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Nanotechnologies in Russia

, Volume 4, Issue 1–2, pp 85–92 | Cite as

Preparation of polymer nanocomposites by explosive processing

  • N. A. Adamenko
  • A. V. Kazurov
  • A. V. Fetisov
  • G. V. Agafonova
Experiment

Abstract

This work is aimed at preparing polymer nanocomposites or, in the case of high-filled composites with a metal content of over 50%, organometallic nanoalloys by explosive processing of powder polymer-metal mixes with a metal dispersion of no more than 100m. The nanostructuring is a result of the jet-like flow, intense localized plastic deformation, the crushing of initial structural components followed by their activation, and turbulent hashing. These simultaneous processes are accompanied by destructive-recombination reactions in the polymer and in the adhesive interaction of the components.

Keywords

Shock Wave Central Zone Shock Front Initial Porosity Main Zone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    I. D. Morokhov, I. D. Trusov, and S.P. Chizhik, Ultradispersed Metallic Media (Atomizdat, Moscow, 1977) [in Russian].Google Scholar
  2. 2.
    Yu. I. Petrov, Clusters and Small Particles (Nauka, Moscow, 1986) [in Russian].Google Scholar
  3. 3.
    A. I. Gusev and A. A. Rempel, Nanocrystalline Materials (Fizmatlit, Moscow, 2000; Cambridge International Science, Cambridge, 2004).Google Scholar
  4. 4.
    A. A. Rempel, “Nanotechnologies: Properties and Applications of Nanostructured Materials,” Usp. Khim. 76(5), 474–500 (2007).Google Scholar
  5. 5.
    Yu. D. Tretyakov, “Self-Organization Processes in the Chemistry of Materials,” Usp. Khim. 72(8), 731–763 (2003).Google Scholar
  6. 6.
    R. Z. Valiev and I. V. Aleksandrov, Nanostructured Materials Produced by Severe Plastic Deformation (Logos, Moscow, 2000) [in Russian].Google Scholar
  7. 7.
    A. I. Gusev, Nanomaterials, Nanostructures, and Nanotechnologies (Fizmatlit, Moscow, 2005) [in Russian].Google Scholar
  8. 8.
    A. D. Pomogailo, A. S. Rozenberg, and I. E. Uflyand, Nanoparticles of Metals in Polymers (Khimiya, Moscow, 2000) [in Russian].Google Scholar
  9. 9.
    A. A. Okhlopkova, A. V. Vinogradov, and L. S. Pinchuk, Plastics Filled with Ultradispersed Inorganic Compounds (Institute of Mechanics of Metal-Containing Polymer Systems of the National Academy of Sciences of Belarus, Gomel, 1999) [in Russian].Google Scholar
  10. 10.
    I. D. Simonov-Emel’yanov, “Technology for Producing and Reprocessing Nanostructured Polymer and Carbon Composite Materials,” in Abstracts of Papers of the International Conference “High Chemical Technologies—2004,” Volgograd, Russia, 2004 (Volgograd, 2004), Vol. 2, pp. 58–60.Google Scholar
  11. 11.
    A. D. Pomogailo, “Fundamental Approaches to the Formation of Metal-Containing Nanocomposites,” in Proceedings of the All-Russia Workshop “Nanoparticles and Nanochemistry,” Chernogolovka, Moscow oblast, Russia, 2000 (Chernogolovka, 2000), p. 13.Google Scholar
  12. 12.
    O. V. Arzhakova, et al., “Metal-Containing Nanocomposites Based on Cruised Polymer Matrices,” in Proceedings of the Fourth International Conference “The Chemistry of Highly Organized Substances and Scientific Foundations of Nanotechnology,” St. Petersburg State University, St. Petersburg, Russia, 2004 (St. Petersburg, 2004), p. 131.Google Scholar
  13. 13.
