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Reactivity of hydrogen peroxide with respect to ozone

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
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Abstract

Ozone decomposition in pure water, H2O2 aqueous solution, and water with ethanol admixture is investigated. It is found that, in the presence of H2O2, ozone decomposes significantly faster than in pure water owing to its interaction with H2O2. The effective rate constant (k = (0.023 ± 0.002) l/(mol s)) is determined, which is much higher than the overall rate constant of ozone decomposition in water, but much lower than the specific rate of ozone decomposition in water in the presence of common organic admixtures (fulvic acids, ethanol). It is concluded that at the combined use of O3 and H2O2 for the decomposition of organic admixtures in water, the contribution of their interaction with each other is little.

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References

  1. Yu. I. Skurlatov, Usp. Khim. 60(3), 575 (1991).

    CAS  Google Scholar 

  2. Ozone and Other Ecologically Pure Oxidants. Science and Engineering. Proceedings of the 30th All-Russia Seminar, Moscow (MAKS Press, Moscow, 2008).

  3. V. A. Petrenev, Tsellyul. Bumaga Karton, Nos. 1–2, 14 (1996).

  4. T. R. Card and R. L. Purdom, in Ozone World Congr., Ozone in Wastewater Treatment (New York, 1989), vol. 2, p. 281.

    Google Scholar 

  5. G. Reynolds, N. Graham, A. Perry, and R. G. Rice, Ozone Sci. Eng. 11, 339 (1989).

    Article  CAS  Google Scholar 

  6. W. H. Glaze and J.-W. Kang, Ind. Eng. Chem. Res. 28, 1573 (1989).

    Article  CAS  Google Scholar 

  7. S. D. Razumovskii, Russ. J. Phys. Chem. A 70, 1237 (1996).

    Google Scholar 

  8. Ozone and Methods of Efferent Therapy in Medicine, Proceedings, VINITI, News of Science and Engineering, Ser. Medicine (Moscow, 2000) [in Russian].

  9. T. G. Shcherbatyuk, Candidate’s Dissertation in Medical Science (Nizhni Novgorod Medical Academy, Nizhni Novgorod, 1997).

  10. S. D. Razumovskii, M. L. Konstantinova, and V. Ya. Zaitsev, Biomed. Khim. 56, 380 (2010).

    Google Scholar 

  11. S. D. Razumovskii, M. L. Konstantinova, T. V. Grinevich, and G. V. Korovina, Kinet. Catal. 51, 492 (2010).

    Article  CAS  Google Scholar 

  12. B. G. Ershov and P. A. Morozov, Russ. J. Phys. Chem. A 83, 1295 (2009).

    Article  CAS  Google Scholar 

  13. U. von Gutten, Water Res. 37, 1443 (2003).

    Article  Google Scholar 

  14. K. Sehested, H. Gorfitzen, J. Holcman, H. Fischer, and E. J. Hart, Environ. Sci. Res. 25, 1589 (1991).

    Article  CAS  Google Scholar 

  15. M. L. Konstaninova, S. D. Razumovskii, and G. E. Zaikov, Izv. Akad. Nauk, Ser. Khim., No. 6, 1443 (1992).

  16. S. D. Razumovskii and G. E. Zaikov, Ozone and its Reactions with Organic Compounds (Nauka, Moscow, 1974), p. 214 [in Russian].

    Google Scholar 

  17. S. D. Razumovskii, M. L. Konstantinova, and V. V. Podmaster’ev, Izv. Akad. Nauk, Ser. Khim., No. 1, 60 (1996).

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

    S. D. Razumovskii

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    T. V. Grinevich & G. V. Korovina

Authors
  1. S. D. Razumovskii
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  2. T. V. Grinevich
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  3. G. V. Korovina
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Correspondence to S. D. Razumovskii.

Additional information

Original Russian Text © S.D. Razumovskii, T.V. Grinevich, G.V. Korovina, 2011, published in Khimicheskaya Fizika, 2011, Vol. 30, No. 10, pp. 54–56.

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Razumovskii, S.D., Grinevich, T.V. & Korovina, G.V. Reactivity of hydrogen peroxide with respect to ozone. Russ. J. Phys. Chem. B 5, 797–799 (2011). https://doi.org/10.1134/S1990793111090211

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  • DOI: https://doi.org/10.1134/S1990793111090211

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