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Russian Journal of Physical Chemistry B

, Volume 12, Issue 1, pp 53–57 | Cite as

2,4,6-Triazido-1,3,5-Triazine, 2,4,6-Triazidopyrimidine, and 2,4,6-Triazidopyridine as Precursors of Carbon Nitride Materials

  • N. V. Chukanov
  • S. V. Chapyshev
  • V. V. Nedel’ko
  • V. V. Zakharov
  • N. N. Dremova
  • B. L. Korsunskii
  • A. D. Chervonnyi
Kinetics and Mechanism of Chemical Reactions. Catalysis
  • 17 Downloads

Abstract

The thermolysis of 2,4,6-triazido-1,3,5-triazine (I), 2,4,6-triazidopyrimidine (II), and 2,4,6-triazidopyridine (III) and its products were studied by DSC, mass spectrometry, IR spectroscopy, and electron microscopy. The thermal transformations of I gave planar nets formed by polyconjugated C–N bonds arranged into bundle aggregates. The thermolysis product of III consists of low-molecular compounds and has globular morphology. The thermolysis of II resulted in a mixture of products of both types, among which the planar nets were dominant. The relationship between the structure of the products of the thermal transformations of I, II, and III and the kinetic characteristics of these processes was discussed.

Keywords

2,4,6-triazido-1,3,5-triazine 2,4,6-triazidopyrimidine 2,4,6-triazidopyridine thermal decomposition calorimetry mass spectrometry IR spectroscopy electron microscopy carbon nitride materials 

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References

  1. 1.
    H. Finger, Z. Prakt. Chem 75, 103 (1907).CrossRefGoogle Scholar
  2. 2.
    E. Kroke and M. Schwarz, Adv. Mater. 11, 158 (1999).CrossRefGoogle Scholar
  3. 3.
    E. Gillan, Chem. Mater. 12, 3906 (2000).CrossRefGoogle Scholar
  4. 4.
    V. V. Nedel’ko, B. L. Korsunskii, T. S. Larikova, S. V. Chapyshev, N. V. Chukanov, and Shu Yuantsze, Russ. J. Phys. Chem. B 10, 570 (2016).CrossRefGoogle Scholar
  5. 5.
    C. Ye, H. Gao, J. A. Boatz, et al., Angew. Chem., Int. Ed. 45, 7262 (2006).CrossRefGoogle Scholar
  6. 6.
    M. H. V. Huynh, M. A. Hiskey, J. G. Archuleta, et al., Angew. Chem., Int. Ed. 43, 5658 (2004).CrossRefGoogle Scholar
  7. 7.
    M. H. V. Huynh, M. A. Hiskey, J. G. Archuleta, et al., Angew. Chem., Int. Ed. 44, 737 (2005).CrossRefGoogle Scholar
  8. 8.
    D. R. Miller, D. C. Swenson, and E. D. Gillan, J. Am. Chem. Soc. 126, 5372 (2005).CrossRefGoogle Scholar
  9. 9.
    D. R. Miller, J. R. Holst, and E. D. Gillan, Inorg. Chem. 46, 2767 (2007).CrossRefGoogle Scholar
  10. 10.
    V. V. Nedel’ko, B. L. Korsunskii, T. S. Larikova, S. V. Chapyshev, N. V. Chukanov, and Shu Yuantsze, Russ. Chem. Bull. 65, 2068 (2016).CrossRefGoogle Scholar
  11. 11.
    V. V. Nedel’ko, B. L. Korsunskii, T. S. Larikova, S. V. Chapyshev, N. V. Chukanov, and Shu Yuantsze, Russ. J. Phys. Chem. B 10, 902 (2016).CrossRefGoogle Scholar
  12. 12.
    E. Keßenich, T. Klapötke, and J. Knizek, Eur. J. Inorg. Chem., 2013 (1998).Google Scholar
  13. 13.
    S. V. Chapyshev, E. N. Ushakov, P. Neuhaus, et al., Org. Chem. 79, 6047 (2014).CrossRefGoogle Scholar
  14. 14.
    S. V. Chapyshev and A. V. Chernyak, Synthesis 44, 3158 (2012).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. V. Chukanov
    • 1
  • S. V. Chapyshev
    • 1
  • V. V. Nedel’ko
    • 1
  • V. V. Zakharov
    • 1
  • N. N. Dremova
    • 1
  • B. L. Korsunskii
    • 1
  • A. D. Chervonnyi
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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