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The rate constants of singlet oxygen collision-induced emission at 634 and 703 nm wavelengths

  • M. V. Zagidullin
Structure of Chemical Compounds. Spectroscopy

Abstract

Absolute spectral luminosity from an O2–O2(a)-H2O gas flow formed by a chemical singlet oxygen generator was measured at 600–800 and 1230–1310 nm wavelengths. The results were used to determine the rate constants for O2(a, 0) + O2(a, 0) → O2(X, 0) + O2(X, 0) + hν (λ = 634 nm) and O2(a, 0) + O2(a, 0) → O2(X, 1) + O2(X, 0) + hν (λ = 703 nm) collision-induced emission ((6.72 ± 0.8) × 10−23 and (7.17 ± 0.8) × 10−23 cm3/s, respectively).

Keywords

singlet oxygen collision-induced emission 

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  1. 1.Lebedev Physical Institute, Samara BranchRussian Academy of SciencesSamaraRussia

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