Abstract
The results of experiments and computer simulations on the radical-chain oxidation of methyl linoleate in micelles are reported. The reaction rate constants included in the developed mathematical model are estimated. The ratio of the rates of first-order and bimolecular chain termination is examined. It is demonstrated that the rate constant of bimolecular chain termination in micelles is lower than that in the homogeneous phase.
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Original Russian Text © E.M. Pliss, D.V. Loshadkin, A.M. Grobov, T.S. Kuznetsova, A.I. Rusakov, 2015, published in Khimicheskaya Fizika, 2015, Vol. 34, No. 1, pp. 68–72.
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Pliss, E.M., Loshadkin, D.V., Grobov, A.M. et al. Kinetic study and simulation of methyl linoleate oxidation in micelles. Russ. J. Phys. Chem. B 9, 127–131 (2015). https://doi.org/10.1134/S1990793115010091
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DOI: https://doi.org/10.1134/S1990793115010091