Skip to main content
Log in

Structural Parameters of Ordered Nanocomposites Based on Opal Matrices in Accordance with the Data of Small Angle X-Ray and Neutron Scattering: Opal Matrix. Part I

  • Functional Nanomaterials
  • Published:
Nanotechnologies in Russia Aims and scope Submit manuscript

Abstract

The structure of nanocomposites based on opal matrices with different types of filling of structural voids is investigated. It is shown that the order in which tetrahedral and octahedral voids in the opal matrix are filled with various substances affects the X-ray diffraction pattern in the small angle region. On the basis of neutron diffraction, small angle X-ray scattering, and transmission electron microscopy data, models are proposed for filling the voids. The structural parameters of ordered nanocomposites based on opal matrices of different compositions are determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. I. Svergun and L. A. Feigin, X-Ray and Neutron Small-Angle Scattering (Nauka, Moscow, 1986) [in Russian].

    Google Scholar 

  2. A. A. Eliseev, D. F. Gorozhankin, K. S. Napol’skii, A. V. Petukhov, N. A. Sapoletova, A. V. Vasilieva, N. A. Grigoryeva, A. A. Mistonov, D. V. Byelov, V. G. Bouwman, K. O. Kvashnina, D. Yu. Chernyshov, A. A. Bosak, and S. V. Grigoriev, “Determination of the real structure of artificial and natural opals on the basisof three-dimensional reconstructions of reciprocal space,” JETP Lett. 90, 272 (2009).

    Article  Google Scholar 

  3. V. M. Masalov, E. A. Kudrenko, N. A. Grigoryeva, K. V. Voronina, V. V. Roddatis, N. S. Sukhinina, M. V. Arefyev, A. A. Mistonov, S. V. Grigoriev, and G. A. Emelchenko, “Direct observation of the shelllike structure of SiO2 particles synthesized by the multistage stober method,” NANO: Brief Rep. Rev. 8, 1350036 (2013).

    Article  Google Scholar 

  4. F. Marlow, M. Muldarisnur, P. Sharifi, and H. Zabel, “Interpretation of small-angle diffraction experiments on opal-like photonic crystals,” Phys. Rev. B 84, 073401 (2011).

    Article  Google Scholar 

  5. P. Sharifi, “Structural characterization of opal-based photonic crystals,” PhD Dissertation (2013).

    Google Scholar 

  6. S. N. Ivicheva, S. V. Kutsev, Yu. F. Kargin, and N. A. Alad’ev, “Colloidal and transparent opal-matrix nanocomposites filled with europium-doped silica sols,” Inorg. Mater. 50, 253 (2014).

    Article  Google Scholar 

  7. S. N. Ivicheva, Yu. F. Kargin, N. A. Aladiev, S. V. Kutsev, and V. S. Gorelik, “Nanocomposites based on opal matrices and silica sols doped with rare earth compounds,” J. Sol-Gel Sci. Technol. 68, 429–437 (2013).

    Article  Google Scholar 

  8. S. N. Ivicheva, Yu. F. Kargin, and S. G. Sakharov, “Manufacture of opal-matrix functional nanocomposites by catalytic dehydrogenation of isopropanol under supercritical conditions,” Russ. J. Inorg. Chem. 59, 1077 (2014).

    Article  Google Scholar 

  9. S. N. Ivicheva, Yu. F. Kargin, S. V. Kutsev, and A. A. Ashmarin, “Synthesis of different bismuth titanates and ordered Bi–Ti–O nanocomposites based on opal matrices,” Russ. J. Inorg. Chem. 60, 1317 (2015).

    Article  Google Scholar 

  10. O. Glatter and O. Kratky, Small Angle X-Ray Scattering (Academic, London, 1982).

    Google Scholar 

  11. T. C. Huang, H. Toraya, T. N. Blanton, and Y. Wu, “X-ray powder diffraction analysis of silver behenate, a possible low-angle diffraction standard,” J. Appl. Crystallogr. 26, 180–184 (1993).

    Article  Google Scholar 

  12. R. Mayoral, J. Requena, C. Lypez, S. J. Moya, H. Mhguez, L. Vozquez, F. Meseguer, M. Holgado, A. Cintas, and A. Blanco, “3D long range ordering of submicrometric SiO2 sintered superstructures,” Adv. Mater. 9, 257–260 (1997).

    Article  Google Scholar 

  13. N. V. Belov, Structure of Ionic Crystals and Metal Phases (Akad. Nauk SSSR, Moscow, 1947) [in Russian].

    Google Scholar 

  14. O. A. Kavtreva, A. V. Ankudinov, A. G. Bazhenova, Yu. A. Kumzerov, M. F. Limonov, K. B. Samusev, and A. V. Sel’kin, “Optical characterization of natural and synthetic opals by Bragg reflection spectroscopy,” Phys. Solid State 49, 708 (2007).

    Article  Google Scholar 

  15. A. K. Boldyrev, Crystallography, 3rd ed. (GorGeoNefteIzdat, Groznyi, Novosibirsk, Moscow, Leningrad, 1934) [in Russian].

    Google Scholar 

  16. W. Hume-Rothery, Elements of Structural Metallurgy (Inst. Metals, London, 1961).

    Google Scholar 

  17. G. B. Bokii, Introduction to Crystal Chemistry (Mosk. Gos. Univ., Moscow, 1954) [in Russian].

    Google Scholar 

  18. A. G. Khachaturyan, Theory of Phase Transformations and the Structure of Solid Solutions (Nauka, Moscow, 1974) [in Russian].

    Google Scholar 

  19. A. S. Poplavnoi, “Symmetry of crystals composed of two bravais sublattices in 6D crystal spaces,” Crystallogr. Rep. 55, 169 (2010).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. N. Ivicheva.

Additional information

Original Russian Text © S.N. Ivicheva, S.V. Amarantov, Yu.F. Kargin, V.V. Volkov, 2018, published in Rossiiskie Nanotekhnologii, 2018, Vol. 13, Nos. 7–8.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ivicheva, S.N., Amarantov, S.V., Kargin, Y.F. et al. Structural Parameters of Ordered Nanocomposites Based on Opal Matrices in Accordance with the Data of Small Angle X-Ray and Neutron Scattering: Opal Matrix. Part I. Nanotechnol Russia 13, 356–364 (2018). https://doi.org/10.1134/S1995078018040079

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995078018040079

Navigation