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Polymer Science, Series B

, Volume 59, Issue 6, pp 650–654 | Cite as

Features of Reactions of Radical (Co)Polymerization of Methacryloylguanidine Trifluoroacetate in Various Solvents

  • M. R. Menyashev
  • V. A. Gerasin
  • A. I. Martynenko
  • N. A. Kleshcheva
  • N. I. Popova
  • N. A. Sivov
Polymerization

Abstract

A method for the synthesis of methacryloylguanidine trifluoroacetate was developed for the first time and its radical (co)polymerization was carried out in various solvents. The polymerization proceeds homogeneously in water, methanol, and DMSO up to high conversion and heterogeneously in acetone after reaching 20% conversion. For the first time, methacryloylguanidine trifluoroacetate and methylmethacrylate copolymers were synthesized in acetone and DMSO; the copolymerization constants for this system in acetone were determined to be r1 = 1.41 ± 0.24 and r2 = 0.11 ± 0.01. Preliminary biological tests showed a fairly high biocidal and fungicidal activity of the synthesized copolymers.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • M. R. Menyashev
    • 1
  • V. A. Gerasin
    • 1
  • A. I. Martynenko
    • 1
  • N. A. Kleshcheva
    • 1
  • N. I. Popova
    • 1
  • N. A. Sivov
    • 1
  1. 1.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

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