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Synthesis of oligomeric chlorophosphazenes in the presence of ZnCl2

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Abstract

With the use of 31P NMR spectroscopy and gas chromatography-mass spectrometry, the partial ammonolysis of PCl5 by ammonium chloride in chlorobenzene in the presence of zinc chloride is investigated. The use of zinc chloride reduces the reaction time to 1.5 h and increases the yield of oligomeric chlorophosphazenes up to 95%. Some assumptions are made about the role of ZnCl2 in the process and about the feasibility of the mechanism of formation of higher cyclic chlorophosphazenes, the hexamer and the octamer.

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References

  1. V. V. Kireev, N. S. Bredov, Yu. V. Bilichenko, K. A. Lysenko, R. S. Borisov, and V. P. Chuev, Polymer Science, Ser. A 50, 609 (2008).

    Article  Google Scholar 

  2. V. V. Kireev, N. S. Bredov, B. M. Prudskov, Jianxin Mu, R. S. Borisov, I. B. Sokol’skaya, and V. P. Chuev, Polymer Science, Ser. B 53, 64 (2011).

    Article  CAS  Google Scholar 

  3. V. V. Kireev, E. M. Chistyakov, S. N. Filatov, R. S. Borisov, and B. M. Prudskov, Polymer Science, Ser. B 53, 412 (2011).

    Article  CAS  Google Scholar 

  4. E. M. Chistyakov, Yu. V. Bilichenko, V. V. Kireev, L. L. Gapochkina, V. F. Posokhova, and V. P. Chuev, RF Patent No. 2375039 (2009).

  5. A. K. Andrianov, Polyphosphazenes for Biomedical Applications (Wiley, New Jersey, 2009).

    Book  Google Scholar 

  6. M. A. Vantsyan, M. F. Bobrov, G. V. Popova, V. V. Kireev, and V. G. Tsirel’son, Polymer Science, Ser. A 49, 355 (2007).

    Article  Google Scholar 

  7. V. P. Chuev, Doctoral Dissertation in Technical Sciences (Moscow, 2010).

  8. E. M. Chistyakov, Candidate’s Dissertation in Chemistry (Moscow, 2011).

  9. H. N. Stokes, Am. Chem. J. 19, 782 (1897).

    Google Scholar 

  10. M. Becke-Goehring and E. Fluck, Angew. Chem. 74, 382 (1962).

    Article  CAS  Google Scholar 

  11. S. M. Zhivukhin, V. V. Kireev, G. S. Kolesnikov, V. P. Popilin, and E. A. Filippov, Zh. Neorg. Khim. 14, 1051 (1969).

    CAS  Google Scholar 

  12. Wan Le, Ye Yong, Ju Zhiyu, Zhong Shangbin, and Zhao Yufen, Phosphorus, Sulfur, Silicon, Relat. Elem. 184, 1958 (2009).

    Article  Google Scholar 

  13. Yuan Fulong, Zhu Yujun, Zhao Jinggui, Bin Zhang, and Jiang Dexiang, Phosphorus, Sulfur, Silicon, Relat. Elem. 176, 77 (2001).

    Article  Google Scholar 

  14. US Patent No. 4,382,914 (1983).

  15. UK Patent No. 2,397,058B (2005).

  16. A. Weissberger, E. Proskauer, J. Riddick, and E. Toops, Organic Solvents. Physical Properties and Methods of Purification (Wiley, New York, 1955; Inostrannaya Literatura, Moscow, 1958).

    Google Scholar 

  17. R. W. Kiser, J. G. Dillard, and D. L. Dugger, Adv. Chem. Ser. 72, 153 (1969).

    Article  Google Scholar 

  18. H. R. Allcock and R. J. Best, Can. J. Chem. 42, 447 (1964).

    Article  CAS  Google Scholar 

  19. V. V. Kireev, V. V. Korshak, G. I. Mitropol’skaya, and V. Sulkovski, Vysokomol. Soedin., Ser. A 21, 100 (1979).

    CAS  Google Scholar 

  20. J. Emsley and P. Udy, Inorg. Phys. Theor., 3025 (1970).

    Google Scholar 

  21. G. I. Derkach, I. N. Zhmurova, A. V. Kirsanov, et al., Phosphazo Compounds, Ed. by A. V. Kirsanov (Naukova Dumka, Kiev, 1965) [in Russian].

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    I. S. Sirotin, Yu. V. Bilichenko, O. V. Suraeva, A. N. Solodukhin & V. V. Kireev

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  1. I. S. Sirotin
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  2. Yu. V. Bilichenko
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  3. O. V. Suraeva
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  4. A. N. Solodukhin
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  5. V. V. Kireev
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Correspondence to V. V. Kireev.

Additional information

Original Russian Text © I.S. Sirotin, Yu.V. Bilichenko, O.V. Suraeva, A.N. Solodukhin, V.V. Kireev, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 2, pp. 218–224.

This work was supported by the Russian Foundation for Basic Research, project no. 12-03-00328.

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Sirotin, I.S., Bilichenko, Y.V., Suraeva, O.V. et al. Synthesis of oligomeric chlorophosphazenes in the presence of ZnCl2 . Polym. Sci. Ser. B 55, 63–68 (2013). https://doi.org/10.1134/S1560090413020048

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  • DOI: https://doi.org/10.1134/S1560090413020048

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