Phase Equilibrium of the Propylene Glycol–Propane/Butane Binary System

Abstract

The phase equilibrium of the propylene glycol–propane/butane system and the solubility of propylene glycol in a supercritical propane-butane mixture at temperatures of 403, 423, and 443 K are studied using a high-pressure optical cell. The results are described using the Peng–Robinson equation of state and the Mukhopadhyay and Rao mixing law.

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REFERENCES

  1. 1

    A. I. Cooper, J. Mater. Chem. 10, 207 (2000).

    CAS  Article  Google Scholar 

  2. 2

    F. M. Gumerov, A. N. Sabirzyanov, and G. I. Gumerova, Sub- and Supercritical Fluids in Polymer Processing (FEN, Kazan, 2000) [in Russian].

    Google Scholar 

  3. 3

    M. Hagiwara, H. Mitsui, S. Machi, and T. Kagiya, J. Polym. Sci., Part A 6, 721 (1968).

    CAS  Google Scholar 

  4. 4

    M. F. Kemmere and O. Meyer, Supercritical Carbon Dioxide in Polymer Reaction Engineering (Wiley-VCH, Weinheim, 2005).

    Google Scholar 

  5. 5

    P. S. Timashev, L. I. Krotova, D. A. Lemenovskii, and V. K. Popov, Sverkhkrit. Flyuidy: Teor. Prakt. 5 (2), 70 (2010).

    Google Scholar 

  6. 6

    R. Arshady, Colloid Polym. Sci. 270, 717 (1992).

    CAS  Article  Google Scholar 

  7. 7

    M. A. McHugh and V. J. Krukonis, Supercritical Fluid Extraction (Butterworth-Heinemann, Stoneham, MA, 1994).

    Google Scholar 

  8. 8

    J. J. Watkins, V. J. Krukonis, P. D. Condo, and D. Pradhan, Jr., J. Supercrit. Fluids 4 (24), 24 (1991).

    CAS  Article  Google Scholar 

  9. 9

    J. Jung and M. Perrut, J. Supercrit. Fluids 20, 179 (2001).

    CAS  Article  Google Scholar 

  10. 10

    I. M. Gil’mutdinov, V. F. Khairutdinov, I. V. Kuznetsova, A. A. Mukhamadiev, F. R. Gabitov, F. M. Gumerov, and A. N. Sabirzyanov, Russ. J. Phys. Chem. B 3, 1145 (2009).

    Article  Google Scholar 

  11. 11

    V. F. Khairutdinov, F. R. Gabitov, F. M. Gumerov, B. le Neindre, and E. S. Vorob’ev, Russ. J. Phys. Chem. B 5, 1228 (2011).

    CAS  Article  Google Scholar 

  12. 12

    V. K. Popov, Doctoral (Chem.) Dissertation (Mosc. State Univ., 2013).

  13. 13

    S. D. Yeo and E. Kiran, J. Supercrit. Fluids 34, 287 (2005).

    CAS  Article  Google Scholar 

  14. 14

    V. N. Bagratashvili, A. B. Solov’eva, N. N. Glagolev, A. V. Cherkasova, I. V. Andreeva, and P. S. Timashev, Russ. J. Phys. Chem. B 5, 1144 (2011).

    CAS  Article  Google Scholar 

  15. 15

    Yu. S. Zavorotnyi, L. I. Krotova, V. K. Popov, A. O. Rybaltovskii, and P. S. Timashev, Russ. J. Phys. Chem. B 5, 1161 (2011).

    CAS  Article  Google Scholar 

  16. 16

    M. Bork, in Proceedings of the 5th Meeting and Natural Products Processing, Nice, March 23–25, 1998, p. 387.

  17. 17

    US Patent No. 4306058 (1981).

