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Effect of the surface charge on the complexing and catalytic properties of Cu2+-containing composite materials based on zirconia and powdered cellulose

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
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Abstract

Composite materials (CMs) based on zirconia xerogels and powdered cellulose (PC) were synthesized. The effect of the CM surface charge on their complexing properties with respect to Cu2+ ions and on the catalytic activity of the samples in model reactions of the decomposition of H2O2 and the oxidative dehydrogenation of trimethylhydroquinone with atmospheric oxygen was analyzed. It was experimentally proved that the use of PC for the synthesis of ZrO2-based CMs, as in the case of previously studied CMs based on SiO2 and TiO2, leads to an increase in the specific surface area S sp and a decrease in the negative electric potential of their surface. The surface charge, sorption method, and the composition of the buffer solution used for sorption have a significant effect on the copper(II) content in the CM phase, the distribution pattern, and the composition of the sorbed copper(II) compounds and on the catalytic activity of the synthesized Cu2+-containing CMs.

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References

  1. A. V. Ivanov and L. M. Kustov, Russ. Chem. Bull. 49, 39 (2000).

    Article  CAS  Google Scholar 

  2. A. A. Lur’e, Sorbents and Chromatographic Carriers (Khimiya, Moscow, 1972) [in Russian].

    Google Scholar 

  3. N. B. Ur’ev and A. A. Potanin, Fluidity of Suspensions and Powders (Khimiya, Moscow, 1992) [in Russian].

    Google Scholar 

  4. A. B. Shishmakov, Yu. V. Mikushina, M. S. Valova, et al., Russ. J. Appl. Chem. 80, 2107 (2007).

    Article  CAS  Google Scholar 

  5. N. I. Nikitin, Chemistry of Wood and Cellulose (Nauka, Leningrad, 1962) [in Russian].

    Google Scholar 

  6. A. B. Shishmakov, Yu. V. Mikushina, and M. S. Valova, Russ. J. Appl. Chem. 82, 2113 (2009).

    Article  CAS  Google Scholar 

  7. E. V. Parshina, L. S. Molochnikov, E. G. Kovaleva, et al., Russ. J. Phys. Chem. A 85, 452 (2011).

    Article  CAS  Google Scholar 

  8. E. G. Kovaleva and L. S. Molochnikov, Nitroxides: Theory, Experiment and Applications, Ed. by A. I. Kokorin (InTech Publ., Croatia, 2012), p. 211.

  9. L. S. Molochnikov, E. G. Kovalyova, I. A. Grigor’ev, et al., J. Phys. Chem. B 108, 1302 (2004).

    Article  CAS  Google Scholar 

  10. K. I. Zamaraev, R. I. Salganik, V. N. Romannikov, et al., Dokl. Akad. Nauk 340, 779 (1995).

    CAS  Google Scholar 

  11. T. A. Tukmacheva, L. M. Edugina, E. V. Parshina, et al., in Proceedings of the All-Russia Scientific-Technical Conference on Scientific Creativity of Youth — to the Forest Complex of Russia (Ural. Gos. Lesotekh. Univ., Yekaterinburg, 2008), Part 2, p. 296.

    Google Scholar 

  12. L. S. Molochnikov, E. G. Kovaleva, E. L. Golovkina, et al., Colloid. J. 69, 769 (2007).

    Article  CAS  Google Scholar 

  13. E. L. Golovkina, E. G. Kovaleva, L. S. Molochnikov, et al., Sorbts. Khromatogr. Protsessy 8, 971 (2008).

    Google Scholar 

  14. E. G. Kovaleva, L. S. Molochnikov, V. G. Kharchuk, et al., Kinet. Catal. 45, 752 (2004).

    Article  CAS  Google Scholar 

  15. V. A. Bushmelev and N. S. Vol’man, Cellulose and its Derivatives (Khimiya, Moscow, 1974) [in Russian].

    Google Scholar 

  16. R. I. Sarybaeva, Powder Cellulose: Production, Properties, Application (Ilim, Frunze, 1987) [in Russian].

    Google Scholar 

  17. E. V. Novozhilov and D. N. Poshina, Khim. Rastit. Syr’ya, No. 3, 15 (2011).

    Google Scholar 

  18. I. S. Puzyrev, Candidate’s Dissertation in Chemistry (Ural. Federal Univ., Yekaterinburg, 2010).

    Google Scholar 

  19. A. B. Shishmakov, E. G. Kovaleva, Yu. V. Mikushina, et al., Russ. J. Inorg. Chem. 55, 937 (2010).

    Article  CAS  Google Scholar 

  20. Chemist’s Manual, Vol. 3 (Goskhimizdat, Moscow, 1952), p. 1192 [in Russian].

  21. A. A. Bobko, V. V. Khramtsov, and I. A. Grigor’ev, Org. Biomol. Chem. 3, 1269 (2005).

    Article  Google Scholar 

  22. M. A. Voinov, I. A. Kiriluyk, and A. I. Smirnov, J. Phys. Chem. B 113, 3453 (2009).

    Article  CAS  Google Scholar 

  23. V. V. Khramtsov, D. Marsh, L. Weiner, et al., Biochim. Biophys. Acta 1104, 317 (1992).

    Article  CAS  Google Scholar 

  24. A. B. Shishmakov, V. G. Kharchuk, O. V. Kuznetsova, et al., Russ. J. Phys. Chem. A 77, 548 (2003).

    Google Scholar 

  25. V. G. Kharchuk, L. Yu. Buldakova, A. B. Shishmakov, et al., Russ. J. Gen. Chem. 74, 101 (2004).

    Article  CAS  Google Scholar 

  26. A. T. Nikitaev, A. D. Pomogailo, N. D. Golubeva, et al., Kinet. Katal. 27, 709 (1986).

    CAS  Google Scholar 

  27. E. G. Kovaleva, L. S. Molochnikov, and I. N. Lipunov, Russ. J. Phys. Chem. A 74, 1262 (2000).

    Google Scholar 

  28. G. P. Vishnevskaya, R. Sh. Safin, and B. K. Radionov, Vysokomol. Soedin. B 29, 247 (1987).

    CAS  Google Scholar 

  29. G. P. Vishnevskaya, L. S. Molochnikov, and R. Sh. Safin, EPR in Ion Exchangers (Nauka, Moscow, 1992) [in Russian].

    Google Scholar 

  30. G. P. Vishnevskaya, R. Sh. Safin, E. N. Frolova, et al., Zh. Fiz. Khim. 68, 533 (1994).

    CAS  Google Scholar 

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Correspondence to E. G. Kovaleva.

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Original Russian Text © E.G. Kovaleva, L.S. Molochnikov, E.V. Parshina, A.B. Shishmakov, Yu.V. Mikushina, I.A. Kirilyuk, I.A. Grigor’ev, 2014, published in Khimicheskaya Fizika, 2014, Vol. 33, No. 6, pp. 27–36.

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Kovaleva, E.G., Molochnikov, L.S., Parshina, E.V. et al. Effect of the surface charge on the complexing and catalytic properties of Cu2+-containing composite materials based on zirconia and powdered cellulose. Russ. J. Phys. Chem. B 8, 317–325 (2014). https://doi.org/10.1134/S199079311403021X

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  • DOI: https://doi.org/10.1134/S199079311403021X

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