Abstract
The kinetics and mechanism of corundum formation from hydrargillite in an water medium under sub- and supercritical conditions in the presence of manganese ions was studied. The conclusion was drawn that corundum structure formation with the insertion and uniform distribution of manganese ions occurred thanks to solid-state mobility, which appeared under the conditions of reversible dehydroxylation in the interaction of a solid matrix with an water fluid. Complex defects containing Mn2+, Mn3+, and Mn4+ ions along with hydroxyl groups and oxygen vacancies were formed when corundum was doped with manganese ions in different charge states because of redox processes in a supercritical water fluid. Corundum doped with manganese exhibited ferromagnetic properties at room temperature.
Similar content being viewed by others
References
L. V. Usov, G. P. Panasyuk, and V. B. Lazarev, Zh. Neorg. Khim. 35, 2464 (1990).
L. V. Usov, G. P. Panasyuk, and V. B. Lazarev, Zh. Neorg. Khim. 35, 2741 (1990).
V. B. Lazarev, G. P. Panasyuk, and M. N. Danchevskaya, Zh. VKhO Mendeleeva 36, 706 (1991).
L. V. Usov, Zh. Neorg. Khimii 41, 1447 (1996).
V. B. Lazarev, G. P. Panssyuk, I. L. Voroshilov, G. P. Budova, M. N. Danchevskaya, S. N. Torbin, and Yu. D. Ivakin, Ind. Eng. Chem. Res. 35, 3721 (1996).
M. N. Danchevskaya, O. G. Ovchinnikova, Yu. D. Ivakin, and G. P. Muravieva, Zh. Fiz. Khim. 74, 1391 (2000) [Russ. J. Phys. Chem. 74, 1250 (2000)].
M. N. Danchevskaya, Yu. D. Ivakin, S. N. Torbin, G. P. Pansyuk, V. N. Belan, and I. L. Voroshilov, High Press. Res. 20, 229 (2001).
K. Torkar and H. Krischner, Mh. Chem. 91, 764 (1960).
P. K. Panda, V. A. Jaleel, and S. Usha Devi, J. Mater. Sci. 41, 8386 (2006).
K. Sue, M. Suzuki, K. Arai, T. Ohashi, H. Ura, K. Matsui, Y. Hakuta, H. Hayashi, M. Watanabe, and T. Hiaki, Green Chem. 8, 634 (2006).
M. N. Danchevskaya, Yu. D. Ivakin, G. P. Muravieva, and A. I. Zui, Vestn. Mosc. Univ., Ser. 2: Khimiya 38(1), 21 (1997).
M. N. Danchevskaya, S. N. Torbin, Yu. D. Ivakin, and G. P. Muravieva, J. Phys.: Condens. Matter 16, 1187 (2004).
O. V. Al’myasheva, E. N. Korytkova, A. V. Maslov, and V. V. Gusarov, Neorg. Mater. 41, 540 (2005) [Inorg. Mater. 41, 460 (2005)].
M. N. Danchevskaya, Yu. D. Ivakin, L. F. Martynova, A. I. Zuy, G. P. Muravieva, and V. B. Lazarev, J. Thermal Analys. 46, 1215 (1996).
Yu. D. Ivakin, A. I. Zui, G. P. Murav’eva, and M. N. Danchevskaya, Vestn. Mosc. Univ., Ser. 2: Khimiya 42, 258 (2001).
Yu. D. Ivakin, M. N. Danchevskaya, and G. P. Muravieva, in Proc. of the 11the Eur. Meeting on Supercritical Fluids Reactions, Materials and Natural Products Processing (Barcelona, Spain, 2008), p. 6.
S. Ono, G. Yamagushi, H. Yanagida, and T. Shimizu, J. Ceram. Assos. Jpn. 76(7), 207 (1968).
Yu. D. Ivakin, G. P. Muravieva, and M. N. Danchevskaya, High Press. Res. 20, 87 (2001).
M. N. Danchevskaya, Yu. D. Ivakin, and O. G. Ovchin-nikova, Vestn. Mosc. Univ., Ser. 2: Khimiya 44, 287 (2003).
B. V. Erofeev, Dokl. Akad. Nauk SSSR 52, 515 (1946).
M. I. F. Macedo, C. A. Bertran, and C. C. Osawa, Eng. Chem. Mat. Sci. 42, 2830 (2007).
C. S. Nordahl and G. L. Messing, Thermochim. Acta 318, 187 (1998).
Yu. D. Ivakin, M. N. Danchevskaya, S. N. Torbin, V. A. Kreisberg, and L. F. Martynova, in Proc. of the 7th Meeting on Supercritical Fluids Particles Design, Materials and Natural Products Processing (Antibes, France, 2000), vol. 1, p. 525.
Zh. Syushe, Physical Chemistry of Semiconductors (Metallurgiya, Moscow, 1969) [in Russian].
V. N. Kuklina, E. A. Levitskii, L. M. Plyasova, and V. I. Zharkov, Kinet. Katal. 13, 1269 (1972).
M. Pyzalski and M. Wojcik, J. Thermal Analys. 36, 2147 (1990).
M. Pijolat, M. Dauzat, and M. Soustelle, Thermochim. Acta 122, 71 (1987).
Yu. D. Ivakin, M. N. Danchevskaya, G. P. Murav’eva, and S. N. Torbin, Vestn. Mosc. Univ., Ser. 2: Khimiya 38, 312 (1997).