  18. 18

    K. M. Scholsky, K. M. O’Connor, C. S. Weiss, and V. J. Krukronis, J. Appl. Polym. Sci. 33, 2925 (1987).

    CAS  Article  Google Scholar 

  19. 19

    C. Champault, C. Cordinet, B. Herbreteau, M. Zafosse, and M. Dreux, in Proceedings of the 5th Meeting on Supercritical Fluids, Strasbourg, France, 1998, p. 217.

  20. 20

    T. R. Bilalov, F. M. Gumerov, and R. F. Gatina, Sverkhkrit. Flyuidy: Teor. Prakt. 11 (4), 17 (2016).

    Google Scholar 

  21. 21

    T. R. Bilalov, N. B. Zav’yalova, and F. M. Gumerov, Sverkhkr. Flyuidy: Teor. Prakt. 14 (14), 27 (2019).

    Google Scholar 

  22. 22

    O. N. Dyment, K. S. Kazanskii, and A. M. Miroshnikov, Glycols and other Derivatives of Ethylene and Propylene Oxides (Khimiya, Moscow, 1976) [in Russian].

    Google Scholar 

  23. 23

    T. Salmi, E. Paatero, P. Nyholm, M. Still, and K. Narhi, Chem. Eng. Sci. 49, 5053 (1994).

    CAS  Article  Google Scholar 

  24. 24

    N. Juntarachat, J. Chem. Eng. Data, No. 58, 671 (2013).

    CAS  Article  Google Scholar 

  25. 25

    P. Beranek, Fluid Phase Equilib. 6, 279 (1981).

    CAS  Article  Google Scholar 

  26. 26

    M. Skerget, D. Cucek, and Z. Knez, J. Supercrit. Fluids 95, 129 (2014).

    CAS  Article  Google Scholar 

  27. 27

    A. Lancia, D. Musmarra, and F. Pepe, J. Chem. Eng. 29, 449 (1996).

    CAS  Article  Google Scholar 

  28. 28

    V. F. Khairutdinov, F. M. Gumerov, Z. I. Zaripov, I. Sh. Khabriev, L. Yu. Yarullin, and I. M. Abdulagatov, J. Supercrit. Fluids 156, 1 (2020).

    Article  Google Scholar 

  29. 29

    V. F. Khairutdinov, F. M. Gumerov, I. Sh. Khabriev, M. I. Farakhov, I. Z. Salikhov, I. B. Polishuk, and I. M. Abdulagatov, Fluid Phase Equilib. 510, 1 (2020).

    Article  Google Scholar 

  30. 30

    D. F. Williams, J. Chem. Eng. Sci. 36, 1769 (1981).

    CAS  Article  Google Scholar 

  31. 31

    M. Mukhopadhyay and G. V. R. Rao, Ind. Eng. Chem. Res., No. 32, 922 (1993).

  32. 32

    T. R. Bilalov, F. M. Gumerov, and B. Le Neindre, Description and Generalization of Solubility in Supercritical Fluids (LAP LAMBERT Academic, Saarbrücken, Germany, 2018).

    Google Scholar 

  33. 33

    T. R. Bilalov and F. M. Gumerov, Russ. J. Phys. Chem. B 13, 1290 (2019).

    CAS  Article  Google Scholar 

  34. 34

    R. Dohrn and G. Brunner, in Proceedings of the 3rd International Symposium on Supercritical Fluids, Strasburg, France, 1994, Vol. 1, p. 241.

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Funding

This study was supported by Russian Science Foundation (project no. 19-73-10029).

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Correspondence to T. R. Bilalov.

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Translated by L. Mosina

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Bilalov, T.R., Gumerov, F.M., Khairutdinov, V.F. et al. Phase Equilibrium of the Propylene Glycol–Propane/Butane Binary System. Russ. J. Phys. Chem. B 14, 1282–1286 (2020). https://doi.org/10.1134/S1990793120080023

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  • Keywords: propylene glycol
  • supercritical propane/butane mixture
  • phase equilibrium
  • solubility
  • Peng–Robinson equation of state
  • Mukhopadhyay and Rao mixing law