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Polymeric and Low-Molecular Stabilizers for Au Nanoparticles in a Diblock Copolymer Matrix

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Abstract

An effect of several polymeric stabilizers on the composites based on a diblock copolymer of styrene and 2-vinyl pyridine and spherical Au nanoparticles has been studied. Among the tested substances were thiol-terminated polystyrene, thiol-terminated poly(2-vinyl pyridine), diblock copolymers of styrene with 2- and 4-vinyl pyridine, and decanethiol as a typical low molecular mass stabilizer. Thin composite films with a microphase-separated cylindrical morphology have been prepared and characterized by atomic force and scanning electron microscopy to describe the surface morphology and nanoparticle distribution in the block copolymer matrix. In all the cases, the nanoparticles were selectively positioned either within vinyl pyridine domains or at the domain boundaries. The most effective stabilization of Au nanoparticles, both regarding their location and prevention of aggregation, was provided by the diblock copolymers.

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References

  1. M. Shimomura and T. Sawadaishi, Curr. Opin. Colloid Interface Sci. 6, 11 (2001).

    Article  CAS  Google Scholar 

  2. A. Biswas, I. S. Bayer, A. S. Biris, T. Wang, E. Dervishi, and F. Faupel, Adv. Colloid Interface Sci. 170, 2 (2012).

    Article  CAS  PubMed  Google Scholar 

  3. D. J. Norris and M. G. Bawendi, Phys. Rev. B 53, 16338 (1996).

    Article  CAS  Google Scholar 

  4. E. Hutter and J. H. Fendler, Adv. Mater. 16, 1685 (2004).

    Article  CAS  Google Scholar 

  5. S. Seo, M. R. Gartia, and G.L. Liu, Nanoscale 6, 11795 (2014).

    Article  CAS  PubMed  Google Scholar 

  6. L. Polavarapu, J. Perez-Juste, Q.-H. Xu, and L. M. Liz-Marzan, J. Mater. Chem. C 2, 7460 (2014).

    Article  CAS  Google Scholar 

  7. A. Kuzyk, R. Schreiber, Z. Fan, G. Pardatscher, E.-M. Roller, A. Hogele, F. C. Simmel, A. O. Govorov, and T. Liedl, Nature 483, 311 (2012).

    Article  CAS  PubMed  Google Scholar 

  8. S. Zhang, G. Leem, L. Srisombat, and T. R. Lee, J. Am. Chem. Soc. 130, 113 (2008).

    Article  CAS  PubMed  Google Scholar 

  9. M. Karg, N. Schelero, C. Oppel, M. Gradzielski, T. Hellweg, and R. von Klitzing, Chem.-Eur. J. 17, 4648 (2011).

    Article  CAS  PubMed  Google Scholar 

  10. C. R. Bullen and P. Mulvaney, Nano Lett. 4, 2303 (2004).

    Article  CAS  Google Scholar 

  11. P. J. G. Goulet, G. R. Bourret, and R. B. Lennox, Langmuir 28, 2909 (2012).

    Article  CAS  PubMed  Google Scholar 

  12. Z. Fan, M. K. Serrano, A. Schaper, S. Agarwal, and A. Greiner, Adv. Mater. 27, 3888 (2015).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  13. A. M. Alkilany, A. C. Caravana, M. A. Hamaly, K. T. Lerner, and L. B. Thompson, J. Colloid Interface Sci. 461, 39 (2016).

    Article  CAS  PubMed  Google Scholar 

  14. A. A. Ezhov, Y. I. Derikov, G. A. Shandryuk, E. V. Chernikova, S. S. Abramchuk, A. S. Merekalov, G. N. Bondarenko, and R. V. Talroze, Polym. Sci., Ser. C 58, 102 (2016).

    Article  CAS  Google Scholar 

  15. A. A. Ezhov, Y. I. Derikov, E. V. Chernikova, S. S. Abramchuk, G. A. Shandryuk, A. S. Merekalov, V. I. Panov, and R. V. Talroze, Polymer 77, 113 (2015).

    Article  CAS  Google Scholar 

  16. Y. I. Derikov, I. Yu. Kutergina, G. A. Shandryuk, A. S. Merekalov, M. V. Gorkunov, S. S. Abramchuk, and A. A. Ezhov, Polym. Sci., Ser. A 56, 488 (2014).

    Article  CAS  Google Scholar 

  17. W. A. Lopes and H. M. Jaeger, Nature 414, 735 (2001).

    Article  CAS  PubMed  Google Scholar 

  18. S. Singh, P. Samanta, R. Srivastava, A. Horechyy, U. Reuter, M. Stamm, H.-L. Chend, and B. Nandan, Phys. Chem. Chem. Phys. 19, 27651 (2017).

    Article  CAS  PubMed  Google Scholar 

  19. B. K. Kuila, E. B. Gowd, and M. Stamm, Macromolecules 43, 7713 (2010).

    Article  CAS  Google Scholar 

  20. J. Q. Lu and S. S. Yi, Langmuir 22, 3951 (2006).

    Article  CAS  PubMed  Google Scholar 

  21. B. J. Kim, J. Bang, C. J. Hawker, J. J. Chiu, D. J. Pine, S. G. Jang, S.-M. Yang, and E. J. Kramer, Langmuir 23, 12693 (2007).

