Abstract
Novel silicon-containing amine curing agents for epoxy oligomers were synthesized by the interaction of diols of variable structure with aminopropyltriethoxysilane. The development of these curing agents yields a significant reduction in the polymer glass point, an increase in the degree of conversion of epoxide groups in the course of curing, and a significant improvement in the chemical stability and hydrophobicity of epoxy amine coatings, as well as their physicomechanical properties.
Similar content being viewed by others
References
I. Z. Chernin, F. M. Smekhov, and Yu. V. Zherdev, Epoxy resins and compositions (Khimiya, Moscow, 1982) [in Russian].
B. A. Rozenberg and E. F. Oleinik, Usp. Khim. (1984).
Epoxy resin (review), Khim. Kompleks Rossii, 104(6), 17–26 (2003).
V. I. Irzhak, B. A. Rozenberg, and E. S. Enikopyan, Network Polymers (Nauka, Moscow, 1979) [in Russian].
S. M. Mezhikovskii and V. I. Irzhak, Chemical Physics of Cured Oligomers (Nauka, Moscow, 2008) [in Russian].
M. F. Sorokin, Z. A. Kochnova, A. A. Zakharova, and I. A. Cherebylo, Lakokras. Mater. Ikh Primen., No. 4, 32–35 (1980).
K. Nakanisi, Infrared Spectra and Structure of Organic Compounds, Ed. by A. A. Mal’tsev (Mir, Moscow, 1965) [in Russian].
A. Ya. Malkin and S. G. Kulichikhin, Rheology in the Formation and Transformation of Polymers (Khimiya, Moscow, 1985) [in Russian].
P. I. Voskresenskii, Technology of Laboratory Works (Goskhimizdat, Moscow, 1962) [in Russian].
M. I. Karyakina, Laboratory Workshop on Technical Analysis and Production Control of Paints and Coatings (Khimiya, Moscow, 1989) [in Russian].
A. T. Sanzharovskii, Physico-Mechanical Properties of Polymers and Coatings (Khimiya, Moscow, 1978) [in Russian].
A. A. Askadskii, Structure and Properties of Heat-Resistant Polymers (Khimiya, Moscow, 1981) [in Russian].
Hardeners of Epoxy Resins: An Informational Overview (NIITEKhIM, Moscow, 1976) [in Russian].
T. R. Deberdeev, R. M. Garipov, G. F. Novikov, and I. A. Chernov, Vest. KTU, No. 5, 134–137 (2008).
M. V. Sobolevskii, O. A. Muzovskaya, and G. S. Popeleva, Properties and Fields of Use of Silicone Products (Khimiya, Moscow, 1975) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © R.M. Garipov, A.I. Zagidullin, M.V. Kolpakova, O.V. Stoyanov, 2010, published in Klei. Germetiki. Tekhnologii, 2010, No. 12, pp. 23–30.
Rights and permissions
About this article
Cite this article
Garipov, R.M., Zagidullin, A.I., Kolpakova, M.V. et al. Silicon-containing amine curing agents and their application to protective epoxide compositions. Polym. Sci. Ser. D 4, 188–195 (2011). https://doi.org/10.1134/S1995421211030051
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1995421211030051