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Polymer Science Series B

, Volume 56, Issue 2, pp 229–237 | Cite as

Composite proton-conducting membranes based on poly(ethylene glycol vinyl glycidyl ether)

  • M. V. Markova
  • D. M. Mognonov
  • L. V. Morozova
  • A. I. Mikhaleva
  • B. A. Trofimov
Polymer Membranes

Abstract

Composite proton-conducting membranes in the form of interpolymer films are prepared in an aqueous medium from sulfo-acid-modified poly(ethylene glycol vinyl glycidyl ether) and poly(vinyl alcohol). The initial poly(hydroxysulfo acid) is synthesized through the radical polymerization of ethylene glycol vinyl glycidyl ether followed by modification with sodium sulfite via epoxy groups and treatment with a cationite in the H form. The proton-conducting membranes feature improved thermal stability (200–250°C), a breaking strength of 1.0–8.9 MPa, elasticity (a relative elongation at break of 1.0–8.2%), chemical resistance, and specific proton conductivity attaining 10−1 S/cm after doping with orthophosphoric acid.

Keywords

Oligomer Polymer Science Series Solid State Ionic Relative Elongation Anionic Polymeriza Tion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • M. V. Markova
    • 1
  • D. M. Mognonov
    • 2
  • L. V. Morozova
    • 1
  • A. I. Mikhaleva
    • 1
  • B. A. Trofimov
    • 1
  1. 1.Favorsky Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia
  2. 2.Baikal Institute for Nature Management, Siberian BranchRussian Academy of SciencesUlan-UdeBuryatia, Russia

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