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Russian Journal of Physical Chemistry B

, Volume 4, Issue 6, pp 904–908 | Cite as

The mechanism of decomposition of secondary nitramines in solution

Kinetics and Mechanism of Chemical Reactions. Catalysis
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Abstract

It was found that, like hexogen, octogen, ketohexogen, and Tetryl decomposed in easily oxidizable solvents by the chain mechanism, whereas the decomposition of dimethylnitramine and framework nitramine CL-20 was a monomolecular reaction in solution.

Keywords

secondary nitramines solutions decomposition mechanism 

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References

  1. 1.
    Yuanjie Shu, V. V. Dubikhin, G. M. Nazin, and G. B. Manelis, Dokl. Akad. Nauk 368, 357(1999).Google Scholar
  2. 2.
    Yuanjie Shu, V. V. Dubikhin, G. M. Nazin, and G. B. Manelis, in Proc. of the 30th Intern. Annual Conf. of ICT (DWS Werbeagenter und Verlag, Karlsruhe, 1999), p. 59.Google Scholar
  3. 3.
    Yuanjie Shu, V. V. Dubikhin, V. G. Matveev, G. M. Nazin, and G. B. Manelis, Izv. Akad. Nauk, Ser. Khim., No. 8, 13 (2002).Google Scholar
  4. 4.
    Y. P. Agrawal, Prog. Energy Combust. Sci. 24, 1 (1998).CrossRefGoogle Scholar
  5. 5.
    Yu. Ya. Maksimov, Theory of Explosive Substances (Vysshaya Shkola, Moscow, 1967), p. 73 [in Russian].Google Scholar
  6. 6.
    J. C. Oxley, A. B. Kooh, R. Szekeres, and W. Zheng, J. Phys. Chem. 98, 7004 (1994).CrossRefGoogle Scholar
  7. 7.
    J. M. Flournoy, J. Phys. Chem. 36, 1106 (1962).CrossRefGoogle Scholar
  8. 8.
    B. L. Korsunskii and F. I. Dubovitskii, Dokl. Akad. Nauk SSSR 155, 402 (1964).Google Scholar
  9. 9.
    B. L. Korsunskii, F. I. Dubovitskii, and G. V. Sitonina, Dokl. Akad. Nauk SSSR 174, 1126 (1964).Google Scholar
  10. 10.
    F. I. Dubovitskii and B. L. Korsunskii, Usp. Khim. 50, 1828 (1988).Google Scholar
  11. 11.
    B. Korsounskii, V. Nedelko, N. Chukanov, T. Larikova, and F. Volk, in Proc. of the 30th Intern. Annual Conf. of ICT (DWS Werbeagenter und Verlag, Karlsruhe, 1999), p. 64.Google Scholar
  12. 12.
    Yue Ling, Zehua Tang, and Heming Xiao, in Proc. of the 17th Intern. Pyrotech. Sem. Combined with the 2nd Beijing Intern. Symp. on Pyrotech. and Explosives, Beijing, China (Beijing Inst. Technol., Beijing, 1991), Vol. 1, p. 466.Google Scholar

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© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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