M. N. Danchevskaya, Yu. D. Ivakin, S. N. Torbin, and G. P. Muravieva, J. Supercritical Fluids 42, 419 (2007).
A. I. Zui, Candidate’s Dissertation in Chemistry (1997).
M. N. Danchevskaya, Yu. D. Ivakin, O. G. Ovchinnikova, and V. N. Smirnov, J. Non-Cryst. Solids 149, 46 (1992).
Yu. D. Ivakin, M. N. Danchevskaya, O. G. Ovchinnikova, and G. P. Muravieva, J. Mater. Sci. 41, 1377 (2006).
M. N. Danchevskaya, S. N. Torbin, V. A. Kreisberg, and E. V. Yazeva, in Proc. of the 8th Intern. Meeting of Supercritical Fluids, Chemical Reactivity and Material Processing in Supercritical Fluids, Bordeaux, France, 14–17 Apr. 2002 (2002), Vol. 2, p. 675.
R. P. Bashuk and S. V. Grum-Grzhimailo, in Crystal Spectroscopy, Collected vol. (Nauka, Moscow, 1966), p. 204 [in Russian].
E. G. Valyashko, S. V. Grum-Grzhimailo, I. M. Kutovoi, V. N. Mednikova, and R. K. Sviridova, in Crystal Spectroscopy, Collected vol. (Nauka, Moscow, 1966), p. 211 [in Russian].
D. T. Sviridov, R. K. Sviridova, and Yu. F. Smirnov, Optical Spectra of Transitional Metals in Crystals (Nauka, Moscow, 1976) [in Russian].
S. Geschwind, P. Kisliuk, M. P. Klein, J. P. Remeika, and D. L. Wood, Phys. Rev. 126, 1684 (1962).
B. R. Jovanic, J. Luminescence 75, 171 (1997).
A. Lever, Inorganic Electronic Spectroscopy (Elsevier, Amsterdam, New York, 1985; Mir, Moscow, 1987), Vol. 2.
N. Mironova, V. Skvortsova, A. Smirnov, and L. Cugunov, Opt. Mater. 6, 225 (1996).
E. Hanamura, Y. Kawabe, H. Takashima, T. Sato, and A. Tomita, J. Nonlinear Opt. Phys. Mater. 12, 467 (2003).
K. H. Hsu, M. R. Yang, and K. S. Chen, J. Mater. Sci.: Mater. Electronics 9, 283 (1998).
M. Yu, J. Lin, Y. H. Zhou, and S. B. Wang, Mater. Lett. 56, 1007 (2002).
Ya. Zhydachevskii, A. Durygin, V. Drozd, A. Suchocki, D. Sugak, and J. Wrobel, J. Phys.: Condens. Matter 20, 095204 (2008).
G. B. Loutts, M. Warren, L. Taylor, R. R. Rakhimov, H. R. Ries, G. Miller, M. A. Noginov, M. Curley, N. Noginova, N. Kikhtarev, H. J. Caulfield, and P. Venkateswarlu, Phys. Rev. B 57, 3706 (1998).
D. S. McClure, Solid State Phys. 9, 399 (1959).
K. H. Lee and J. J. H. Crawford, Phys. Rev. B 15, 4065 (1977).
K. H. Lee and J. H. Crawford, Jr., Phys. Rev. B 19, 3217 (1979).
B. D. Evans and M. Stapelbroek, Phys. Rev. B 18, 7089 (1978).
V. S. Kortov, I. I. Mil’man, S. V. Nikiforov, and V. E. Pelenev, Fiz. Tverd. Tela 45, 1202 (2003) [Phys. Solid State 45, 1260 (2003)].
Y. H. Zhou, J. Lin, S. B. Wang, and H. J. Zhang, Opt. Mater. 20, 13 (2002).
S. P. Feofilov, A. B. Kulinkin, A. B. Kutsenko, and R. I. Zakharchenya, J. Luminescence 76, 217 (1998).
A. Krause and E. Dinjus, J. Supercritical Fluids 39, 362 (2007).
T. Sato, M. Watanabe, J. Smith, T. Adschiri, and K. Arai, J. Supercritical Fluids 28, 69 (2004).
S. V. Grum-Grzhimailo, Zap. Vses. Min. Obshch. 6(1), 175 (1958).
S. V. Grum-Grzhimailo, Dokl. Akad. Nauk SSSR 60, 1377 (1948).
Author information
Authors and Affiliations
Additional information
Original Russian Text © Yu.D. Ivakin, M.N. Danchevskaya, O.G. Ovchinnikova, G.P. Murav’eva, V.A. Kreisberg, 2008, published in Sverkhkriticheskie Flyuidy: Teoriya i Praktika, 2008, Vol. 3, No. 4, pp. 11–34.
Rights and permissions
About this article
Cite this article
Ivakin, Y.D., Danchevskaya, M.N., Ovchinnikova, O.G. et al. The kinetics and mechanism of doped corundum structure formation in an water fluid. Russ. J. Phys. Chem. B 3, 1019–1034 (2009). https://doi.org/10.1134/S199079310907001X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S199079310907001X