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Silicon-containing amine curing agents and their application to protective epoxide compositions

  • R. M. Garipov
  • A. I. Zagidullin
  • M. V. Kolpakova
  • O. V. Stoyanov
Article

Abstract

Novel silicon-containing amine curing agents for epoxy oligomers were synthesized by the interaction of diols of variable structure with aminopropyltriethoxysilane. The development of these curing agents yields a significant reduction in the polymer glass point, an increase in the degree of conversion of epoxide groups in the course of curing, and a significant improvement in the chemical stability and hydrophobicity of epoxy amine coatings, as well as their physicomechanical properties.

Keywords

epoxide composite materials silicon-containing amine curing agents 

References

  1. 1.
    I. Z. Chernin, F. M. Smekhov, and Yu. V. Zherdev, Epoxy resins and compositions (Khimiya, Moscow, 1982) [in Russian].Google Scholar
  2. 2.
    B. A. Rozenberg and E. F. Oleinik, Usp. Khim. (1984).Google Scholar
  3. 3.
    Epoxy resin (review), Khim. Kompleks Rossii, 104(6), 17–26 (2003).Google Scholar
  4. 4.
    V. I. Irzhak, B. A. Rozenberg, and E. S. Enikopyan, Network Polymers (Nauka, Moscow, 1979) [in Russian].Google Scholar
  5. 5.
    S. M. Mezhikovskii and V. I. Irzhak, Chemical Physics of Cured Oligomers (Nauka, Moscow, 2008) [in Russian].Google Scholar
  6. 6.
    M. F. Sorokin, Z. A. Kochnova, A. A. Zakharova, and I. A. Cherebylo, Lakokras. Mater. Ikh Primen., No. 4, 32–35 (1980).Google Scholar
  7. 7.
    K. Nakanisi, Infrared Spectra and Structure of Organic Compounds, Ed. by A. A. Mal’tsev (Mir, Moscow, 1965) [in Russian].Google Scholar
  8. 8.
    A. Ya. Malkin and S. G. Kulichikhin, Rheology in the Formation and Transformation of Polymers (Khimiya, Moscow, 1985) [in Russian].Google Scholar
  9. 9.
    P. I. Voskresenskii, Technology of Laboratory Works (Goskhimizdat, Moscow, 1962) [in Russian].Google Scholar
  10. 10.
    M. I. Karyakina, Laboratory Workshop on Technical Analysis and Production Control of Paints and Coatings (Khimiya, Moscow, 1989) [in Russian].Google Scholar
  11. 11.
    A. T. Sanzharovskii, Physico-Mechanical Properties of Polymers and Coatings (Khimiya, Moscow, 1978) [in Russian].Google Scholar
  12. 12.
    A. A. Askadskii, Structure and Properties of Heat-Resistant Polymers (Khimiya, Moscow, 1981) [in Russian].Google Scholar
  13. 13.
    Hardeners of Epoxy Resins: An Informational Overview (NIITEKhIM, Moscow, 1976) [in Russian].Google Scholar
  14. 14.
    T. R. Deberdeev, R. M. Garipov, G. F. Novikov, and I. A. Chernov, Vest. KTU, No. 5, 134–137 (2008).Google Scholar
  15. 15.
    M. V. Sobolevskii, O. A. Muzovskaya, and G. S. Popeleva, Properties and Fields of Use of Silicone Products (Khimiya, Moscow, 1975) [in Russian].Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • R. M. Garipov
    • 1
  • A. I. Zagidullin
    • 1
  • M. V. Kolpakova
    • 1
  • O. V. Stoyanov
    • 1
  1. 1.Kazan State Technological UniversityKazan, TatarstanRussia

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