Polymer Science, Series B

, Volume 59, Issue 6, pp 708–717 | Cite as

Linear-Dendritic Block Copolymers Based on N-Isopropylacrylamide and Perfluorinated Polyphenylenegermane: Synthesis and Properties at Various Interfacial Boundaries

  • O. G. Zamyshlyayeva
  • E. A. Smirnov
  • N. S. Zakharycheva
Functional Polymers

Abstract

It is shown that linear-dendritic block copolymers poly(N-isopropylacrylamide)–block–polyphenylenegermane can be prepared by the polymerization of N-isopropylacrylamide in the presence of bis(pentafluorophenyl)germane followed by activated polycondensation with tris(pentafluorophenyl)germane. The properties of the dilute solutions and Langmuir monolayers of the functional polymers and the linear-dendritic block copolymers of N-isopropylacrylamide are studied.

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References

  1. 1.
    E. H. Sprecht, A. Neuman, and H. T. Neher, US Patent No. 2773063 (1956).Google Scholar
  2. 2.
    I. Y. Galaev and B. Matiason, Enzyme Microb. Technol. 15, 354 (1993).CrossRefGoogle Scholar
  3. 3.
    I. Yu. Galaev, Russ. Chem. Rev. 64, 471 (1995).CrossRefGoogle Scholar
  4. 4.
    H. G. Schild, Prog. Polym. Sci. 17, 163 (1992).CrossRefGoogle Scholar
  5. 5.
    S. Dinçer, Z. M. O. Rzaev, and E. Pişkin, J. Polym. Res. 13, 121 (2006).CrossRefGoogle Scholar
  6. 6.
    J. H. Priest, R. J. Murray, R. J. Nelson, and A. S. Hoffman, ACS Symp. Ser. 350, 255 (1987).CrossRefGoogle Scholar
  7. 7.
    A. Tuncel, D. Demirgöz, S. Patir, and E. Pişkin, J. Appl. Polym. Sci. 84, 2060 (2002).CrossRefGoogle Scholar
  8. 8.
    Z. M. O. Rzaev, S. Dinçer, and E. Pişkin, Prog. Polym. Sci. 32, 534 (2007).CrossRefGoogle Scholar
  9. 9.
    S. Akerman, P. Vinikka, B. Sfarfar, K. Putkonen, K. Jarvinen, K. Kontturi, J. Nasman, A. Urtti, and P. Paronen, Int. J. Pharm. 164, 29 (1988).CrossRefGoogle Scholar
  10. 10.
    E. R. Gasilova, O. G. Zakharova, A. V. Kozlov, A. P. Filippov, and Yu. D. Semchikov, Polym. Sci., Ser. A 51 (5), 492 (2009).CrossRefGoogle Scholar
  11. 11.
    O. G. Zakharova, M. A. Simonova, E. V. Tarasova, A. P. Filippov, and Yu. D. Semchikov, Int. J. Polym. Anal. Charact. 14, 47 (2009).CrossRefGoogle Scholar
  12. 12.
    A. Weissberger, E. S. Proskauer, J. A. Riddick, and E. E. Toops, Technique of Organic Chemistry (Wiley- Intersci., New York, 1955).Google Scholar
  13. 13.
    S. Fujishige, Polym. J. 19, 297 (1987).CrossRefGoogle Scholar
  14. 14.
    F. R. Mayo, J. Am. Chem. Soc. 65, 2324 (1943).CrossRefGoogle Scholar
  15. 15.
    O. G. Zamyshlyayeva, A. A. Simonova, and A. P. Filippov, Int. J. Polym. Anal. Charact. 20 (3), 223 (2015).CrossRefGoogle Scholar
  16. 16.
    S. D. Zaitsev, A. A. Turshatov, G. M. Pavlov, Yu. D. Semchikov, M. N. Bochkarev, and O. G. Zakharova, Polym. Sci., Ser. B 46 (7–8), 241 (2004).Google Scholar
  17. 17.
    O. G. Zakharova, Yu. V. Golyagina, and Yu. D. Semchikov, Russ. J. Appl. Chem. 82, 644 (2009).CrossRefGoogle Scholar
  18. 18.
    K. V. Kir’yanov, Yu. D. Semchikov, M. N. Bochkarev, and S. D. Zaitsev, Polym. Sci., Ser. A 45 (5), 413 (2003).Google Scholar
  19. 19.
    E. I. Tiktopulo, V. E. Bychkova, J. Ricka, and O. B. Ptysin, Macromolecules 27, 2879 (1994).CrossRefGoogle Scholar
  20. 20.
    S. S. Rafikov, S. A. Pavlova, and I. I. Tverdokhlebova, Determination Methods of Molecular Weights and Polydispersity of High-molecular Compounds (Izv. AN SSSR, Moscow, 1963) [in Russian].Google Scholar
  21. 21.
    O. G. Zamyshlyayeva, O. S. Lapteva, M. A. Baten’kin, Yu. D. Semchikov, and N. B. Melnikova, Russ. Chem. Bull. 63, 1823 (2014).CrossRefGoogle Scholar
  22. 22.
    J. A. Walker and C. A. Vause, Sci. Am. 253, 98 (1987).CrossRefGoogle Scholar
  23. 23.
    S. I. Gusev, S. D. Zaitsev, Yu. D. Semchikov, and O. G. Zakharova, Russ. J. Appl. Chem. 79, 1338 (2006).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • O. G. Zamyshlyayeva
    • 1
  • E. A. Smirnov
    • 1
  • N. S. Zakharycheva
    • 2
  1. 1.National Research Nizhny Novgorod State UniversityNizhny NovgorodRussia
  2. 2.Research Institute of ChemistryNational Research Nizhny Novgorod State UniversityNizhny NovgorodRussia

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