    Article  CAS  PubMed  Google Scholar 

  22. C. Mantzaridis and S. Pispas, Macromol. Rapid Commun. 29, 1793 (2008).

    Article  CAS  Google Scholar 

  23. S. G. Jang, E. J. Kramer, and C. J. Hawker, J. Am. Chem. Soc. 133, 16986 (2011).

    Article  CAS  PubMed  Google Scholar 

  24. S. G. Jang, A. Khan, C. J. Hawker, and E. J. Kramer, Macromolecules 45, 1553 (2012).

    Article  CAS  Google Scholar 

  25. W. Lee, S. Y. Lee, X. Zhang, O. Rabin, and R. M. Briber, Nanotechnology 24, 045305 (2013).

    Article  CAS  PubMed  Google Scholar 

  26. S. Chang, S. Singamaneni, E. Kharlampieva, S. L. Young, and V. V. Tsukruk, Macromolecules 42, 5781 (2009).

    Article  CAS  Google Scholar 

  27. Z. Liu, H. Huang, and T. He, Small 9, 505 (2013).

    Article  CAS  PubMed  Google Scholar 

  28. E. B. Gowd, B. Nandan, M. K. Vyas, N. C. Bigall, A. Eychmueller, H. Schlorb, and M. Stamm, Nanotechnology 20, 415302 (2009).

    Article  CAS  Google Scholar 

  29. K. Tsutsumi, Y. Funaki, Y. Hirokawa, and T. Hashimoto, Langmuir 15, 5200 (1999).

    Article  CAS  Google Scholar 

  30. Y. V. Derikov, G. A. Shandryuk, R. V. Talroze, A. A. Ezhov, and Y. V. Kudryavtsev, Beilstein J. Nanotechnol. 9, 616 (2018).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  31. Y. I. Derikov, C. Abetz, G. A. Shandryuk, R. V. Talroze, A. A. Ezhov, V. Abetz, Y. V. Kudryavtsev, and M. A. Osipov, Polym. Sci., Ser. C 60, 78 (2018).

    Article  CAS  Google Scholar 

  32. E. K. Plyler and R. S. Mulliken, J. Am. Chem. Soc. 81, 823 (1959).

    Article  CAS  Google Scholar 

  33. X.-P. Qiu and F. M. Winnik, Macromolecules 40, 872 (2007).

    Article  CAS  Google Scholar 

  34. A. E. Saunders, M. B. Sigman, Jr., and B. A. Korgel, J. Phys. Chem. B 108, 193 (2004).

    Article  CAS  Google Scholar 

  35. E. B. Gowd, M. Böhme, and M. Stamm, IOP Conf. Ser.: Mater. Sci. Eng. 14, 012015 (2010).

    Article  CAS  Google Scholar 

  36. G. Singh, K. G. Yager, D.-M. Smilgies, M. M. Kulkarni, D. G. Bucknall, and A. Karim, Macromolecules 45, 7107 (2012).

    Article  CAS  Google Scholar 

  37. A. Knoll, R. Magerle, and G. Krausch, J. Chem. Phys. 120, 1105 (2004).

    Article  CAS  PubMed  Google Scholar 

  38. B. J. Kim, G. H. Fredrickson, and E. J. Kramer, Macromolecules 41, 436 (2008).

    Article  CAS  Google Scholar 

  39. C. Liedel, K. A. Schindler, M. J. Pavan, C. Lewin, C. W. Pester, M. Ruppel, V. S. Urban, R. Shenhar, and A. Böker, Small 9, 3276 (2013).

    CAS  PubMed  Google Scholar 

  40. J. Lee, J. Kwak, C. Choi, S. H. Han, and J. K. Kim, Macromolecules 50, 9373 (2017).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    Y. I. Derikov, O. N. Karpov, G. A. Shandryuk, A. A. Ezhov & Y. V. Kudryavtsev

  2. Helmholtz-Zentrum Geesthacht, Institute of Polymer Research, Geesthacht, 21502, Germany

    C. Abetz & V. Abetz

  3. Faculty of Physics, Lomonosov Moscow State University, Moscow, 119991, Russia

    A. A. Ezhov

  4. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    Y. V. Kudryavtsev

  5. Institute of Physical Chemistry, University of Hamburg, Hamburg, 20146, Germany

    V. Abetz

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  1. Y. I. Derikov
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  2. C. Abetz
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  3. O. N. Karpov
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  4. G. A. Shandryuk
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  5. A. A. Ezhov
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  6. Y. V. Kudryavtsev
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  7. V. Abetz
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Correspondence to Y. I. Derikov.

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Derikov, Y.I., Abetz, C., Karpov, O.N. et al. Polymeric and Low-Molecular Stabilizers for Au Nanoparticles in a Diblock Copolymer Matrix. Polym. Sci. Ser. C 60 (Suppl 1), 240–250 (2018). https://doi.org/10.1134/S1811238218020054

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  • DOI: https://doi.org/10.1134/S1811238218020054

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