Synthesis of Polymer–Metal Composites by the Impregnation of Hypercrosslinked Polystyrene with Palladium Compounds in Supercritical Carbon Dioxide and Their Catalytic Activity in the Liquid-Phase Hydrogenation of Diphenylacetylene

Russian Journal of Physical Chemistry B volume 14, pages1172–1177(2020)Cite this article

Abstract

Composites—palladium metal particles in a polymer matrix—are obtained by impregnation of hypercrosslinked polystyrene with palladium compounds in supercritical carbon dioxide (SC-CO2) followed by molecular hydrogen reduction. The synthesized composites exhibit a high level of catalytic activity in the liquid-phase hydrogenation of diphenylacetylene (DPA). The turnover frequency (TOF) is 15–50 min–1 and the selectivity in the formation of diphenylethylene is 60–80% at ~90% conversion of the substrate.

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ACKNOWLEDGMENTS

The authors thank D.Sc. M.V. Bermeshev (Institute of Petrochemical Synthesis, Russian Academy of Sciences) for providing the polynorbornene sample.

Funding

This work was financially supported by the Russian Foundation for Basic Research (grant no. 18-29-06032).

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Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. E. Lazhko

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    G. O. Bragina & A. Yu. Staheev

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    S. E. Lyubimov & V. A. Davankov

  4. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    O. P. Parenago

Authors
  1. A. E. Lazhko
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  2. G. O. Bragina
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  3. S. E. Lyubimov
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  4. V. A. Davankov
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  5. A. Yu. Staheev
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  6. O. P. Parenago
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Corresponding author

Correspondence to O. P. Parenago.

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Translated by K. Utegenov

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Lazhko, A.E., Bragina, G.O., Lyubimov, S.E. et al. Synthesis of Polymer–Metal Composites by the Impregnation of Hypercrosslinked Polystyrene with Palladium Compounds in Supercritical Carbon Dioxide and Their Catalytic Activity in the Liquid-Phase Hydrogenation of Diphenylacetylene. Russ. J. Phys. Chem. B 14, 1172–1177 (2020). https://doi.org/10.1134/S1990793120070118

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  • Keywords: hypercrosslinked polystyrene
  • palladium compounds
  • supercritical carbon dioxide
  • composite
  • palladium particles
  • hydrogenation
  • diphenylacetylene
  • activity