state and the model Gibbs potential, which are known to adequately describe the phase behavior of solutions in some practically important range of parameters. Such a thermodynamically consistent model is convenient for the numerical simulation of the filtration of multicomponent solutions with phase transitions—in this way we achieve a significant reduction in the execution time and reliability of numerical computation, and also exclude some unphysical solutions.
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References
K. Aziz and E. Settari, Petroleum Reservoir Simulation (Warren & Root, 1963; Nedra, Moscow, 1982).
M. D. Rozenberg and S. A. Kundin, Multiphase Multicomponent Filtration during Oil and Gas Extraction (Nedra, Moscow, 1978) [in Russian].
F. M. Orr, Theory of Gas Injection Processes (Stanford, 2005).
V. S. Mitlin, “Two-Phase Multicomponent Filtration: Instabilities, Autowaves and Retrograde Phenomena,” J. Fluid Mech. 220, 369–395 (1990).
S. M. Walas, Phase Equilibrium in Chemical Engineering (Bulterworth Pub., Sydney, 1985; Mir, Moscow, 1989).
O. Yu. Batalin, A. I. Brusilovskii, and M. Yu. Zakharov, Phase Equilibriums in the Natural Hydrocarbon Systems (Nedra, Moscow, 1992) [in Russian].
A. V. Koldoba and E. V. Koldoba, “Model Equation of State for the Numerical Solution of the Problems of Multicomponent Filtration with Phase Transitions,” Geokhim., No. 5, 573–576 (2004) [Geochem. Int. 42, No. 5,493 (2004)].
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Original Russian Text © A.V. Koldoba, E.V. Koldoba, 2010, published in Matematicheskoe Modelirovanie, 2010, Vol. 22, No. 4, pp. 147–154.
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Koldoba, A.V., Koldoba, E.V. Thermodynamically consistent model of a multicomponent mixture with phase transitions. Math Models Comput Simul 2, 782–787 (2010). https://doi.org/10.1134/S207004821006013X
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DOI: https://doi.org/10.1134/S207004821006013X