Polyurethane adhesives based on carborane-containing compounds
- 111 Downloads
The results are reported of studies of adhesives based on polyurethanes containing carborane groups. It is established by TGA methods that for polyurethane-carborane systems, total mass losses upon heating to 600°C are equal to 20%, whereas for adhesives free of carborane groups, such losses are equal to 80%. It is revealed that the properties of the adhesives studied are substantially affected by carborane isomeric structure. Compositions containing polyestercarboranes with m-carborane provide higher stability of adhesive joints to elevated temperatures. Results of the study of the kinetics of gas evolution are reported and the scheme of the two-stage mechanism of thermal degradation is proposed. Results of IR spectroscopy analysis show that upon the curing of carborane-containing polyurethane composition, isocyanate groups of polyisocyanate first interact with hydroxyl groups of polyestercarborane, which results in the formation of macrodiisocyanates. Subsequent heating to 350°C leads to further curing of compositions that involves carborane, ester, and polyurethane groups.
KeywordsPolyurethane Polymer Science Series Thermal Aging Adhesive Joint Organotin Compound
Unable to display preview. Download preview PDF.
- 1.Valetskii, P.M. and Petrova, A. P., Klei. Germetiki. Tekhnologii, 2005, no. 3, p. 2.Google Scholar
- 2.Sidorenko, V. I., Cand. Sci. (Engineering) Dissertation, Moscow: Inst. Of Organoelement Compounds, 1981.Google Scholar
- 3.Lipatova T. E. and Bakalo, L. A. in Uspekhi khimii poliuretanov (Progress in Chemistry of Polyurethanes), Kiev: Naukova Dumka, 1972, p. 195.Google Scholar