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Synthesis, properties, and application of surface-active block copolymers based on poly(ethylene oxide) and polyorganosiloxanes in the heterogeneous polymerization of styrene

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Abstract

A number of linear and comb-shaped organosilicon surfactants containing poly(ethylene oxide) blocks were synthesized and studied. The structures of the copolymers were varied systematically, and the obtained copolymers were characterized via elemental analysis, GPC, and 1H NMR. A comparative study of the surface activities of amphiphilic organosilicon block copolymers was performed. Their structures were shown to considerably affect the surface activities as well as the styrene polymerization rates and the sizes of microparticles obtained with the use of the studied copolymers as surfactants.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    V. V. Istratov & V. A. Vasnev

  2. Lomonosov State University of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    E. V. Milushkova & I. A. Gritskova

Authors
  1. V. V. Istratov
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  2. E. V. Milushkova
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  3. I. A. Gritskova
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  4. V. A. Vasnev
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Correspondence to V. V. Istratov.

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Original Russian Text © V.V. Istratov, E.V. Milushkova, I.A. Gritskova, V.A. Vasnev, 2014, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2014, Vol. 56, No. 6, pp. 528–534.

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Istratov, V.V., Milushkova, E.V., Gritskova, I.A. et al. Synthesis, properties, and application of surface-active block copolymers based on poly(ethylene oxide) and polyorganosiloxanes in the heterogeneous polymerization of styrene. Polym. Sci. Ser. B 56, 721–727 (2014). https://doi.org/10.1134/S1560090414060104

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  • DOI: https://doi.org/10.1134/S1560090414060104

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