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A Study of the Regularities of the Solid-Phase Synthesis of Metal Stearates

  • Kinetics and Mechanism of Chemical Reactions Catalysis
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Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

Features of the solid-phase synthesis of metal stearates (calcium, barium, zinc, and silver stearates) on a Bridgman anvil-type device were studied. Factors of the solid-phase reaction between reagents were determined. The activation volumes of the reactions between stearic acid with calcium oxide and silver oxide were determined. The initial rates of the solid-phase synthesis of silver and calcium stearate were calculated. The rates of synthesis of metal stearates in liquid and solid phases were compared. The data showed that metal carboxylates could be synthesized in a solution-less medium.

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Authors and Affiliations

  1. Kazan National Research Technological University, Kazan, Republic of Tatarstan, 420015, Russia

    A. A. Momziakov, K. S. Fadeeva, T. R. Deberdeev & R. Y. Deberdeev

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Zharov

  3. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Berlin

Authors
  1. A. A. Momziakov
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  2. A. A. Zharov
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  3. K. S. Fadeeva
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  4. T. R. Deberdeev
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  5. A. A. Berlin
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  6. R. Y. Deberdeev
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Correspondence to A. A. Momziakov.

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Momziakov, A.A., Zharov, A.A., Fadeeva, K.S. et al. A Study of the Regularities of the Solid-Phase Synthesis of Metal Stearates. Russ. J. Phys. Chem. B 13, 68–74 (2019). https://doi.org/10.1134/S1990793119010275

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  • DOI: https://doi.org/10.1134/S1990793119010275

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