Polymer Science Series C

, Volume 57, Issue 1, pp 120–127 | Cite as

Reversible addition-fragmentation chain transfer (RAFT) (Co)polymerization of isobornyl acrylate

  • E. E. Kulikov
  • S. D. Zaitsev
  • Yu. D. Semchikov
Article

Abstract

Controlled/living radical homopolymerization of isobornyl acrylate and its copolymerization with styrene with reversible chain transfer via the addition-fragmentation mechanism in the presence of benzyl dithiobenzoate have been studied. It has been shown that the (co)polymerization proceeds through living chains, a result that is confirmed by a linear increase in the number-average molecular weight with conversion and by low polydispersity indexes. With the use of polymer RAFT agents block copolymers have been synthesized. Amphiphilic copolymers have been obtained through acid hydrolysis of isobornyl acrylate units in copolymers of various microstructures.

Keywords

Block Copolymer Polymer Science Series Benzoyl Peroxide Reversible Addition Fragmentation Chain Transfer Reversible Addition Fragmentation Chain Transfer Agent 

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References

  1. 1.
    Polymer Handbook, Ed. by J. Brandrup, E. H. Immergut, E. A. Grulke (Wiley, New York, 1999).Google Scholar
  2. 2.
    V. Coessens, T. Pintauer, and K. Matyjaszewski, Prog. Polym. Sci. 26(3), 337 (2001).CrossRefGoogle Scholar
  3. 3.
    C. Khoury, G. A. Mensing, and D. J. Beebe, Lab-on-a-Chip 2, 50 (2002).CrossRefGoogle Scholar
  4. 4.
    S. A. Bulgakova, M. M. Jons, A. E. Pestov, M. N. Toropov, N. I. Chkhalo, S. A. Gusev, E. V. Skorokhodov, N. N. Salashchenko, Russ. Microelectron. 42(3), 165 (2013).CrossRefGoogle Scholar
  5. 5.
    A. Ovabeek, J. Coat. Technol. Res. 7(1), 1 (2010).CrossRefGoogle Scholar
  6. 6.
    M. D. C. Lopez-Garcia, D. J. Beebe, and W. C. Crone, J. Appl. Polym. Sci. 105(4), 1894 (2007).CrossRefGoogle Scholar
  7. 7.
    P. Choi, P. F. Fu, and L. J. Guo, Adv. Funct. Mater. 17(5), 65 (2007).CrossRefGoogle Scholar
  8. 8.
    Controlled and Living Polymerization: From Mechanisms to Applications, Ed. by A. H. E. Muller and K. Matyjaszewski (Wiley-Interscience, New York, 2009).Google Scholar
  9. 9.
    R. E. Richard, M. Schwarz, S. Ranade, A. K. Chan, K. Matyjaszewski, B. Sumerlin, Biomacromolecules 6(6), 3410 (2005).CrossRefGoogle Scholar
  10. 10.
    W. M. Moreau, Semiconductor Lithography. Principles, Practices, and Materials (Plenum Press, New York, 1988).CrossRefGoogle Scholar
  11. 11.
    A. Weissberger, E. S. Proskauer, J. A. Riddick, and E. E. Toops, Technique of Organic Chemistry (Wiley-Interscience, New York, 1955).Google Scholar
  12. 12.
    E. V. Chernikova, A. V. Tarasenko, E. S. Garina, and V. B. Golubev, Polym. Sci., Ser. A 48(10), 1046 (2006).CrossRefGoogle Scholar
  13. 13.
    T. Kelen and F. J. Tudos, J. Macromol. Sci., Chem. 9(1), 1 (1975).CrossRefGoogle Scholar
  14. 14.
    M. Fineman and S. D. Ross, J. Polym. Sci., Part A: Polym. Chem. 9(2), 259 (1950).Google Scholar
  15. 15.
    Yu. E. Begantsova, F. S. Malyshev, S. D. Zaitsev, Yu. D. Semchikov, Polym. Sci., Ser. A 44(4), 329 (2002).Google Scholar
  16. 16.
    Handbook of RAFT Polymerization, Ed. by C. Barner, Kowollik Wiley-Interscience, New York, 2008).Google Scholar
  17. 17.
    Y. K. Chong, J. Krstina, T. P. T. Le, G. Moad, A. Postma, E. Rizzardo, S. H. Thang, Macromolecules 36(7), 2256 (2003).CrossRefGoogle Scholar
  18. 18.
    S. D. Zaitsev, Yu. D. Semchikov, E. V. Vasil’eva, and L. V. Kurushina, Polym. Sci., Ser. B 54(3–4), 205 (2012).CrossRefGoogle Scholar
  19. 19.
    C. Barner-Kowollik, M. L. Coote, T. P. Davis, L. Radom, P. Vana, J. Polym. Sci., Part A: Polym. Chem. 41(18), 2828 (2003).CrossRefGoogle Scholar
  20. 20.
    Y. Kwak, A. Goto, Y. Tsujii, Y. Murata, K. Komatsu, T. Fukuda, Macromolecules 35(8), 3026 (2002).CrossRefGoogle Scholar
  21. 21.
    S. A. Bulgakova, D. A. Gurova, M. M. Jons, S. D. Zaitsev, E. E. Kulikov, E. V. Skorokhodov, M. N. Toropov, D. A. Pryahin, A. E. Pestov, N. I. Chkhalo, N. N. Salashchenko, Russ. Microelectron. 43(6), 392 (2014).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • E. E. Kulikov
    • 1
  • S. D. Zaitsev
    • 1
  • Yu. D. Semchikov
    • 1
  1. 1.Lobachevskii Nizhny Novgorod State UniversityNizhny NovgorodRussia

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