Abstract
We synthesized 2,6-poly(phenylquinoline)s, the elementary polymer unit of which contained alkyl carbazole or alkyl indolo[3,2-b]carbazole moieties with C12 and C18 alkyl side chains at nitrogen atoms and the oxygen or phenylamine bridge group between the quinoline cycles. The synthesized polymers form heat-resistant coatings, for which the temperature for 5% weight loss is higher than 450°С. It is demonstrated that introduction of 10 wt % of 2,1,3-benzothiadiazole to the poly(phenylquinoline)s leads to an increase in the photosensitivity of the composite as compared with the original polymers. Structural-morphological studies of the synthesized poly(phenylquinoline)s and their composites were carried out.
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Original Russian Text © N.V. Matyushina, V.M. Svetlichnyi, L.A. Myagkova, E.L. Aleksandrova, E.N. Popova, I.V. Gofman, M.E. Vylegzhanina, A.Ya. Volkov, T.E. Sukhanova, V.V. Kudryavtsev, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 6, pp. 461–473.
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Matyushina, N.V., Svetlichnyi, V.M., Myagkova, L.A. et al. Synthesis and Properties of New 2,6-Poly(phenylquinoline)s and Their Composites with 2,1,3-Benzothiadiazole. Polym. Sci. Ser. B 59, 718–729 (2017). https://doi.org/10.1134/S1560090417060021
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DOI: https://doi.org/10.1134/S1560090417060021