    G. I. Dzhardimalieva, et al., “Synthesis and Magnetic Properties of Metal-Containing Nanocomposites,” in Proceedings of the Fourth International Conference “The Chemistry of Highly Organized Substances and Scientific Foundations of Nanotechnology,” St. Petersburg State University, St. Petersburg, Russia, 2004 (St. Petersburg, 2004), p. 130.Google Scholar
  14. 14.
    S. P. Gubin, M. S. Korobov, G. Yu. Yurkov, A. K. Tsvetnikov, and V. M. Buznik, “Nanometallization of Ultradispersed Poly(tetrafluoroethylene),” Dokl. Akad. Nauk, Ser. Khim. 388(4–6), 493–496 (2003) [Dokl. Chem. 388 (4–6), 44–46 (2003)].Google Scholar
  15. 15.
    N. A. Adamenko, A. V. Fetisov, and A. V. Kazurov, Explosive Treatment of Metal-Containing Composites (Volgograd State Technical University, Volgograd, Russia, 2007) [in Russian].Google Scholar
  16. 16.
    V. D. Rogozin, Explosive Treatment of Powdered Materials Volgograd State Technical University, Volgograd, Russia, 2002) [in Russian].Google Scholar
  17. 17.
    A. G. Beloshapko, A. A. Bukaemskii, and A. M. Staver, “Formation of Ultradispersed Compounds upon Shock- Wave Loading of Porous Aluminum: Investigation of Particles Obtained,” Fiz. Goreniya Vzryva 26(4), 93–97 (1990) [Combust., Explos. Shock Waves 26 (4), 457–460 (1990)].Google Scholar
  18. 18.
    R. Z. Valiev, A. V. Korznikov, and R. R. Mulyukov, “Structure and Properties of Metallic Materials with a Submicrocrystalline Structure,” Fiz. Met. Metalloved. 73(6), 70–86 (1992) [Phys. Met. Metallogr. 73 (6), 373–384 (1992)].Google Scholar
  19. 19.
    A. P. Il’in, et al., in Proceedings of the Second Interregional Conference on Ultrafine-Dispersed Powders, Nanostructures, and Materials, Krasnoyarsk State Technical University, Krasnoyarsk, Russia, 1999 (Krasnoyarsk, 1999), p. 31.Google Scholar
  20. 20.
    A. M. Staver, N. V. Gubareva, A. I. Lyamkin, and E. A. Petrov, “Ultrafine Diamond Powders Made by the Use of Explosion Energy,” Fiz. Goreniya Vzryva, 20(5), 100–104 (1984) [Combust., Explos. Shock Waves 20 (5), 567–570 (1984)].Google Scholar
  21. 21.
    A. G. Beloshapko, A. A. Bukaemskii, I. G. Kuz’min and A. M. Staver, “Ultradispersed Stabilized Zirconium Dioxide Powder Synthesized by the Dynamical Method,” Fiz. Goreniya Vzryva, 29(6), 111–112 (1993) [Combust., Explos. Shock Waves 29 (6), 772–773 (1993)].Google Scholar
  22. 22.
    N. A. Adamenko, Yu. P. Trykov, V. N. Arisova, V. D. Rogozin, and A. V. Fetisov, “Structural Transformations of the Fluoroplastic Material under Explosive Pressing in Cylindrical Ampoules,” Fiz. Khim. Obrab. Mater., No. 5, 54–57 (2000).Google Scholar
  23. 23.
    N. A. Adamenko, Yu. P. Trykov, and A. V. Kazurov, “Properties of the Iron Fluoroplastic Composite Produced under Explosive Pressing in Ampoules,” Perspekt. Mater., No. 4, 83–86 (2003).Google Scholar
  24. 24.
    N. A. Adamenko, Yu. P. Trykov, A. V. Fetisov, and G. V. Agafonova, “Shock-Wave Treatment of Polymers and Polymer Composites,” Fiz. Khim. Obrab. Mater., No. 5, 20–24 (2006).Google Scholar
  25. 25.
    M. K. Baramboim, Mechanochemistry of Polymers (MacLaren, London, 1964; Khimiya, Moscow, 1971).Google Scholar
  26. 26.
    A. M. Dubinskaya, “Transformations of Organic Compounds under the Action of Mechanical Stresses,” Usp. Khim. 68(8), 708–724 (1999).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • N. A. Adamenko
    • 1
  • A. V. Kazurov
    • 1
  • A. V. Fetisov
    • 1
  • G. V. Agafonova
    • 1
  1. 1.Volgograd State Technical UniversityVolgogradRussia

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